TBDMSCl CAS 18162-48-6 tert-Butyldimethylsilyl Chloride Purity > 99.5% (GC) Hoobkas
Shanghai Ruifu Chemical Co., Ltd. yog cov chaw tsim khoom thiab cov chaw muag khoom ntawm tert-Butyldimethylsilyl Chloride (TBDMSCl) (CAS: 18162-48-6) nrog cov khoom zoo, muaj peev xwm ntau lawm 1400 tons hauv ib xyoos.Ruifu tuaj yeem muab kev xa khoom thoob ntiaj teb, tus nqi sib tw, me me thiab ntau ntau muaj.Yuav TBDMSCl, Please contact: alvin@ruifuchem.com
Tshuaj npe | tert-Butyldimethylsilyl Chloride |
Synonyms | TBDMSCl;TBDMS-Cl;TBSCL;TBS-Cl;tert-Butyldimethylchlorosilane;tert-Butylchlorodimethylsilane;Chlorodimethyl-tert-butylsilane;tert-Butyl (dimethyl) silane Chloride;Chloro-tert-Butyldimethyl-Silane |
CAS Nr | 18162-48-6 |
Tshuag xwm txheej | Hauv Tshuag, Kev Tsim Khoom Loj |
Molecular Formula | C6H15ClSi |
Molecular Luj | 150.72 Nws |
Melting Point | 86.0 ~ 90.0 ℃ (lit.) |
Boiling Point | 124.0 ~ 126.0 ℃ @ 760mmHg |
Qhov ntom | 0.87 g / mL ntawm 20 ℃ (lit.) |
Refractive Index | N20/D 1.46 |
rhiab heev | Moisture Sensitive |
Solubility | Soluble hauv Dichloromethane, Ether, Toluene, Benzene |
Cia Temp. | Txias thiab qhuav (≤10 ℃) |
COA & MSDS | Muaj |
Hom | Ruifu Tshuaj |
Yam khoom | Specifications |
Qhov tshwm sim | Dawb Crystalline hmoov |
Purity / Analysis Method | > 99.5% (GC) |
Melting Point | 86.0 ~ 90.0 ℃ |
T-Butyldimethylsilanol | <0.30% (GC) |
Proton NMR Spectrum | Raws li tus qauv |
Solubility hauv CHCL3 | Tsis muaj xim, Ntshiab, 25mg / ml Pass |
Nco ntsoov | Moisture rhiab heev.Tiv thaiv los ntawm lub teeb thiab Khaws rau hauv qhov chaw qhuav qhuav (≤10 ℃) |
Test Standard | Enterprise Standard |
Pob:Lub raj mis, Aluminium ntawv ci hnab, 25kg / Cardboard Nruas, los yog raws li tus neeg yuav tsum tau muaj.
Cia txias:Moisture rhiab heev.Khaws rau hauv cov thawv ntim khoom ntawm qhov txias thiab qhuav (≤10 ℃) warehouse kom deb ntawm cov khoom tsis sib xws.Tiv thaiv los ntawm lub teeb thiab noo noo.
Shipping:Xa mus thoob ntiaj teb los ntawm FedEx / DHL Express.Muab kev xa khoom sai thiab txhim khu kev qha.
Risk Codes
R22 - Ua phem yog tias nqos
R35 - Ua rau kub hnyiab heev
R40 - Cov pov thawj txwv ntawm cov nyhuv carcinogenic
R34 - Ua rau kub hnyiab
R10 - Flammable
R19 - Tej zaum yuav tsim cov peroxides tawg
R11 - Cov nplaim hluav taws kub heev
R67 - Vapors tuaj yeem ua rau qaug zog thiab kiv taub hau
R65 - Ua phem: Tej zaum yuav ua rau lub ntsws puas yog tias nqos
R63 - Muaj peev xwm tsim kev puas tsuaj rau tus menyuam hauv plab
R48/20 -
R20/21/22 - Ua phem los ntawm kev nqus pa, tiv tauj nrog daim tawv nqaij thiab yog tias nqos.
R45 - Tej zaum yuav ua rau mob qog noj ntshav
R23/24/25 - Toxic los ntawm kev nqus pa, tiv tauj nrog daim tawv nqaij thiab yog tias nqos.
R37 - Ua rau khaus ua pa
R36/37/38 - Kab mob rau qhov muag, ua pa thiab tawv nqaij.
Kev nyab xeeb piav qhia
S26 - Nyob rau hauv rooj plaub ntawm qhov muag, yaug tam sim ntawd nrog dej txaus thiab nrhiav kev kho mob.
S36/37/39 - Hnav cov khaub ncaws tiv thaiv, hnab looj tes thiab tiv thaiv qhov muag / ntsej muag.
S46 - Yog tias nqos tau, nrhiav kev kho mob tam sim ntawd thiab qhia lub thawv lossis daim ntawv lo.
