1,1′-Bis(diphenylphosphino)ferrocene CAS 12150-46-8 DPPF Maʻemaʻe >98.0% Fe 9.7~10.4%
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Inoa Kimia | 1,1'-Bis(diphenylphosphino)ferrocene |
Nā huaʻōlelo like | 1,1'-Ferrocenebis(diphenylphosphine);DPPF |
Helu CAS | 12150-46-8 |
Helu CAT | RF-PI2275 |
Kūlana Kūʻai | Ma ka waihona, hoʻonui ʻia a hiki i nā tona |
ʻĀpana Molekala | C34H28FeP2 |
Kaumaha Molecular | 554.39 |
Pilikino | Paʻi Lewa |
Solubility i ka wai | ʻAʻole hiki ke hoʻonā i ka wai |
Ka hikiwawe | Hiki ke hoʻoheheʻe ʻia i loko o Chloroform |
Hydrolytic Sensitivity | 7: Hana mālie me ka wai |
Brand | Kemika Ruifu |
'ikamu | Nā kikoʻī |
Ka nana aku | Melemele i ka pauda ʻalani |
Maʻemaʻe / Kaʻina Hanana | >98.0% (Chelometric Titration) |
Hao (Fe) | 9.7~10.4% (Titration e Na2S2O3) |
Kalapona ma ka Elemental Analysis | 71.1~76.2% |
Lae hehee | 181.0~183.0 ℃ |
Wai na Karl Fischer | <0.50% |
Solubility i CHCL3 | Melemele a ʻAlani, Māmā(2.5%) Pass |
Infrared Spectrum | Kūlike i ka hoʻolālā |
Kūlana hoʻāʻo | Kūlana ʻoihana |
Pūʻolo: ʻOmole, ʻeke ʻeke Aluminum, 25kg / pahu pahu pahu, a i ʻole e like me ka makemake o ka mea kūʻai aku.
Kūlana mālama:E mālama i loko o nā pahu i hoʻopaʻa ʻia ma kahi maloʻo a maloʻo;E pale i ka malamalama a me ka wai
1,1'-Bis(diphenylphosphino)ferrocene (CAS: 12150-46-8), Suzuki-Miyaura Cross Coupling Reaction, Ligands, Organic Metallic Catalysts.Hoʻohana maʻamau i nā hopena kemika e like me Buchwald-Hartwig Cross Coupling Reaction, Carbonylations, Ene Reaction, Heck Reaction, Negishi Coupling, Sonogashira Coupling, Stille Coupling, Suzuki-Miyaura Coupling, Tsuji-Trost Reaction.Hoʻohana ʻia ka hui hoʻohui maʻamau i ka synthesis, hana maʻalahi i nā paʻakikī me nā metala like ʻole, ʻo ia hoʻi i ka wā e hana ai me ka acetonitrile a i ʻole benzonitrile paʻakikī o PdCl2 i hoʻokumu ʻia (dppf)PdCl2, he reagent kaulana no nā hopena hoʻohui palladium-catalyzed.Ua hoʻomākaukau ʻia nā derivatives furan hana hou ma o ka Pd-phosphine sequential CC a me ka hoʻokumu ʻana i ka paʻa CO.Hoʻohana ʻia ʻo Ligand i kahi Pd(II) -catalyzed cross-coupling synthesis o nā ʻōnaehana apo oxazepine.Hana ʻo 1,1'-Bis(diphenylphosphino)ferrocene ma ke ʻano he ligand i ka catalysis homogeneous.Hoʻohana ʻia ʻo ia ma ke ʻano he ligand no ka ruthenium-catalyzed greener amine synthesis mai nā amines a me nā waiʻona e ka hydrogen-borrowing.Hoʻohana ʻia ʻo ia ma ke ʻano he ligand no Buchwald-Hartwig cross coupling.Eia kekahi, hoʻohana ʻia ia i ka synthesis o ka hui hoʻohui a me ka hoʻokumu ʻana o nā paʻakikī me nā metala like ʻole e like me ka palladium chloride.Ma waho aʻe o kēia, lawelawe ia ma ke ʻano he reagent no ka palladium-catalyzed coupling reactions a he hana koʻikoʻi hoʻi i ka hopena Suzuki.