1,1′-Bis (diphenylphosphino) ferrocene CAS 12150-46-8 DPPF Purity > 98.0% Fe 9.7 ~ 10.4%
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Tshuaj npe | 1,1'-Bis (diphenylphosphino) ferrocene |
Synonyms | 1,1'-Ferrocenebis (diphenylphosphine);DPPF |
CAS Nr | 12150-46-8 |
CAT Number | Qauv TSIS MUAJ: RF-PI2275 |
Tshuag xwm txheej | Nyob rau hauv Tshuag, ntau lawm Scale mus txog Tons |
Molecular Formula | C34H28FeP2 |
Molecular Luj | 554.39 ib |
rhiab heev | Huab cua Sensitive |
Solubility hauv dej | Insoluble hauv dej |
Solubility | Soluble hauv Chloroform |
Hydrolytic rhiab heev | 7: Reacts maj mam nrog noo noo / dej |
Hom | Ruifu Tshuaj |
Yam khoom | Specifications |
Qhov tshwm sim | Yellow rau txiv kab ntxwv hmoov |
Purity / Analysis Method | > 98.0% (Chelometric Titration) |
Hlau (Fe) | 9.7 ~ 10.4% (Titration los ntawm Na2S2O3) |
Carbon los ntawm Elemental Analysis | 71.1 ~ 76.2% |
Melting Point | 181.0 ~ 183.0 ℃ |
Dej los ntawm Karl Fischer | <0.50% |
Solubility hauv CHCL3 | Yellow rau txiv kab ntxwv, Ntshiab (2.5%) dhau |
Infrared Spectrum | Raws li tus qauv |
Test Standard | Enterprise Standard |
Pob: Lub raj mis, Aluminium ntawv ci hnab, 25kg / Cardboard Nruas, los yog raws li tus neeg yuav tsum tau muaj
Cia txias:Khaws rau hauv cov thawv ntim khoom ntawm qhov chaw txias thiab qhuav;Tiv thaiv los ntawm lub teeb thiab noo noo
1,1'-Bis (diphenylphosphino) ferrocene (CAS: 12150-46-8), Suzuki-Miyaura Cross Coupling Reaction, Ligands, Organic Metallic Catalysts.Feem ntau siv rau hauv cov tshuaj tiv thaiv nram qab no uas yog Buchwald-Hartwig Cross Coupling Reaction, Carbonylations, Ene Reaction, Heck Reaction, Negishi Coupling, Sonogashira Coupling, Stille Coupling, Suzuki-Miyaura Coupling, Tsuji-Trost Reaction.Daim ntaub ntawv Feem ntau siv kev sib koom ua ke hauv kev sib xyaw ua ke, yooj yim tsim cov complexes nrog ntau yam hlau, piv txwv li thaum reacting nrog cov acetonitrile los yog benzonitrile complexes ntawm PdCl2 nws cov ntaub ntawv (dppf) PdCl2, uas yog ib tug nrov reagent rau palladium-catalyzed coupling tshua.Novel functionalized furan derivatives tau npaj los ntawm Pd-phosphine sequential CC thiab CO daim ntawv cog lus.Ligand siv hauv Pd(II)-catalyzed cross-coupling synthesis ntawm oxazepine nplhaib tshuab.1,1'-Bis (diphenylphosphino) ferrocene ua raws li ligand hauv homogeneous catalysis.Nws yog siv los ua ligand rau ruthenium-catalyzed greener amine synthesis los ntawm amines thiab cawv los ntawm hydrogen-qiv.Nws kuj tseem ua haujlwm raws li ligand rau Buchwald-Hartwig cross coupling.Tsis tas li ntawd, nws yog siv rau hauv kev sib txuas ntawm kev sib koom ua ke nrog rau kev tsim cov complexes nrog ntau yam hlau xws li palladium chloride.Ntxiv rau qhov no, nws ua haujlwm ua reagent rau palladium-catalyzed coupling cov tshuaj tiv thaiv thiab tseem ua lub luag haujlwm tseem ceeb hauv Suzuki cov tshuaj tiv thaiv.