1,1′-Bis(diphenylphosphino)ferrocene CAS 12150-46-8 DPPF Purity >98.0% Fe 9.7~10.4%

Short Description:

Chemical Name: 1,1′-Bis(diphenylphosphino)ferrocene

Synonyms: 1,1′-Ferrocenebis(diphenylphosphine); DPPF

CAS: 12150-46-8

Purity: >98.0% (Chelometric Titration)

Fe (Titration by Na2S2O3) 9.7~10.4%

Appearance: Yellow to Orange Powder

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Description:

Shanghai Ruifu Chemical Co., Ltd. is the leading supplier of 1,1'-Bis(diphenylphosphino)ferrocene (CAS: 12150-46-8) with high quality. We can provide COA, worldwide delivery, small and bulk quantities available. If you are interested in this product, please send detailed information includes CAS number, product name, quantity to us. Please contact: alvin@ruifuchem.com

Chemical Properties:

Chemical Name	1,1'-Bis(diphenylphosphino)ferrocene
Synonyms	1,1'-Ferrocenebis(diphenylphosphine); DPPF
CAS Number	12150-46-8
CAT Number	RF-PI2275
Stock Status	In Stock, Production Scale Up to Tons
Molecular Formula	C34H28FeP2
Molecular Weight	554.39
Sensitive	Air Sensitive
Solubility in Water	Insoluble in Water
Solubility	Soluble in Chloroform
Hydrolytic Sensitivity	7: Reacts Slowly With Moisture/Water
Brand	Ruifu Chemical

Specifications:

Item	Specifications
Appearance	Yellow to Orange Powder
Purity / Analysis Method	>98.0% (Chelometric Titration)
Iron (Fe)	9.7~10.4% (Titration by Na2S2O3)
Carbon by Elemental Analysis	71.1~76.2%
Melting Point	181.0~183.0℃
Water by Karl Fischer	<0.50%
Solubility in CHCL3	Yellow to Orange, Clear(2.5%) Pass
Infrared Spectrum	Conforms to Structure
Test Standard	Enterprise Standard

Package & Storage:

Package: Bottle, Aluminium foil bag, 25kg/Cardboard Drum, or according to customer's requirement

Storage Condition: Store in sealed containers at cool and dry place; Protect from light and moisture

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Application:

1,1'-Bis(diphenylphosphino)ferrocene (CAS: 12150-46-8), Suzuki-Miyaura Cross Coupling Reaction, Ligands, Organic Metallic Catalysts. Generally used in the following chemical reactions namely Buchwald-Hartwig Cross Coupling Reaction, Carbonylations, Ene Reaction, Heck Reaction, Negishi Coupling, Sonogashira Coupling, Stille Coupling, Suzuki-Miyaura Coupling, Tsuji-Trost Reaction. Applications Commonly used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which is a popular reagent for palladium-catalyzed coupling reactions. Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation. Ligand used in a Pd(II)-catalyzed cross-coupling synthesis of oxazepine ring systems. 1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.