1,1′-Bis(diphenylphosphino)ferrocene CAS 12150-46-8 DPPF Kemurnian >98,0% Fe 9,7~10,4%
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Jeneng Kimia | 1,1'-Bis(diphenylphosphino)ferrocene |
sinonim | 1,1'-Ferrocenebis(diphenylphosphine);DPPF |
Nomer CAS | 12150-46-8 |
Nomer CAT | RF-PI2275 |
Status Simpenan | Ing Simpenan, Skala Produksi Nganti Ton |
Formula Molekul | C34H28FeP2 |
Bobot Molekul | 554.39 |
Sensitif | Sensitif Udara |
Kelarutan ing banyu | Ora larut ing banyu |
Kelarutan | Larut ing Kloroform |
Sensitivitas Hidrolitik | 7: Reaksi alon-alon karo Kelembapan/Banyu |
Merk | Kimia Ruifu |
Item | Spesifikasi |
Penampilan | Bubuk Kuning nganti Oranye |
Kemurnian / Metode Analisis | >98,0% (Titrasi Kèlometri) |
Besi (Fe) | 9,7~10,4% (Titrasi kanthi Na2S2O3) |
Karbon kanthi Analisis Unsur | 71,1-76,2% |
Titik Lebur | 181.0~183.0 ℃ |
Banyu dening Karl Fischer | <0,50% |
Kelarutan ing CHCL3 | Kuning nganti Oranye, Clear (2,5%) Pass |
Spektrum Infrared | Conforms kanggo Struktur |
Test Standar | Standar Perusahaan |
Paket: Botol, tas Aluminium foil, 25kg / Karton Drum, utawa miturut kabutuhan pelanggan
Kondisi panyimpenan:Simpen ing wadhah sing disegel ing papan sing adhem lan garing;Nglindhungi saka cahya lan Kelembapan
1,1'-Bis(diphenylphosphino)ferrocene (CAS: 12150-46-8), Suzuki-Miyaura Cross Coupling Reaksi, Ligan, Katalis Metalik Organik.Umumé digunakake ing reaksi kimia ing ngisor iki yaiku Buchwald-Hartwig Cross Coupling Reaction, Carbonylations, Ene Reaction, Heck Reaction, Negishi Coupling, Sonogashira Coupling, Stille Coupling, Suzuki-Miyaura Coupling, Tsuji-Trost Reaction.Aplikasi Senyawa koordinasi sing umum digunakake ing sintesis, gampang mbentuk kompleks karo macem-macem logam, yaiku nalika bereaksi karo kompleks asetonitril utawa benzonitril saka PdCl2 sing dibentuk (dppf)PdCl2, yaiku reagen populer kanggo reaksi kopling katalis paladium.Turunan furan fungsional novel disiapake liwat pembentukan ikatan Pd-phosphine sekuensial CC lan CO.Ligan digunakake ing Pd(II) -catalyzed cross-coupling sintesis saka sistem ring oxazepine.1,1'-Bis(diphenylphosphino)ferrocene tumindak minangka ligan ing katalisis homogen.Iki digunakake minangka ligan kanggo sintesis amina ijo sing dikatalisis ruthenium saka amina lan alkohol kanthi peminjaman hidrogen.Iki uga digunakake minangka ligan kanggo kopling silang Buchwald-Hartwig.Kajaba iku, digunakake ing sintesis senyawa koordinasi uga pambentukan kompleks karo macem-macem logam kayata paladium klorida.Kajaba iku, iku minangka reagen kanggo reaksi kopling palladium-catalyzed lan uga nduweni peran penting ing reaksi Suzuki.