(S)-(-)-2-Methyl-CBS-Oxazaborolidine;(S)-Me-CBS Catalyst CAS 112022-81-8 Ụlọ ọrụ
Aha Chemical | (S)-(-)-2-Methyl-CBS-Oxazaborolidine (ihe dị ka 1mol/L na Toluene) |
Ụdị okwu | (S)-Me-CBS Catalyst;(S) -2-Methyl-CBS-Oxazaborolidine;(S) -5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine.(ihe dị ka 1 mol/L na Toluene) |
Nọmba CAS | 112022-81-8 |
Nọmba CAT | RF-CC106 |
Ọnọdụ Ahịa | N'ọkwa, Mpụta Ihe ruru Tọn |
Usoro ihe omimi | C18H20BNO |
Ibu molekụla | 277.17 |
Ụlọ ahịa n'okpuru Inert gas | Ụlọ ahịa n'okpuru Inert gas |
Ọnọdụ Ịzere | Mmiri nwere mmetụta |
Ebe Na-agbaze | 85 ~ 95 ℃ (ọkụ) |
Ebe esi nri | 111 ℃ |
Njupụta | 0.93 g/ml na 20 ℃ |
Ụdị | Ruifu Chemical |
Ihe | Nkọwapụta |
Ọdịdị | Mmiri mmiri na-acha odo odo na-enweghị agba |
njirimara | 1H NMR, IR |
Ntinye uche na Tol | 1 mol/L |
Nyocha | 28.5 ~ 31.5% |
Nlele ọkọlọtọ | Standardkpụrụ ụlọ ọrụ |
Ojiji | Ndị na-emepụta CBS |
ngwugwu: Kalama, Barrel, 25kg / gbọmgbọm, ma ọ bụ dị ka ndị ahịa chọrọ.
Ọnọdụ Nchekwa:Na-echekwa n'ime akpa ndị a kpuchiri ekpuchi na ebe dị jụụ na nke kpọrọ nkụ;Chebe site na ọkụ, mmiri mmiri na ụmụ ahụhụ.
Onye nrụpụta;Ogo dị elu na ọnụ ahịa asọmpi
CBS Catalyst
(S)-(-)-2-Methyl-CBS-Oxazaborolidine;(S)-Me-CBS Catalyst (ihe dị ka 1mol/L na Toluene);Nọmba: 112022-81-8
(R)-(+) -2-Methyl-CBS-Oxazaborolidine;(R) - Me-CBS Catalyst (ihe dị ka 1mol / L na Toluene);Nọmba ekwentị: 112022-83-0
(S)-(-)-2-Methyl-CBS-Oxazaborolidine (CAS 112022-81-8), bụ oxazaborolidine catalyst, ihe na-akpata chiral nke a na-eji na mmeghachi omume kemịkal, a na-ejikarị ya na mbelata asymmetric nke ketones prochiral.Ngwa ndị ọzọ gụnyere njikọ enantioselective nke α-hydroxy acid, α-amino acid, C2-symmetrical ferrocenyl diols, na propargyl alcohols.
(S)-(-)-2-Methyl-CBS-Oxazaborolidine (CAS 112022-81-8) Mmeghachi omume
Ihe mkpali dị mma maka mbelata borane enantioselective nke ketone n'oge okpomọkụ.
Ngwakọta asymmetric nke α-chiral hydroxyalkylphosphines site na mbelata ike nke acylphosphines na-enye ike.
Nickel-catalyzed cross-couplings nke benzylic pivalates na arylboroxines: Stereospecific nhazi nke diarylalkanes na triarylmethane.
Mbelata nke ketones prochiral na NaBH4/Me2SO4/(S) -Me-CBS.