TBDMSCl CAS 18162-48-6 tert-Butyldimethylsilyl Chloride Purity >99.5% (GC) Factory

Description:

tert-Butyldimethylsilyl Chloride

Synonyma: TBDMSCl

CAS: 18162-48-6

Puritas: >99.5% (GC)

Aspectus: Crystallinus Powder Alba

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E-Mail: alvin@ruifuchem.com


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Descriptio:

Shanghai Ruifu Chemical Co., Ltd. est primarium fabricae et supplementi tert-Butyldimethylsilyl Chloride (TBDMSCl) (CAS: 18162-48-6) magna qualitate, capacitate productionis 1400 talentorum per annum.Ruifu partus terrarum, quantitatis competitive pretium, parvas et parvas quantitates in promptu habere potest.Purchase TBDMSCl, Please contact: alvin@ruifuchem.com 

Chemical Properties:

Nomen chemicum tert-Butyldimethylsilyl Chloride
Synonyma TBDMSCl;TBDMS-Cl;TBSCl;TBS-Cl;tert-Butyldimethylchlorosilane;tert-Butylchlorodimethylsilane;Chlorodimethyl-tert-butylsilane;tert-Butyl (dimethyl) silane Chloride;Chloro-tert-Butyldimethyl-Silane
CAS Number 18162-48-6
Stock Status In Stock, Massa Productio
Formulae hypotheticae C6H15ClSi
M. Pondus 150.72
Liquescens punctum 86.0~90.0℃(lit.)
Ferveret 124.0~12.0℃ @ 760mmHg
Density 0.87 g/mL in 20℃(lit.)
Index refractivus n20/D 1.46
Sensitiva umorem Sensitivum
Solubilitas Solutum in Dichloromethane, Aether, Toluene, Benzene
Repono Nativ. Frigidus et siccus (≤10)
COA & MSDS Praesto
Brand Ruifu Chemical

Specifications:

Item Specifications
Aspectus Crystallina pulveris alba
Puritas / Analysis Methodus >99.5% (GC)
Liquescens punctum 86.0~90.0
T-Butyldimethylsilanol <0.30% (GC)
Proton NMR Spectrum Conformat ut Structure
Solubilitas in CHCL3 Hyalina, Serena, 25mg/ml Pass
Operam Humorem sensitivum.Protege a luce et Store in loco frigido (≤10℃)
Test Standard Enterprise Standard

Sarcina & Repono:

Sarcina:Utrem, aluminium foil, sacculum, 25kg/cardboard Drum, vel secundum exigentiam emptoris.
Repono Condition:Humorem sensitivum.Condite in vasis obsignatis apud frigus et siccum (≤10℃) horreum ab substantiis incompossibilibus.A luce et humore protege.
Naviportans:Libera ad orbem terrarum per FedEx / DHL Express.Ieiunium et certas traditiones provide.

commoda:

1

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18162-48-6 - Periculum et Salus;

Periculum Codes
R22 - noxia absorptus
R35 - Causis gravibus urit
R40 - argumentum limitata carcinogenici effectus
R34 - Causae ardet
R10 - Flammabiles
R19 - Sit formet explosive peroxides
R11 - Flammabiles
R67 - Vapores ut dormitationem et vertiginem faciam
R65 - noxius: Sit causa pulmonis damnum absorptus
R63 - Possibile est periculum nocumentum in nascituro
R48/20 -
R20/21/22 - Inspiratio noxia, in contactu cum cute et absorpta.
R45 - Sit causa cancer
R23/24/25 - Toxicus ab inspiratione, in contactu cum cute et absorptus.
R37 - Irritando ad systema respiratorium
R36/37/38 - Irritando ad oculos, systema respiratorium et cutem.
Salus Descriptio
S26 - In contactu cum oculis, statim cum aqua multa ablue et consilium medicinae quaeras.
S36/37/39 - Indumentum tutelae idoneum, caestus et oculi/facies tutelam gerunt.
S46 - Si absorptus, statim consilium medicinae quaere et hunc vas vel pittacium ostende.
S62 - Si absorbetur, vomitum non inducunt;Quaere consilium medicinae statim et hunc vas vel pittacium ostende.
S45 - In casu casu vel si bene sentis, consilium medicinae statim quaere (titalam quoties fieri potest).
S25 - Fuge contactum cum oculis.
S16 - Ex ignitionis fontibus abstinete.
S28 - Post contactum cutis, statim lava cum copia saponis suds.
S27 - Exue illico omnem vestem contaminatam.
S33 - Cautelae contra statice obit.
S29 - Ne vacuas in cloacas.
S53 - expositionis vitandae - speciales instructiones ante usum obtinendum.
S36/37 - indumentis tutelae idoneis gere et caestus.
UN IDs UN 2925 4.1/PG 2
WGK Germania 2
RTECS VV2000000
FLUKA BRAND F CODES 10-21
TSCA Ita
HS Codicis 2931900090
Aleam Nota Flammabiles / Mordax / umor Sensitiva
Aleam Class 4.1
Stipare Group III

Applicatio:

tert-Butyldimethylsilyl Chloride (TBDMSCl) (CAS: 18162-48-6) est compositum organosilicon quod adhiberi potest versatile servans reagens ad alcohols, amines, amidos et varias acida carboxylicas.Tert-Butyldimethylsilyl Chloride est chemica usus ad alcoholos tutandos in synthesi organica.Agit versatile gerens aminos, amids et alcohols tutans.
TBDMSCl est agentis tutelae organosilicon sterically impeditum, quod late in synthesi medicamentorum originalium adhibetur.Usus est coetus tutelae pro hydroxylo in synthesi ribonucleosidum et etiam oxidantis et decyanidis est.
Materiae rudis auxiliaris ad synthesim prostaglandinorum, antibioticorum quorundam, medicamentorum hypolipidemicorum lovastatin et simvastatin adhibitis intermediis pharmaceuticis et in synthesi organica adhibita, ut hydroxylus tutela agentis in synthesi organica adhibita in mediis medicamentis et synthesi organica, est sterically impeditur agens silicone tutelae. late in synthesi medicamentorum originalium.In synthesi ribonucleosidum uti coetus tutelae pro hydroxylo adhibetur, item agentis oxidantis et decyanantis.silanizer.Ut hydroxylus tutela agens in synthesi organica, derivatio reagentia ad analysin et praeparationem adhibentur.Protege alcoholis tertiariis.Cum alcohols reflectitur ad aetherem silicone formare.Determinatio conformationis cholesteroli derivatorum.
Definitio ChEBI: chloridum Tert-butyldimethylsilyl est chloridum silyllum constans ex atomo pii centrali uni chloro covalenter alligato, tert-butylo uno et duobus yl coetibus.tert-Butyldimethylsilyl chloride derivatio est agens in chromatographia gasi/massa spectrometriae applicationis.Munus habet ut chromatographico gerenti.

Praeparatio:

tert-Butyldimethylsilyl Chloride (TBDMSCl) (CAS: 18162-48-6) summatim per reactionem tert-butyllithii cum dichlorodimethylsilane.
Pentanae solutio dichlorodimethylsilanae ad 0℃ refrigerata est, et pentanea solutio tert-butyllithii addita est guttatim cum nitrogen agitando.Temperatura conservata est in 0℃, commota ad 1.5 h, et tunc calefacta ad 25℃, et continuata est reactio pro 48 h.Distillationem, 125℃ (97.5kPa) fractiones collige, sta solidanda, et chloridem tert-butyldimethylsilyl obtine.LXX% Cedant.

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