4-Dimethylaminopyridine DMAP CAS 1122-58-3 Maʻemaʻe >99.0% (HPLC) Kiʻi Hōʻike ʻia ʻo Catalyst

4-Dimethylaminopyridine DMAP CAS 1122-58-3 Maʻemaʻe> 99.0% (HPLC) Mea Hoʻoikaika Kiʻekiʻe

ʻO ka wehewehe pōkole:

Inoa Kemika: 4-Dimethylaminopyridine

Nā huaʻōlelo like:DMAP

CAS: 1122-58-3

Keʻokeʻo a i ʻole ke keʻokeʻo Crystalline pauda

Maʻemaʻe: >99.0% (HPLC)

Kiʻekiʻe Efficiency Catalyst, Coupling Reagent

Hoʻokaʻaʻike: Kauka Alvin Huang

Mobile/Wechat/WhatsApp: +86-15026746401

Inquiry: alvin@ruifuchem.com

E hoʻouna i ka leka uila iā mākou

Huahana Huahana

Nā Huahana Pili

Huahana Huahana

wehewehe:

ʻO Shanghai Ruifu Chemical Co., Ltd. ka mea hana nui o 4-Dimethylaminopyridine (DMAP) (CAS: 1122-58-3) me ke kūlana kiʻekiʻe.Hiki iā Ruifu Chemical ke hāʻawi i ka hāʻawi honua, ke kumukūʻai hoʻokūkū, ka liʻiliʻi a me ka nui o ka nui.Kūʻai DMAP, Please contact: alvin@ruifuchem.com

Na Waiwai Kemika:

Inoa Kimia	4-Dimethylaminopyridine
Nā huaʻōlelo like	DMAP;4-(Dimethylamino)pyridine;N-(4-Pyridyl)dimethylamine;N,N-Dimethylpyridin-4-Amine;N,N-Dimethyl-4-Pyridinamine;gamma-(Dimethylamino)pyridine
Helu CAS	1122-58-3
Kūlana Kūʻai	I loko o ka waihona, i hana ʻia 40 Tons i kēlā me kēia mahina
ʻĀpana Molekala	C7H10N2
Kaumaha Molecular	122.17
Lae hehee	110.0~114.0 ℃
Lae paila	190 ℃/150 mmHg
ʻO ka mānoanoa	0.906 g/mL ma 25 ℃
Hōʻike Hōʻike	n20/D 1.431
Solubility i loko o ka Methanol	Nawaliwali loa
Solubility i ka wai	Hiki i ka wai, 80 g/l 25 ℃
Solubility (Malu loa i loko)	Chloroform, Benzene, Methanol, Acetone
COA & MSDS	Loaʻa
Brand	Kemika Ruifu

Nā kikoʻī:

'ikamu	Nā kikoʻī
Ka nana aku	Keʻokeʻo a i ʻole ke keʻokeʻo Crystalline pauda
Maʻemaʻe / Kaʻina Hanana	>99.0% (HPLC)
Lae hehee	110.0~114.0 ℃
ʻAʻole hiki ke hoʻonā i ka wai	<0.10%
Māmā (KF)	<0.30%
Nalo ma ka maloo	<0.50% (Ma lalo o ka Mūmā No 3 Hora Ma 60ºC)
Hoʻokahi haumia	<0.50%
Huina paumaele	<1.00%
Infrared Spectrum	Kūlike me ka Hoʻolālā
1 H NMR Spectrum	Kūlike me ka Hoʻolālā
Kūlana hoʻāʻo	Kūlana ʻoihana

Pūʻolo a me ka waiho ʻana:

Pūʻolo:ʻO ka ʻōmole, ʻeke ʻeke alumini, 25kg / pahu pahu pahu, a i ʻole e like me ka makemake o ka mea kūʻai aku.
Kūlana mālama:E kūʻai i loko o nā pahu i hoʻopaʻa ʻia ma kahi hale kūʻai maloʻo a maloʻo (≤10 ℃) mai nā mea like ʻole.E pale i ka malamalama a me ka wai.
Hoʻouna:Hāʻawi i ka honua ma FedEx / DHL Express.Hāʻawi wikiwiki a hilinaʻi hoʻi.

Pono:

ʻO ka mana kūpono: lawa nā lako a me nā ʻenehana

ʻOihana Hoʻonaʻauao: Hoʻokahi lawelawe kūʻai kūʻai

Puke OEM: Loaʻa ka pūʻolo maʻamau a me ka lepili

Hoʻouna wikiwiki: Inā i loko o ke kumukūʻai, ʻekolu lā hoʻouna i hōʻoia ʻia

Hoʻolako Paʻa: E mālama i ka waiwai kūpono

Kākoʻo ʻenehana: Loaʻa ka hopena ʻenehana

Hana Hana Hana Kuʻuna: Mai ka grama a hiki i ke kilo

Kūlana Kiʻekiʻe: Hoʻokumu i kahi ʻōnaehana hōʻoia maikaʻi piha

FAQ:

1122-58-3 - Pilikia a palekana:

