1,1 ′-Bis (diphenylphosphino) ferrocene CAS 12150-46-8 DPPF Purity > 98.0% Fe 9.7 ~ 10.4%
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Ainm Ceimigeach | 1,1'-Bis (diphenylphosphino) ferrocene |
Co-fhaclan | 1,1'-Ferrocenebis (diphenylphosphine);DPPF |
Àireamh CAS | 12150-46-8 |
Àireamh CAT | RF-PI2275 |
Inbhe Stoc | Ann an stoc, ìre toraidh suas gu tonna |
Foirmle Molecular | C34H28FeP2 |
Cuideam Molecular | 554.39 |
Mothachail | Air Mothachadh |
Solubility ann an uisge | Neo-sholabailte ann an uisge |
Fuasgladh | Soluble ann an cloroform |
Mothachadh Hydrolytic | 7: A’ freagairt gu mall le Taiseachd/Uisge |
Brand | Ceimigeach Ruifu |
Nì | Sònrachaidhean |
Coltas | Buidhe gu Pùdar Orains |
Purity / Modh Mion-sgrùdadh | > 98.0% (Titration Chelometric) |
Iarann (Fe) | 9.7~10.4% (Titration by Na2S2O3) |
Carbon le mion-sgrùdadh eileamaid | 71.1~76.2% |
Rubha leaghaidh | 181.0 ~ 183.0 ℃ |
An t-uisge le Karl Fischer | <0.50% |
Solubility ann an CHCL3 | Buidhe gu Orains, Soilleir (2.5%) Pass |
Spectrum fo-dhearg | A 'gèilleadh ris an Structar |
Inbhe deuchainn | Inbhe Iomairt |
Pacaid: Botal, poca foil alùmanum, 25kg / druma cairt-bhòrd, no a rèir riatanas luchd-ceannach
Suidheachadh stòraidh:Bùth ann an soithichean dùinte ann an àite fionnar is tioram;Dìon bho sholas is taiseachd
1,1'-Bis (diphenylphosphino) ferrocene (CAS: 12150-46-8), Suzuki-Miyaura Cross Coupling Reaction, Ligands, Catalysts Meatailt Organach.Mar as trice air a chleachdadh anns na h-ath-bhualaidhean ceimigeach a leanas is iad sin Ath-bhualadh Crois Buchwald-Hartwig, Carbonylations, Ene Reaction, Heck Reaction, Negishi Coupling, Sonogashira Coupling, Stille Coupling, Suzuki-Miyaura Coupling, Tsuji-Trost Reaction.Tagraidhean Cumadh co-òrdanachaidh a thathas a’ cleachdadh gu cumanta ann an synthesis, gu furasta a’ cruthachadh iom-fhilltean le diofar mheatailtean, ie nuair a bhios e ag ath-fhreagairt leis na h-ionadan acetonitrile no benzonitrile de PdCl2 bidh e a’ cruthachadh (dppf) PdCl2, a tha na imoibreant mòr-chòrdte airson ath-bheachdan ceangail palladium-catalyzed.Chaidh derivatives furan gnìomh ùr-nodha ullachadh tro chruthachadh bannan CC agus CO sreath Pd-phosphine.Ligand air a chleachdadh ann an synthesis tar-cheangail Pd(II)-catalyzed de shiostaman fàinne oxazepine.Tha 1,1'-Bis (diphenylphosphino) ferrocene ag obair mar ligand ann an catalysis aon-ghnèitheach.Tha e air a chleachdadh mar ligand airson synthesis amine nas uaine ruthenium-catalyzed bho amines agus alcohols le bhith a’ faighinn iasad de hydrogen.Tha e cuideachd air a chleachdadh mar ligand airson ceangal crois Buchwald-Hartwig.A bharrachd air an sin, tha e air a chleachdadh ann an synthesis todhar co-òrdanachaidh a bharrachd air cruthachadh iom-fhillte le diofar mheatailtean leithid palladium chloride.A bharrachd air an seo, tha e na inneal airson ath-bheachdan ceangail palladium-catalyzed agus tha àite cudromach aige cuideachd ann am freagairt Suzuki.