4-Dimethylaminopyridine DMAP CAS 1122-58-3 Chiyero> 99.0% (HPLC) Chothandizira Kwambiri
Shanghai Ruifu Chemical Co., Ltd. ndi amene amapanga 4-Dimethylaminopyridine (DMAP) (CAS: 1122-58-3) yokhala ndi khalidwe lapamwamba.Ruifu Chemical imatha kubweretsa padziko lonse lapansi, mtengo wampikisano, zochepa komanso zochulukirapo zomwe zilipo.Gulani DMAP, Please contact: alvin@ruifuchem.com
Dzina la Chemical | 4-Dimethylaminopyridine |
Mawu ofanana ndi mawu | DMAP;4-(Dimethylamino)pyridine;N-(4-Pyridyl) dimethylamine;N, N-Dimethylpyridin-4-Amine;N, N-Dimethyl-4-Pyridinamine;gamma-(Dimethylamino)pyridine |
Nambala ya CAS | 1122-58-3 |
Stock Status | Mu Stock, Mphamvu Yopanga Matani 40 pamwezi |
Molecular Formula | C7H10N2 |
Kulemera kwa Maselo | 122.17 |
Melting Point | 110.0 ~ 114.0 ℃ |
Boiling Point | 190 ℃/150 mmHg |
Kuchulukana | 0.906 g/mL pa 25 ℃ |
Refractive Index | n20/D 1.431 |
Kusungunuka mu Methanol | Kwambiri Faint Turbidity |
Kusungunuka mu Madzi | Zosungunuka mu Madzi, 80 g/l 25 ℃ |
Kusungunuka (Kusungunuka Kwambiri) | Chloroform, benzene, methanol, acetone |
COA & MSDS | Likupezeka |
Mtundu | Ruifu Chemical |
Kanthu | Zofotokozera |
Maonekedwe | Ufa Woyera kapena Woyera wa Crystalline |
Kuyera / Kusanthula Njira | >99.0% (HPLC) |
Melting Point | 110.0 ~ 114.0 ℃ |
Zosasungunuka M'madzi | <0.10% |
Chinyezi (KF) | <0.30% |
Kutaya Pa Kuyanika | <0.50% (Pansi pa Vacumn Kwa Maola 3 Pa 60ºC) |
Chidetso Chimodzi | <0.50% |
Zonse Zonyansa | <1.00% |
Infrared Spectrum | Zogwirizana ndi Kapangidwe |
1 H NMR Spectrum | Zogwirizana ndi Kapangidwe |
Test Standard | Enterprise Standard |
Phukusi:Botolo, Aluminiyamu zojambulazo thumba, 25kg/Cardboard Drum, kapena malinga ndi zofunika kasitomala.
Mkhalidwe Wosungira:Sungani m'mitsuko yosindikizidwa pamalo ozizira komanso owuma (≤10 ℃) kutali ndi zinthu zomwe sizingagwirizane.Tetezani ku kuwala ndi chinyezi.
Manyamulidwe:Kutumiza kudziko lonse lapansi ndi FedEx / DHL Express.Perekani mwamsanga ndi yodalirika yobereka.
1122-58-3 - Zowopsa ndi Chitetezo
Zizindikiro Zowopsa
R25 - Zowopsa ngati zitamezedwa
R34 - Imayambitsa kuyaka
R24/25 -
R36/37/38 - Zokwiyitsa maso, kupuma komanso khungu.
R27 - Ndiwowopsa kwambiri pokhudzana ndi khungu
R36 - Zokhumudwitsa m'maso
R24 - Pokhudzana ndi khungu
R20 - Zowopsa pokoka mpweya
R61 - Zitha kuvulaza mwana wosabadwa
R40 - Umboni wochepa wa zotsatira za carcinogenic
R23/24/25 - Poizoni pokoka mpweya, kukhudzana ndi khungu komanso kumeza.
R67 - Nthunzi zingayambitse kugona ndi chizungulire
R66 - Kuwonekera mobwerezabwereza kungayambitse khungu kuuma kapena kusweka
R21/22 - Zowopsa pokhudzana ndi khungu komanso ngati zitamezedwa.
R11 - Yoyaka Kwambiri
R36/37 - Zokhumudwitsa m'maso ndi kupuma.
