(S)-(-)-BINAP CAS 76189-56-5 Maʻemaʻe ≥99.0% (HPLC) EE ≥99.0% Hale Hana

(S)-(-)-BINAP (CAS: 76189-56-5), he pūhui phosphine organik a he mea pono ia ma ke ʻano he chiral catalyst a me ka lāʻau waena.Kiral ligand no ka metala asymmetric catalysis.
2,2'-Bis (diphenylphosphino) -1,1'-Binaphthyl a me kona rhodium a me ka ruthenium derivatives hiki ke hoʻohanaʻia e like me ke koho nui homogeneous catalysts no ka ho'ēmiʻana o aryl ketones, β-ketoesters a me α-aminoketones.Hiki ke hoʻohana ʻia i ka asymmetric hydrogenation a me ka hydroformylation reactions o nā olefins, asymmetric Heck reactions a me asymmetric isomerization reactions o nā hui allyl.
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Hoʻohana ʻia ʻo Ligand i ka asymmetric arylation asymmetric o ka palladium-catalyzed o nā ketones.
Hoʻohana ʻo Ligand i ka rhodium-catalyzed 1,4-hoʻohui i nā enones.
Hoʻohana ʻia ʻo Ligand i ka hydroamination palladium-catalyzed o nā derivatives styrene.
Hoʻohana ʻia ʻo Ligand i ke kala-catalyzed asymmetric Sakuri-Hosomi allylation a me Mukaiyama aldol reaction.
Hoʻohana ʻia ʻo Ligand i ka hoʻonā kinetic rhodium-catalyzed o nā enynes.
Hoʻohana ʻia ʻo Ligand i ka asymmetric rhodium-catalyzed hydroboration o cyclopropenes.
Hoʻohana ʻia ʻo Ligand i loko o ka a-hydroxylation o ka stannyl enol ethers.
Hoʻohana ʻia ʻo Ligand i ka palladium-catalyzed synthesis o nā allenes chiral.
Hoʻohana i ka Reactant i komo i:
Enantioselective a me diastereoselective unpoled carbonyl allylation
Syntehsis o organophophine oxides e like me nā mea hana anittumor
SN2 halogenation o nā hui hydroxy
ʻO ka hoʻohui ʻana o nā paʻakikī BINAP
Nā haʻawina e pili ana i ka maʻalahi conformational o BINAP chelates