S62 - Yog tias nqos tau, tsis txhob ntuav ntuav;nrhiav kev kho mob tam sim ntawd thiab qhia lub thawv los yog daim ntawv lo.
S45 - Thaum muaj xwm txheej lossis yog tias koj tsis xis nyob, nrhiav kev kho mob tam sim ntawd (qhia daim ntawv lo thaum twg los tau.)
S25 - Tsis txhob sib cuag nrog lub qhov muag.
S16 - Khaws kom deb ntawm qhov chaw hluav taws xob.
S28 - Tom qab sib cuag nrog daim tawv nqaij, ntxuav tam sim ntawd nrog xab npum-suds ntau.
S27 - Tshem tawm tag nrho cov khaub ncaws tsis huv tam sim ntawd.
S33 - Siv cov kev tiv thaiv kev tiv thaiv zoo li qub.
S29 - Tsis txhob muab tso rau hauv qhov dej.
S53 - Tsis txhob raug - tau txais cov lus qhia tshwj xeeb ua ntej siv.
S36/37 - Hnav cov khaub ncaws tiv thaiv thiab hnab looj tes tsim nyog.
UN IDs UN 2925 4.1/PG 2
WGK Germany 2
RTECS VV2000000
FLUKA BRAND F CODE 10-21
TSCA Yes
HS Code 2931900090
Hazard Note Flammable / Corrosive / Moisture Sensitive
Hazard Chav Kawm 4.1
Packing Group III
tert-Butyldimethylsilyl Chloride (TBDMSCl) (CAS: 18162-48-6) yog ib qho organosilicon compound uas tuaj yeem siv los ua ntau yam kev tiv thaiv reagent rau cawv, amines, amides, thiab ntau yam carboxylic acids.tert-Butyldimethylsilyl Chloride yog ib yam tshuaj siv los tiv thaiv cawv thaum lub sij hawm cov organic synthesis.Nws ua raws li ntau yam kev tiv thaiv reagent rau amines, amides thiab cawv.
TBDMSCl yog ib tug sterically hindered organosilicon tiv thaiv tus neeg saib xyuas, uas yog dav siv nyob rau hauv lub synthesis ntawm thawj cov tshuaj.Nws yog siv los ua pab pawg tiv thaiv hydroxyl hauv kev sib txuas ntawm ribonucleosides, thiab tseem yog oxidant thiab decyanide.
Cov khoom siv raw khoom siv rau kev sib txuas ntawm prostaglandins, qee yam tshuaj tua kab mob, tshuaj hypolipidemic lovastatin thiab simvastatin siv los ua cov tshuaj nruab nrab thiab siv hauv cov organic synthesis, ua hydroxyl tiv thaiv tus neeg sawv cev hauv cov khoom siv hluavtaws siv hauv cov tshuaj intermediates thiab cov organic synthesis, yog cov tshuaj tiv thaiv kev tiv thaiv silicone. , dav siv nyob rau hauv lub synthesis ntawm thawj cov tshuaj.Nws yog siv los ua pab pawg tiv thaiv rau pawg hydroxyl hauv kev sib txuas ntawm ribonucleosides, thiab kuj yog ib qho oxidant thiab decyanating tus neeg sawv cev.silanizer.Raws li hydroxyl tiv thaiv tus neeg sawv cev hauv cov organic synthesis, derivatization reagents yog siv rau kev tshuaj xyuas thiab kev npaj.Tiv thaiv tertiary alcohols.Reacts nrog cawv los ua silicone ether.Kev txiav txim siab ntawm kev sib haum xeeb ntawm cov roj cholesterol derivatives.
Txhais CHEBI: Tert-butyldimethylsilyl chloride yog silyl chloride uas muaj lub hauv paus silicon atom covalently khi rau ib chloro, ib tug tert-butyl thiab ob pawg methyl.tert-Butyldimethylsilyl chloride yog ib tug derivatisation tus neeg sawv cev siv nyob rau hauv cov roj chromatography/mass spectrometry daim ntaub ntawv.Nws muaj lub luag haujlwm ua chromatographic reagent.
tert-Butyldimethylsilyl Chloride (TBDMSCl) (CAS: 18162-48-6) tau tsim los ntawm cov tshuaj tiv thaiv ntawm tert-butyllithium nrog dichlorodimethylsilane.
Cov tshuaj pentane ntawm dichlorodimethylsilane tau txias rau 0 ℃, thiab cov tshuaj pentane ntawm tert-butyllithium ntxiv dropwise nrog nplawm hauv qab nitrogen.Qhov ntsuas kub tau khaws cia ntawm 0 ℃, nplawm rau 1.5 teev thiab tom qab ntawd rhaub rau 25 ℃, thiab cov tshuaj tiv thaiv txuas ntxiv rau 48 teev.Distillation, sau 125 ℃ (97.5kPa) feem, sawv ntsug kom khov, thiab tau txais tert-butyldimethylsilyl chloride.Yield 70%.