Iodotrimethylsilane CAS 16029-98-4 Maʻemaʻe >99.0% (Argentmetric Titration) Hale Hana

ʻO Iodotrimethylsilane (CAS: 16029-98-4) ka mea i loaʻa i kahi paʻa paʻa (Me3Si) -soft base (I) paʻa e hōʻike i ka oxygenophilicity ikaika i nā ethers, esters, lactones, acetals, a me nā molekala ʻē aʻe e pili ana i ka oxygen atom ma ke ʻano he hui hana.ʻO ka hoʻohana ʻana i ka iodotrimethylsilane ma ke ʻano he mea hana i lawe mai i kahi mahele maʻalahi o ka ester tert-butyl, e hāʻawi ana i ka waikawa carboxylic pili i ka hua maikaʻi loa.Hoʻohana ʻia ʻo Iodotrimethylsilane no ka hoʻokomo ʻana i ka hui trimethylsilyl i ka synthesis organik.Maikaʻi nō hoʻi ia no ka nānā ʻana i ka chromatography gas ma ka hoʻololi ʻana i ka waiʻona i kahi derivative silyl ether, a laila e ʻoi aku ka maʻalahi ma mua o ka mole kumu.ʻO Iodotrimethylsilane kahi mea hoʻoponopono kūpono no ka ether, ester, carbamate, ketal, a me ka lactone cleavage.No ka hoʻokomo ʻana i ka hui TMS, e laʻa, TMS enol ethers.Reagent koʻikoʻi no ka deprotection koho o kahi hui N-Cbz i mua o kahi trimethyltin moiety.Ua hōʻike koke ʻia ʻo Reagent e hoʻohuli i nā allyl- a me benzylphosphotriester i nā iodides pili.ʻO Iodotrimethylsilane kahi mea pale maʻamau i ka hana lāʻau lapaʻau, hoʻohana nui ʻia i ka synthes o nā lāʻau lapaʻau.Hiki iā ia ke pale a pale i nā pūʻulu hana ma ke koho ʻana, e hana ma ke ʻano he silane blocking agent.ʻO ka Iodotrimethylsilane he mea hoʻohana multipurpose i hoʻohana ʻia i nā ʻano kūlohelohe like ʻole.Hoʻohana ʻia ia no ka hana ʻana o nā pūhui liʻiliʻi e like me nā lactones, ethers, acetals, a me nā carbamates a me ka trimethylsilylating agent no ka synthesis o nā esters silyl imino, alkyl a me alkenyl silanes, a pēlā aku. nui nā ʻano hoʻohālikelike.Hiki ke hoʻohana ʻia ʻo Iodotrimethylsilane ma ke ʻano he versatile reagent no ka dealkylation māmā o nā ethers, carboxylic esters, lactones, carbamates, acetals, phosphonate a me phosphate esters;ka wehe ʻana o nā epoxides, cyclopropyl ketones;ka hoʻololiʻana i nā vinyl phosphates i ka vinyl iodide;ka mea hoʻoheheʻe nucleophilic kūʻokoʻa no nā hoʻololi hoʻololi halogen, carbonyl a me nā hopena hoʻohui conjugate;hoʻohana ma ke ʻano he trimethylsilylating agent no ke kūkulu ʻana i nā enol ethers, silyl imino esters, a me N-silylenamines, alkyl, alkenyl a me alkynyl silanes;Lewis acid catalyst no ka hoʻokumu ʻana i ka acetal, α-alkoxymethylation o nā ketones, no nā hopena o nā acetals me nā silyl enol ethers a me allylsilanes;mea hoemi no na epoxide, enediones, α-ketols, sulfoxides, a me sulfonyl halides;mea hoʻoheheʻe wai no nā oxime.