R22 - Zowopsa ngati zitamezedwa
R19 - Itha kupanga ma peroxides ophulika
Kufotokozera Zachitetezo
S36/37/39 - Valani zovala zodzitchinjiriza zoyenera, magolovesi ndi chitetezo chamaso/nkhope.
S45 - Pakachitika ngozi kapena ngati simukumva bwino, funsani upangiri wachipatala nthawi yomweyo (onetsani chizindikirocho ngati kuli kotheka.)
S28A -
S26 - Mukakhudzana ndi maso, muzimutsuka nthawi yomweyo ndi madzi ambiri ndipo funsani malangizo achipatala.
S28 - Mukakhudza khungu, sambani nthawi yomweyo ndi sopo wambiri.
S36/37 - Valani zovala zoteteza ndi magolovesi oyenera.
S53 - Pewani kuwonekera - pezani malangizo apadera musanagwiritse ntchito.
S27 - Chotsani nthawi yomweyo zovala zonse zowonongeka.
S22 - Osapumira fumbi.
S16 - Khalani kutali ndi magwero oyatsira.
Ma ID a UN 2811 6.1/PG 2
WGK Germany 3
RTECS US8400000
TSCA T
HS kodi 2942000000
Zowopsa Zowopsa / Zowononga
Kalasi ya ngozi 8
Packing Gulu II
Poizoni LD50 pakamwa pa Kalulu: 140 mg/kg LD50 dermal Kalulu 90 mg/kg
4-Dimethylaminopyridine (DMAP) (CAS: 1122-58-3) ndi chothandizira chatsopano chomwe chimagwiritsidwa ntchito kwambiri popanga mankhwala.Iwo ali mkulu chothandizira mphamvu mu kaphatikizidwe organic, kaphatikizidwe mankhwala, mankhwala, utoto, fungo kaphatikizidwe wa acylation, alkylation, etherification ndi mitundu ina anachita, ndipo ali ndi zotsatira zoonekeratu pa kuwongolera zokolola.Acylation wa mowa;acylation wa phenols;Acylation wa amine;Acylation wa ma enolates;Zochita za isocyanates;Zosiyanasiyana Mapulogalamu;Kusamutsa Magulu Ogwira Ntchito.
DMAP, ndi chothandizira chachikulu cha nucleophilic acylation.Kumveka kwa gulu la electron-donating dimethylamino mu kapangidwe kake ndi mphete ya kholo (pyridine mphete) imatha kuyambitsa atomu ya nayitrogeni pa mpheteyo kuti ilowe m'malo mwa nucleophilic, yomwe imapangitsa kuti kukana kwambiri, mowa wocheperako komanso ma amines / zidulo. acylation/esterification reaction ndi pafupifupi 104 ~ 106 nthawi ya pyridine.Kutengerapo kwa Acyl ndikusintha kofala kwachilengedwe komanso kaphatikizidwe ka organic, momwe chiral DMAP ndi chothandizira chodziwika bwino cha asymmetric acyl transfer.Kuchokera mu 1996, gulu la Vedejs ndi Fu linanena za zothandizira zapakati pa chiral ndi planar DMAP motsatana, zothandizira za DMAP zachiral zapangidwa kwambiri.Zosiyanasiyana zapakati pa chiral, planar chiral, spiro chiral ndi central chiral DMAP zanenedwapo motsatira, ndipo zagwiritsidwa ntchito bwino pamachitidwe ambiri a asymmetric acyl.
DMAP ndi chothandizira kwambiri cha nucleophilic chothandizira ma acylation reaction and esterifications.Amagwiritsidwanso ntchito pakusintha kwachilengedwe kosiyanasiyana monga Baylis-Hillman reaction, Dakin-West reaction, protection of amines, C-acylations, silylations, applications in natural products chemistry, ndi ena ambiri.
DMAP angagwiritsidwe ntchito ngati chothandizira: Pakuti acylation wa mowa ndi asidi anhydrides pansi wothandiza maziko- ndi zosungunulira-free mikhalidwe kupanga lolingana esters.Mu machitidwe a Baylis-Hillman kupanga chomangira cha kaboni-carbon mwa kuphatikiza alkene yolumikizidwa ndi aldehyde kapena ketone.
Chothandizira kwambiri cha ma acylation reaction.