(S)-(-)-BINAP CAS 76189-56-5 Purity ≥99.0% (HPLC) EE ≥99.0% Hoobkas

(S)-(-)-BINAP (CAS: 76189-56-5), yog ib qho organic phosphine compound thiab muaj txiaj ntsig zoo li chiral catalyst thiab kws tshuaj nruab nrab.Chiral ligand rau hlau mediated asymmetric catalysis.
2,2′-Bis (diphenylphosphino)-1,1′-Binaphthyl thiab nws cov rhodium thiab ruthenium derivatives yuav siv tau raws li ib tug heev xaiv homogeneous catalysts rau txo cov aryl ketones, β-ketoesters thiab α-aminoketones.Nws kuj tuaj yeem siv rau hauv asymmetric hydrogenation thiab hydroformylation cov tshuaj tiv thaiv ntawm olefins, asymmetric Heck cov tshuaj tiv thaiv thiab asymmetric isomerization cov tshuaj tiv thaiv ntawm pawg allyl.
Kev tshwm sim
Ligand ua haujlwm hauv palladium-catalyzed asymmetric arylation ntawm ketones.
Ligand ua haujlwm hauv rhodium-catalyzed 1,4-ntxiv rau enones.
Ligand ua haujlwm hauv palladium-catalyzed hydroamination ntawm styrene derivatives.
Ligand ua haujlwm hauv cov nyiaj-catalyzed asymmetric Sakuri-Hosomi allylation thiab Mukaiyama aldol cov tshuaj tiv thaiv.
Ligand ua haujlwm hauv rhodium-catalyzed kinetic daws teeb meem ntawm enynes.
Ligand ua haujlwm hauv asymmetric rhodium-catalyzed hydroboration ntawm cyclopropenes.
Ligand ua haujlwm hauv silver-catalyzed a-hydroxylation ntawm stannyl enol ethers.
Ligand ua haujlwm hauv palladium-catalyzed synthesis ntawm chiral allenes.
Siv Reactant koom nrog hauv:
Enantioselective thiab diastereoselective unpoled carbonyl allylation
Syntehsis ntawm organophine oxides ua cov tshuaj tua kab mob
SN2 halogenation ntawm hydroxy pawg
Synthesis ntawm BINAP complexes
Kev tshawb fawb ntawm conformational yooj ntawm BINAP chelates