Iodotrimethylsilane CAS 16029-98-4 Purity > 99.0% (Argentmetric Titration) Hoobkas

Iodotrimethylsilane (CAS: 16029-98-4) uas muaj ib qho nyuaj acid (Me3Si) -soft base (I) daim ntawv cog lus qhia muaj zog oxygenophilicity ntawm ethers, esters, lactones, acetals, thiab lwm yam molecules uas muaj oxygen atom ua ib pawg ua haujlwm.Kev siv iodotrimethylsilane raws li tus neeg sawv cev tau coj mus rau qhov yooj yim cleavage ntawm tert-butyl ester, muab cov carboxylic acid sib xws hauv cov txiaj ntsig zoo.Iodotrimethylsilane yog siv rau kev qhia txog trimethylsilyl pawg hauv cov organic synthesis.Nws kuj tseem muaj txiaj ntsig zoo rau kev tshuaj ntsuam xyuas roj chromatography los ntawm kev hloov cawv rau hauv silyl ether derivative, yog li ua rau nws hloov pauv ntau dua li qub molecule.Iodotrimethylsilane yog ib qho reagent zoo rau ether, ester, carbamate, ketal, thiab lactone cleavage.Rau kev qhia txog TMS pawg, xws li TMS enol ethers.Qhov tseem ceeb reagent rau kev xaiv deprotection ntawm ib pawg N-Cbz nyob rau hauv lub xub ntiag ntawm ib tug trimethyltin moiety.Reagent tsis ntev los no tau tshaj tawm los hloov allyl- thiab benzylphosphotriesters rau cov iodides sib xws.Iodotrimethylsilane yog ib tug raug thaiv tus neeg sawv cev nyob rau hauv kev tsim tshuaj, dav siv nyob rau hauv lub syntheses ntawm tshuaj.Nws tuaj yeem tiv thaiv lossis tiv thaiv cov pab pawg ua haujlwm xaiv, ua raws li silane thaiv tus neeg sawv cev.Iodotrimethylsilane yog ib qho khoom siv ntau yam reagent siv nyob rau hauv ntau yam kev cuam tshuam cov organic.Nws yog siv rau kev sib txuas ntawm ob peb lub tebchaw xws li lactones, ethers, acetals, thiab carbamates thiab trimethylsilylating tus neeg sawv cev rau kev sib txuas ntawm silyl imino esters, alkyl thiab alkenyl silanes, thiab lwm yam. Nws kuj ua raws li Lewis acid catalyst thiab ua tus neeg saib xyuas hauv ntau cov tshuaj tiv thaiv organic.Iodotrimethylsilane tuaj yeem siv los ua ntau yam reagent rau me me dealkylation ntawm ethers, carboxylic esters, lactones, carbamates, acetals, phosphonate thiab phosphate esters;cleavage ntawm epoxides, cyclopropyl ketones;hloov vinyl phosphates rau vinyl iodides;nruab nrab nucleophilic reagent rau halogen pauv cov tshuaj tiv thaiv, carbonyl thiab conjugate ntxiv cov tshuaj tiv thaiv;siv los ua tus neeg sawv cev trimethylsilylating rau kev tsim ntawm enol ethers, silyl imino esters, thiab N-silylenamines, alkyl, alkenyl thiab alkynyl silanes;Lewis acid catalyst rau acetal tsim, α- alkoxymethylation ntawm ketones, rau cov tshuaj tiv thaiv ntawm acetals nrog silyl enol ethers thiab allylsilanes;txo tus neeg sawv cev rau epoxides, enediones, α-ketols, sulfoxides, thiab sulfonyl halides;dehydrating tus neeg sawv cev rau oximes.