Potassium Bis (trimethylsilyl) inter CAS 40949-94-8 (0.5M Solutio in Toluene)
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Nomen chemicum | Potassium Bis (trimethylsilyl)amide |
Synonyma | Hexamethyldisilazane Potassium Salt;Potassium Hexamethyldisilazane;KHMDS |
CAS Number | 40949-94-8 |
CATTUS Number | RF-PI2227 |
Stock Status | In Stock, Productio Ascendite ad Tons |
Formulae hypotheticae | C6H18KNSi2 |
M. Pondus | 199.49 |
Ferveret | 111℃ |
Density | 0.877 g/mL ad 25℃ |
Periculum Classis | 3 (8);Flammabiles Liquid, Corrosive |
Stipare Group | II |
Solubilitas | Miscuntur cum Terahydrofuran, Aether, Benzene et Toluene . |
Aqua Solubility | Reacts Cum aqua |
Hydrolytic Sensibilitas | 8: Raptim Reacts cum umore, aqua, pProtic Solvents |
Stabilitas | Humor Sensitivus, Aeris Sensitivus, Calor Sensitivus.Store Sub Nitrogen.Praecipitatum formare potest.Ambiens Temperaturae. |
salus | Ancipitia-An Additional Periculo bona ONERARIUS præcipe Maii Applicare |
Brand | Ruifu Chemical |
Item | Specifications |
Aspectus | Flavo ad Brown Liquid |
Aliae immunitates | ≤3.00% |
Contentus Active Base | 0.45~0.55 M |
Test Standard | Enterprise Standard |
sarcina:Utrem, vel ex adipiscing elit.
Repono Condition:Sensus est humidi et aeris.Repono in loco refrigerio.Continentiam arcte clausam in loco sicco et bene ventilato.Vasa quae aperta sunt, diligenter aperiri debent et recti conservari ne ultrices.Palpate et reponunt sub iners gas.Agentibus oxidizing fortis repugnat.
Aleam Denunciationes:Liquoris flammabilis et vapor valde.Gravis cutis urit et oculorum molestiam.Grave damnum oculi causat.Suspecta de damno fertilitatis vel de foetibus.Sit causare damnum ad organa per longum seu iteratum patefacio.Sit facere vel vertiginis.
Potassium Bis (trimethylsilyl) inter (0.5M Solutio in Toluene) (vulgo abbreviata pro KHMDS) (CAS: 40949-94-8) valida, non-nucleophilica basis cum approximata pKa 26 (conpara lithium diisopropylamide, ad 36 ).Commercium in promptu est ut solida et solutio in variis solventibus (ex. THF, 2Me-THF, toluene, et MTBE).Similes regentes includunt lithium bis (trimethylsilyl)amide (LiHMDS) et sodium bis (trimethylsilyl)amide (NaHMDS).Basis megasterica non-nucleophilica fortis.Media pharmaceutica, adhibita in productione synthetica cephalosporins.KHMDSest chemica reagens usus est in praeparativo summus perficientur liquido chromatographia.Adhibetur complexiones stabiles cum kalium formare, quae tunc a columna separantur.KHMDS usus est etiam in investigationibus diamemicis et ut synthesis asymmetrica catalyst.KHMDS est basis fortis in compositis carbonyl alkylation.KHMDS adhibetur in praeparatione 5-Azacytidine, medicamento antineoplastico.Adhibetur etiam in praeparatione β3-AR agonistarum adhibitarum in anti- vis formularum.Usurpatur etiam ut gerens in complexionibus lanthaniderum praeparandis adhibitis in reactiones selectivae cyclizationis.