(S)-(-)-TolBINAP CAS 100165-88-6 Purity >98.0% (HPLC)
Ko Shanghai Ruifu Chemical Co., Ltd. te kaihanga matua o (S)-(-)-TolBINAP (CAS: 100165-88-6) me te kounga teitei.Ka taea e Ruifu Chemical te tuku i te ao, te utu whakataetae, te ratonga pai, te iti me te rahinga e waatea ana.Hoko (S)-(-)-TolBINAP,Please contact: alvin@ruifuchem.com
| Ingoa matū | (S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl |
| Nga kupu taurite | (S)-(-)-TolBINAP (S)-Tol-BINAP;(S)-T-BINAP;(S)-Tol-BINA;(-)-Tol-BINA;(-)-Tol-BINAP |
| Tūnga Taonga | I roto i te Stock, Production Arumoni |
| Tau CAS | 100165-88-6 |
| Tātai rāpoi | C48H40P2 |
| Taumaha rāpoi | 678.80 g/mol |
| Iwi Whakarewa | 252.0~259.0℃ |
| Tairongo | Te rangi tairongo.Rokiroki i raro i te Hau Inert |
| Wairewa wai | Karekau ki te wai |
| COA & MSDS | Kei te waatea |
| Ngā Kāwai Hua | Nga herenga;Kiroraka Ligands |
| Taketake | Shanghai, Haina |
| Waitohu | Ruifu Chemical |
| Nga taonga | Whakatakotoranga | Hua |
| Te ahua | Ma ki te Paura-White | Paura ma |
| Iwi Whakarewa | 252.0~259.0℃ | 256.9℃ |
| Te Maama / Tikanga Tatauria | >98.0% (HPLC) | 98.5% |
| Te Maama / Tikanga Tatauria | 97.5~102.5% (Te Wetewetetanga) | Ka tutuki |
| Maamaa Optical (ee) | >99.0% (HPLC) | 99.2% |
| Hurihuri Tau [a]20/D | -167.0°~-157.0° (C=1.052, Benzene) | -158.7° |
| Spectrometry Infrared | E rite ana ki te Hanganga | Ka tutuki |
| 1H NMR Spectrum | E rite ana ki te Hanganga | Ka tutuki |
| Whakamutunga | Kua whakamatauria te hua me te whai ki nga whakaritenga kua tohua | |
Mōkī:Pounamu Fluorinated, Peeke pepa konumohe, 25kg / Cardboard Drum, kia rite ranei ki te hiahia a te kaihoko.
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Me pehea te hoko?Whakapā maiDr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com
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MOQ?Kaore he MOQ.Ka whakaaetia te ota iti.
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Waehere Morearea
36/37/38 - He whakapataritari ki nga kanohi, te punaha manawa me te kiri.
Whakaahuatanga Haumaru
S26 - Mena ka pa ki nga kanohi, horoi tonu ki te nui o te wai me te rapu tohutohu hauora.
S36/37/39 - Mau kakahu whakamarumaru tika, karapu me te whakamarumaru kanohi/kanohi.
WGK Tiamana 3
TSCA No
Waehere HS 2931900090
(S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl ((S)-(-)-TolBINAP) (CAS: 100165-88-6) Tauhohenga
Lind whai hua mo te hanga here waro-hauora-palladium-catalyzed.
Ligand mo te palladium-catalyzed α-arylation o ketones.
Ligand mo Cu-catalyzed asymmetric conjugate whakaiti.
Te herenga mo te Cu-catalyzed asymmetric dienolate tāpiritanga ki aldehydes.
Enantioselective conjugate reduction o lactones me lactams.
I whakamahia te Ligand i roto i te cycloaddition enantioselective o allenylsilanes me te α-Imino esters.
Catalytic Aldol tauhohenga ki ketones.
Ko te herenga me te rhodium catalyses [2+2+2] te tauhohenga cycloaddition o te alkenes me te alkynes.
Ligand whakamahia i roto i te iridium-catalyzed enantioselective CH here whakahohenga o 2-(alkylamino)-pyridine ki alkenes.
Iridium-catalyzed regio-, diastereo-, me te enantioselective tert-(hydroxyl)-prenylation o te waipiro.
Rhodium-catalyzed cross cyclotrimerization.
(S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl ((S)-(-)-TolBINAP) (CAS: 100165-88-6) he chiral ka whakamahia nuitia i roto i te whakahiato hangarite.I whakamahia ano hei whakakorikori pai mo te hauwai hangarite o nga alkenes me etahi anhydride hurihanga.Ka whakamahia te BINAP i roto i te whakahiato waro mo nga huringa enantioselective i whakakorikorihia e ona matatini o te ruthenium, rhodium, me te palladium.
(S)-(-)-TolBINAP tauhohe ki te pākawa hiriwa ki te hanga (S)-Tol-BINAP·AgNO3, e taea te whakakōkī i te tauhohenga allylation enantioselective o aldehydes ki te hanga enantiopure waipiro tuarua.Ka taea pea te whakamahi hei riipene chiral i roto i te palladium i whakakorikori i te warowairua asymmetric rua o nga iodoarenes hei hanga α-aminoamides.Ka taea hoki te whakakorikori i te tauhohenga N-allylation hangarite o te ortho-tert-butylanilide derivatives me te diallyl carbonate ki te hanga chiral N-allyl ortho-tert-butylanilides.
