(R)-(+)-1,1′-Bi-2-naphthol CAS 18531-94-7 Assay ≥99.5% (HPLC) ee≥99.5% Te Pure Teitei
Ko te Kaihanga Kaihanga me te Maama me te Kounga Pumau
1,1'-Bi-2-naphthol CAS 602-09-5
(R)-(+)-1,1'-Bi-2-naphthol;(R)-(+)-PINOL;CAS 18531-94-7
(S)-(-)-1,1'-Bi-2-naphthol;(S)-(-)-PINOL;CAS 18531-99-2
(R)-(-)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate;(R)-(-)-BNP Waikawa;CAS 39648-67-4
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate;(S)-(+)-BNP Waikawa;CAS 35193-64-7
Huihuinga Chiral, Kounga Teitei, Hanganga Aromoni
Ingoa matū | (R)-(+)-1,1'-Bi-2-naphthol |
Nga kupu taurite | (R)-(+)-PINOL |
Tau CAS | 18531-94-7 |
Tau CAT | RF-CC216 |
Tūnga Taonga | I roto i te Stock, Production Tauine Up ki Taranata |
Tātai rāpoi | C20H14O2 |
Taumaha rāpoi | 286.32 |
Kiato | 1.301 |
Waitohu | Ruifu Chemical |
Tūemi | Whakatakotoranga |
Te ahua | Paura Tioata Ma |
Ngaronga i te whakamaroke | ≤0.50% |
Iwi Whakarewa | 208.0~210.0 ℃ |
Hurihuri Tau [a]22/D | +34.0° ~ +37.0° (C=1 i roto i te THF) |
Ko te whakamatautau a Chiral | ee ≥99.5% (HPLC) Tīwae Chiral |
Te Whakatau Maama | ≥99.5% (HPLC) |
Paerewa Whakamatau | Paerewa hinonga |
Whakamahinga | Pūhui Hira;Takawaenga Rongoa |
Mōkī: Pounamu, Peeke konumohe konumohe, Paera Kaata, 25kg / Paera, kia rite ranei ki te hiahia a te kaihoko.
Tikanga Rokiroki:Whakaorangia i roto i nga ipu kua hiri ki te waahi makariri me te maroke;Whakaorangia mai i te marama, te makuku me te mate kino.
Ko Shanghai Ruifu Chemical Co., Ltd. te kaihanga matua me te kaiwhakarato o (R)-(+)-1,1'-Bi-2-naphthol (CAS: 18531-94-7) me te kounga teitei, e whakamahia nuitia ana i roto i te waro. te whakahiato, te whakahiatotanga o nga takawaenga rongoa me te whakahiato matū pai.
He mahi nui a Shanghai Ruifu Chemical Co., Ltd. i roto i te matū chiral, e u ana te kamupene ki te hanga i nga pūhui chiral.Ko a maatau hua e whakanuia ana e nga kaihoko.
(R)-(+)-1,1'-Bi-2-naphthol (CAS: 18531-94-7) ka riro mai i te taumira o te BINOL racemic, he mea hanga mai i te 2-naphthol i whakahiatotia e te rino(III) chloride. na roto i te tauhohenga tuwhena.(R)-(+)-1,1'-Bi-2-naphthol kua whakamahia whānuitia mo nga momo tono: 1) nga kai whakakorikori chiral mo te catalytic, tauhohe hangarite penei i te Diels-Alder tauhohenga,ene tauhohenga, hei Lewisacids ranei. ;2) whakaiti enantioselective o ketones;3) te whakahiatotanga o te huringa macro chiral me etahi atu puhui whakamere.He chiral binapthol imminium salt precursor i whakamahia i roto i te catalytic whakahiato hārite o te sulfide ki sulfoxides.Ko nga triflates chiral lanthanide i hangaia mai i te binaphthol hei whakakorikori mo nga tauhohenga asymmetric Diels-Alder.Ko nga hua o te binaphthol katahi ano ka whakamahia i roto i nga whakarereketanga a Claisen hangarite me nga whakapooratanga hangarite.Ko te lithium aluminum hydride derivative o enei diols (BINAP-H) kua whakamahia nui mo te whakaheke i nga ketones.Ka whakamahia i roto i te whakarite biosynthetic mo te oxidation enantioselective o naphthols ki te binaphthyldiols me te horseradish peroxidase catalyst.