1122-58-3 - Pilikia a palekana
Nā Code Risk
R25 - He ʻawaʻawa inā ʻai ʻia
R34 - Ke kumu o ke kuni
R24/25 -
R36/37/38 - E hoʻonāukiuki i nā maka, ka ʻōpū hanu a me ka ʻili.
R27 - He ʻawaʻawa loa i ka pili ʻana me ka ʻili
R36 - Hoʻonanea i nā maka
R24 - He ʻona i ka pili ʻana me ka ʻili
R20 - Hoʻopilikia i ka inhalation
R61 - Hiki ke hoʻopilikia i ke keiki hānau ʻole
R40 - Nā hōʻike liʻiliʻi o ka hopena carcinogenic
R23/24/25 - He mea ʻona ma ka inhalation, pili me ka ʻili a inā ale ʻia.
R67 - Hiki i nā mahu ke hoʻoulu i ka hiamoe a me ka noʻonoʻo
R66 - Hiki ke hoʻomaloʻo a pohā paha ka ʻili i ka ʻike pinepine ʻia
R21/22 - He pōʻino i ka pili ʻana me ka ʻili a inā ale ʻia.
R11 - Hiki ke ahi
R36/37 - E hoʻonāukiuki i nā maka a me ka ʻōnaehana hanu.
R22 - Poino ke aleia
R19 - Hiki ke hana i nā peroxide pahū
Ka wehewehe palekana
S36/37/39 - E hoʻohana i nā lole pale kūpono, nā mīkina lima a me ka pale maka/maka.
S45 - Inā loaʻa ka pōʻino a i ʻole ka maikaʻi ʻole, e ʻimi koke i ka ʻōlelo aʻo kino (e hōʻike i ka lepili inā hiki.)
S28A -
S26 - Inā pili me nā maka, e holoi koke me ka wai nui a e ʻimi i ka ʻōlelo aʻo kino.
S28 - Ma hope o ka pili ʻana me ka ʻili, holoi koke me ka nui o ke kopa.
S36/37 - E hoʻohana i nā lole pale kūpono a me nā mīkina lima.
S53 - Hōʻalo i ka ʻike - loaʻa i nā ʻōlelo kuhikuhi kūikawā ma mua o ka hoʻohana ʻana.
S27 - Wehe koke i nā lole i haumia.
S22 - Mai hanu i ka lepo.
S16 - E hoʻokaʻawale i nā kumu o ke ahi.
Nā ID UN UN 2811 6.1/PG 2
WGK Kelemānia 3
RTECS US8400000
TSCA T
HS Code 2942000000
ʻAiʻona/ʻinoʻino
Papa Hazard 8
Hui Pūʻulu II
ʻona LD50 ma ka waha i loko o ka Lapeti: 140 mg/kg LD50 dermal Lapiti 90 mg/kg

Noi:

ʻO 4-Dimethylaminopyridine (DMAP) (CAS: 1122-58-3) kahi mea hoʻoheheʻe maikaʻi hou i hoʻohana nui ʻia i ka synthesis kemika.Loaʻa iā ia ka mana catalytic kiʻekiʻe i ka synthesis organik, synthesis lāʻau lapaʻau, pesticide, dye, ʻala synthesis o acylation, alkylation, etherification a me nā ʻano ʻano like ʻole, a he hopena maopopo loa i ka hoʻomaikaʻi ʻana i ka hua.Acylation o ka waiʻona;Acylation o nā phenols;Acylation o nā amine;Acylation o nā enolate;Nā pane o nā isocyanates;Nā noi like ʻole;Hoʻololi i nā hui hana.
ʻO DMAP, kahi mea hoʻoheheʻe super nucleophilic acylation.Hiki i ka resonance o ka pūʻulu dimethylamino hāʻawi electron i loko o kona hale a me ke apo makua (pyridine ring) hiki ke hoʻoikaika ikaika i ka atom nitrogen ma ke apo e hana i ka nucleophilic substitution, kahi e hoʻoikaika nui ai i ke kū'ē kiʻekiʻe, haʻahaʻa-reactive alcohols a me nā amine/acids. ʻO ka hopena acylation / esterification ma kahi o 104 ~ 106 mau manawa o ka pyridine.ʻO ka hoʻololi ʻana ʻo Acyl kahi hoʻololi maʻamau i ke ʻano a me ka synthesis organik, kahi chiral DMAP he mea hoʻololi maʻamau asymmetric acyl transfer catalyst.Mai ka makahiki 1996, hōʻike ka hui ʻo Vedejs a me Fu i ke kikowaena chiral a me planar chiral DMAP catalysts, ua hoʻomohala nui ʻia nā chiral DMAP catalysts.Ua hōʻike ʻia nā ʻano chiral waena, planar chiral, spiro chiral a me central chiral DMAP kekahi ma hope o kekahi, a ua hoʻohana maikaʻi ʻia i nā hopena asymmetric acyl transfer.
ʻO DMAP kahi mea hoʻoheheʻe nucleophilic nui loa no nā hopena acylation a me nā esterifications.Hoʻohana ʻia ia i nā loli kūlohelohe like ʻole e like me Baylis-Hillman reaction, Dakin-West reaction, protection of amines, C-acylations, silylations, applications in natural products chemistry, a me nā mea he nui.
Hiki ke hoʻohana ʻia ka DMAP ma ke ʻano he catalyst: No ka acylation o nā ʻawaʻawa me nā anhydride waikawa ma lalo o ke kumu kōkua- a me nā kūlana solvent-free e synthesize esters pili.Ma Baylis-Hillman pane ʻana e hana i ka paʻa kalapona-kāpona ma ka hoʻohui ʻana o kahi alkene i hoʻāla ʻia me kahi aldehyde a i ʻole ketone.
ʻO kahi catalyst maikaʻi loa no nā hopena acylation.