(S)-(-)-TolBINAP CAS 100165-88-6 Maʻemaʻe >98.0% (HPLC)
ʻO Shanghai Ruifu Chemical Co., Ltd. ka mea hana nui o (S)-(-)-TolBINAP (CAS: 100165-88-6) me ke kūlana kiʻekiʻe.Hiki iā Ruifu Chemical ke hāʻawi aku i ka honua holoʻokoʻa, ke kumukūʻai hoʻokūkū, ka lawelawe maikaʻi loa, ka liʻiliʻi a me ka nui nui i loaʻa.Kūʻai (S)-(-)-TolBINAP,Please contact: alvin@ruifuchem.com
| Inoa Kimia | (S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl |
| Nā huaʻōlelo like | (S)-(-)-TolBINAP (S)-Tol-BINAP;(S)-T-BINAP;(S)-Tol-BINA;(-)-Tol-BINA;(-)-Tol-BINAP |
| Kūlana Kūʻai | Ma ke Kahua, Hana Hana Kūʻai |
| Helu CAS | 100165-88-6 |
| ʻĀpana Molekala | C48H40P2 |
| Kaumaha Molecular | 678.80 g/mol |
| Lae hehee | 252.0~259.0 ℃ |
| Pilikino | Paʻi Lewa.Halekuai malalo o ke kinoea inert |
| Hiki i ka wai | ʻAʻole hiki ke hoʻonā i ka wai |
| COA & MSDS | Loaʻa |
| Māhele Huahana | Ligands;ʻO nā Ligands Kiral |
| Ke kumu | Shanghai, Kina |
| Brand | Kemika Ruifu |
| Nā mea | Nā kikoʻī | Nā hualoaʻa |
| Ka nana aku | Keʻokeʻo a hiki i ka pauda keʻokeʻo | Pauda keʻokeʻo |
| Lae hehee | 252.0~259.0 ℃ | 256.9 ℃ |
| Maʻemaʻe / Kaʻina Hanana | >98.0% (HPLC) | 98.5% |
| Maʻemaʻe / Kaʻina Hanana | 97.5~102.5% (Nūnā Hoʻopalekana) | Hoʻokō |
| Maʻemaʻe Optical (ee) | >99.0% (HPLC) | 99.2% |
| Ka Poali Pono [a]20/D | -167.0°~-157.0° (C=1.052, Benzene) | -158.7° |
| Infrared Spectrometry | Kūlike me ka Hoʻolālā | Hoʻokō |
| 1H NMR Spectrum | Kūlike me ka Hoʻolālā | Hoʻokō |
| Ka hopena | Ua hoʻāʻo ʻia ka huahana a hoʻokō me nā kikoʻī i hāʻawi ʻia | |
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Pehea e kūʻai ai?E ʻoluʻolu e kelepona maiDr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com
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36/37/38 - E hoʻonāukiuki i ka maka, ka hanu a me ka ʻili.
Ka wehewehe palekana
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WGK Kelemānia 3
TSCA No
HS Code 2931900090
(S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl ((S)-(-)-TolBINAP) (CAS: 100165-88-6) Pane
Pono pono no ka palladium-catalyzed carbon-oxygen bond formation.
ʻO Ligand no ka palladium-catalyzed α-arylation o nā ketones.
Ligand no Cu-catalyzed asymmetric conjugate hoemi.
Ligand no Cu-catalyzed asymmetric dienolate hoʻohui i nā aldehydes.
ʻO Enantioselective conjugate ka hoʻohaʻahaʻa ʻana i nā lactones a me nā lactams.
Hoʻohana ʻia ʻo Ligand i ka cycloaddition enantioselective o allenylsilanes me nā esters α-Imino.
ʻO ka hopena Catalytic Aldol i nā ketones.
Ligand me rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
Hoʻohana ʻia ʻo Ligand i loko o ka iridium-catalyzed enantioselective CH bond activation o 2-(alkylamino)-pyridine me nā alkenes.
Iridium-catalyzed regio-, diastereo-, a me enantioselective tert-(hydroxyl)-prenylation o nā waiʻona.
Rhodium-catalyzed cross cyclotrimerization.
(S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl ((S)-(-)-TolBINAP) (CAS: 100165-88-6) he chiral hoʻohana nui ʻia ka ligand i ka synthesis asymmetric.Ua hoʻohana pū ʻia ma ke ʻano he catalysts maikaʻi loa no ka hydrogenation asymmetric o nā alkenes a me kekahi mau anhydride cyclic.Hoʻohana ʻia ʻo BINAP i ka synthesis organik no nā hoʻololi enantioselective i hoʻopaʻa ʻia e kāna mau paʻakikī o ruthenium, rhodium, a me palladium.
(S)-(-)-TolBINAP pane me ke kala nitrate e hana (S)-Tol-BINAP·AgNO3, hiki ke hoʻopololei i ka enantioselective allylation hopena o nā aldehydes e hana i enantiopure lua waiʻona.Hiki ke hoʻohana ʻia ma ke ʻano he ligand chiral i loko o ka palladium catalyzed asymmetric double carbohydroamination o iodoarenes e hana i nā α-aminoamides.Hiki iā ia ke hoʻoikaika i ka hopena N-allylation asymmetric o nā derivatives ortho-tert-butylanilide me ka diallyl carbonate e hana i ka chiral N-allyl ortho-tert-butylanilides.
