S)-(-)-TolBINAP CAS 100165-88-6 Puritas >98.0% (HPLC)
Shanghai Ruifu Chemical Co., Ltd. est primarium fabrica (S)-(-)-TolBINAP (CAS: 100165-88-6) cum qualitate alta.Ruifu Chemical traditio totius terrarum, quantitatis competitive pretium, optimum servitium, parvas et moles in promptu habere potest.Purchase (S)-(-)-TolBINAP,Please contact: alvin@ruifuchem.com
| Nomen chemicum | (S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl |
| Synonyma | (S)-(-)-TolBINAP(S)-Tol-BINAP;(S)-T-BINAP;(S)-Tol-BINA;(-)-Tol-BINA;(-)-Tol-BINAP |
| Stock Status | In Stock, Commercial Productio |
| CAS Number | 100165-88-6 |
| Formulae hypotheticae | C48H40P2 |
| M. Pondus | 678.80 g/mol |
| Liquescens punctum | 252.0~ 259.0℃ |
| Sensitiva | Air Sensitiva.Copia sub Inert Gas |
| Aqua Solubility | Insolubilis in aqua |
| COA & MSDS | Praesto |
| Product Categories | Ligandes;Chiral Ligands |
| Origin | Shanghai, China |
| Brand | Ruifu Chemical |
| Items | Specifications | Proventus |
| Aspectus | Alba ad Off-White pulveris | Alba pulveris |
| Liquescens punctum | 252.0~ 259.0℃ | 256.9℃ |
| Puritas / Analysis Methodus | >98.0% (HPLC) | 98.5% |
| Puritas / Analysis Methodus | 97.5~ 102.5% (Titratio Neutralisation) | Obsequitur |
| Puritas optica (ee) | >99.0% (HPLC) | 99.2% |
| Imprimis Rotationes [a]20/D | -167.0°~-157.0° (C=1.052, Benzene) | -158.7° |
| Infrared Spectrometria | Congruunt Structure | Obsequitur |
| 1H NMR Imaginum | Congruunt Structure | Obsequitur |
| conclusio | Productum probatum est et cum datis specificationibus obsequitur | |
Sarcina:Fluorinated Utrem, aluminium ffoyle, 25kg/cardboard Drum, vel secundum exigentiam emptoris.
Repono Condition:Continentem arcte clausam et in frigido, sicco et bene ventilato horreis a substantiis incompossibilibus repone.A luce et humore protege.
Naviportans:Libera ad mundum ab aere, per FedEx / DHL Express.Ieiunium et certas traditiones provide.
Quam mercari?Quaeso contactumDr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com
15 Years Experience?Plus quam XV annos experientiae habemus in fabricando et exportando amplis intermediis pharmaceuticis vel alchimicis pharmaceuticis amplis.
Mercatus principalis?Vendere mercatum domesticum, Americam septentrionalem, Europam, Indiam, Coream, Iaponicam, Australiam etc.
Commodi?Superior qualitas, parabilis pretium, officia professionalia et subsidia technica, ieiunium partus.
Qualitasfides?Qualitas strictioris temperantiae ratio.Pro instrumento analysi professionali includuntur NMR, LC-MS, GC, HPLC, ICP-MS, UV, IR, OR, KF, ROI, LOD, MP, Claritas, Solubilitas, Microbialis limes test, etc.
Exempla?Pleraque producta praebent exempla gratuita pro qualitate aestimationis, sumptus naviculas a clientibus solvendos.
Factory Audit?Factory audit gratissimum.Quaeso ante constitutum.
MOQ?Nec MOQ.Parvus ordo placet.
Tempus adferendi? Si intus prosapia, tres dies partus praestatur.
Transportatio?Per Express (FedEx, DHL), ab Air, per Mare.
Documenta?Post servitium venditionis: COA, MOA, ROS, MSDS, etc. praeberi possunt.
Consuetudo Synthesis?Consuetudo synthesis officia praebere potest ad optimas investigationes tuas necessitates aptandas.
Pensio conditio?Proforma cautionis primum post confirmationem ordinis mittetur, informationes nostrae ripae inclusas.Payment by T/T (Telex Transfer), PayPal, Western Union, etc.
Periculum Codes
36/37/38 - Irritando ad oculos, systema respiratorium et cutem.
Salus Descriptio
S26 - In contactu cum oculis, statim cum aqua multa ablue et consilium medicinae quaeras.
S36/37/39 - Indumentum tutelae idoneum, caestus et oculi/facies tutelam gerunt.
WGK Germania 3
TSCA No
HS Codicis 2931900090
(S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl((S)-(-)-TolBINAP) (CAS: 100165-88-6) Reactio
Utile ligando ad palladium-catalyticum vinculi formationis carbonis oxygeni.
Ligand pro palladium catalysatum α-arylation of ketonum.
Ligandum pro reductione conjugata asymmetrica Cu-catalyzed.
Ligand pro Cu-catalysis asymmetricis dienolatis additis ad aldehydes.
Reductio coniugata lactonum et lactams enantioselectiva.
Ligand usus est in cycloadditione enantioselectiva allenylsilanarum cum α-Imino esters.
Catalytic Aldol reaction to ketones.
Ligandum cum catalysibus rhodii [2+2+2] cycloadditionum reactionem alkenum et alkynorum.
Ligandi usus in iridi-catalytico enantioselectivo CH ligamenti activo 2-(alkylamino) -pyridine cum alkenis.
Iridium catalyzed regio-, diastereo-, et enantioselectivum tert- (hydroxyl) -prenylation alcoholum.
Rhodium-catalyzed crucis cyclotrimerizationis.
(S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl ((S)-(-)-TolBINAP) (CAS: 100165-88-6) chiral. ligand late in synthesi asymmetrica usus est.Etiam catalysts praestantibus usus est ad hydrogenationem asymmetricam alkenum et quaedam cyclica anhydrida.BINAP in synthesi organica adhibetur pro enantioselectivis transmutationibus catalyzis ab complexionibus ruthenii, rhodii et palladii.
(S)-(-)-TolBINAP reagit cum nitrato argenteo ad formandum (S)-Tol-BINAP·AgNO3, quod alligatio enantioselectivam aldehydae reactionem enantiopuram secundarum alcoholorum formare potest.Adhiberi potest ut ligandi chiralis in palladio catalysed asymmetrica duplex carbohydroaminatio iodoarenorum ad formandum α-aminoamides.Potest etiam catalysin asymmetricam N-allylationem reactionem derivationum ortho-tert-butylanilides cum carbonate diallyli ad formandum chiralos N-allyl ortho-tert-butylanilides.
