(S)-(-)-TolBINAP CAS 100165-88-6 Tsafta > 98.0% (HPLC)
Shanghai Ruifu Chemical Co., Ltd. shine babban kamfani na (S) - (-) TolBINAP (CAS: 100165-88-6) tare da inganci mai kyau.Ruifu Chemical na iya samar da isar da saƙo na duniya, farashi mai gasa, kyakkyawan sabis, ƙanana da adadi mai yawa akwai.Sayi (S)-(-)-TolBINAP,Please contact: alvin@ruifuchem.com
Sunan Sinadari | (S)-(-)-2,2'-Bis(di-p-Tolylphosphino) -1,1'-Binaphthyl |
Makamantu | (S)-(-)-TolBINAP (S)-Tol-BINAP;(S)-T-BINAP;(S)-Tol-BINA;(-)-Tol-BINA;(-)-Tol-BINAP |
Matsayin Hannun jari | A Stock, Kasuwancin Kasuwanci |
Lambar CAS | 100165-88-6 |
Tsarin kwayoyin halitta | Saukewa: C48H40P2 |
Nauyin Kwayoyin Halitta | 678.80 g/mol |
Matsayin narkewa | 252.0 ~ 259.0 ℃ |
M | Hankalin iska.Ajiye Karkashin Gas Inert |
Ruwan Solubility | Mara narkewa a cikin Ruwa |
COA & MSDS | Akwai |
Rukunin samfur | Ligands;Chiral Ligands |
Asalin | Shanghai, China |
Alamar | Ruifu Chemical |
Abubuwa | Ƙayyadaddun bayanai | Sakamako |
Bayyanar | Fari zuwa Kashe-Farin Foda | Farin Foda |
Matsayin narkewa | 252.0 ~ 259.0 ℃ | 256.9 ℃ |
Tsarkake / Hanyar Bincike | 98.0% (HPLC) | 98.5% |
Tsarkake / Hanyar Bincike | 97.5 ~ 102.5% (Titration Neutralization) | Ya bi |
Tsaftar gani (ee) | > 99.0% (HPLC) | 99.2% |
Takamaiman Juyawa [a] 20/D | -167.0°~-157.0° (C=1.052, Benzene) | -158.7 |
Infrared Spectrometry | Daidai da Tsarin | Ya bi |
1H NMR Spectrum | Daidai da Tsarin | Ya bi |
Kammalawa | An gwada samfurin kuma ya dace da ƙayyadaddun da aka bayar |
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Yadda ake siya?Da fatan za a tuntuɓiDr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com
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Lambobin haɗari
36/37/38 - Haushi da idanu, tsarin numfashi da fata.
Bayanin Tsaro
S26 - Idan ana hulɗa da idanu, kurkura nan da nan da ruwa mai yawa kuma ku nemi shawarar likita.
S36/37/39 - Sanya tufafin kariya masu dacewa, safar hannu da kariya ta ido/ fuska.
WGK Jamus 3
TSCA No
Lambar 2931900090
(S)-(-)-2,2'-Bis(di-p-Tolylphosphino) -1,1'-Binaphthyl ((S)-(-)-TolBINAP) (CAS: 100165-88-6) Amsa
ligand mai fa'ida don ƙirƙirar haɗin carbon-oxygen-catalyzed palladium.
Ligand don palladium-catalyzed α-arylation na ketones.
Ligand don Cu-catalyzed asymmetric conjugate rage.
Ligand don Cu-catalyzed asymmetric dienolate ƙari zuwa aldehydes.
Enantioselective conjugate rage lactones da lactams.
Ligand da aka yi amfani da shi a cikin enantioselective cycloaddition na allylsilanes tare da α-Imino esters.
Catalytic Aldol martani ga ketones.
Ligand tare da rhodium catalyses [2+2+2] cycloaddition dauki na alkenes da alkynes.
Ligand amfani da iridium-catalyzed enantioselective CH bond kunnawa na 2- (alkylamino) -pyridine tare da alkenes.
Iridium-catalyzed regio-, diastereo-, da enantioselective tert- (hydroxyl) -haɓakar barasa.
Rhodium-catalyzed giciye cyclotrimerization.
(S)-(-)-2,2'-Bis (di-p-Tolylphosphino) -1,1'-Binaphthyl ((S)-(-)-TolBINAP) (CAS: 100165-88-6) shi ne chiral ligand yadu amfani da asymmetric kira.Hakanan ana amfani dashi azaman mai haɓakawa don asymmetric hydrogenation na alkenes da wasu anhydrides na cyclic.Ana amfani da BINAP a cikin haɗin gwiwar kwayoyin halitta don sauye-sauye na enantioselective wanda ke haifar da ruthenium, rhodium, da palladium.
(S) - (-) TolBINAP yana amsawa tare da nitrate na azurfa don samar da (S) -Tol-BINAP · AgNO3, wanda zai iya haifar da halayen haɗin gwiwar aldehydes don samar da enantiopure na sakandare.Ana iya amfani da shi azaman ligand na chiral a cikin palladium catalyzed asymmetric double carbohydroamination na iodoarenes don samar da α-aminoamides.Hakanan yana iya haɓaka halayen asymmetric N-allylation na abubuwan haɓakar ortho-tert-butylanilide tare da diallyl carbonate don samar da chiral N-allyl ortho-tert-butylanilides.