1,1′-Bis(diphenylphosphino)ferrocene CAS 12150-46-8 DPPF Mama >98.0% Fe 9.7~10.4%
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Igoa Vailaau | 1,1'-Bis(diphenylphosphino)ferrocene |
Synonyms | 1,1'-Ferrocenebis(diphenylphosphine);DPPF |
Numera CAS | 12150-46-8 |
CAT Numera | RF-PI2275 |
Tulaga Fa'asoa | I Fa'atauga, Oloa Fua e O'o i Tone |
Fuafua mole | C34H28FeP2 |
Molecular Weight | 554.39 |
Ma'ale'ale | Ea maaleale |
Solubility i le Vai | E le mafai ona solu i le Vai |
Solubility | Solu i le Chloroform |
Maaleale Hydrolytic | 7: Tali lemu ma le susu/vai |
Fa'ailoga | Ruifu Chemical |
Aitema | Fa'amatalaga |
Fa'aaliga | Samasama i moli Pata |
Mama / Suʻesuʻega Metotia | >98.0% (Chelometric Titration) |
Uamea (Fe) | 9.7~10.4% (Titration e Na2S2O3) |
Carbon e ala ile Elemental Analysis | 71.1–76.2% |
Lisi Lisi | 181.0~183.0 ℃ |
Vai saunia e Karl Fischer | <0.50% |
Solubility ile CHCL3 | Samasama i Lanumu, Malamalama(2.5%) Pass |
Alaleo Infrared | E tusa ma le Fauga |
Tulaga Su'ega | Pisinisi Tulaga |
afifi: Fagu, ato pepa alumini, 25kg/Kati Pusa, pe tusa ai ma manaoga o tagata faatau
Tulaga teuina:Teu i totonu o pusa faʻamaufaʻailoga i se nofoaga malulu ma mago;Puipui mai le malamalama ma le susu
1,1'-Bis(diphenylphosphino)ferrocene (CAS: 12150-46-8), Suzuki-Miyaura Cross Coupling Reaction, Ligands, Organic Metallic Catalysts.E masani ona faʻaaogaina i gaioiga faʻasolosolo nei e pei o Buchwald-Hartwig Cross Coupling Reaction, Carbonylations, Ene Reaction, Heck Reaction, Negishi Coupling, Sonogashira Coupling, Stille Coupling, Suzuki-Miyaura Coupling, Tsuji-Trost Reaction.Talosaga E masani ona fa'aogaina fa'amaopoopo fa'atasi i le fa'aputuga, e faigofie ona fai fa'alavelave fa'atasi ma u'amea 'ese'ese, fa'aigoa pe a fa'afeagai ma le acetonitrile po'o le benzonitrile lavelave o le PdCl2 e fau (dppf)PdCl2, ose mea fa'aigoa lauiloa mo tali fa'apipi'i palladium-catalyzed.O mea fou na fa'aaogaina furan na saunia e ala ile Pd-phosphine sequential CC ma CO bond formation.Ligand o loʻo faʻaaogaina i se Pd (II) -faʻapipiʻiina faʻapipiʻi fesoʻotaʻiga faʻapipiʻiina o faiga mama oxazepine.1,1'-Bis(diphenylphosphino)ferrocene galue e pei o se ligand i catalysis homogeneous.O lo'o fa'aaogaina e avea o se ligand mo le fa'ameamea o le amine fa'ameamea o le ruthenium-catalyzed mai amine ma ava malosi e ala i le fa'ameamea o le hydrogen.O loʻo faʻaaogaina foi o se ligand mo Buchwald-Hartwig cross coupling.E le gata i lea, o loʻo faʻaaogaina i le tuʻufaʻatasia o faʻamaopoopo faʻatasi faʻapea foʻi ma le faʻavaeina o faʻalavelave faʻatasi ma metala eseese e pei ole palladium chloride.I le faaopoopo atu i lenei mea, e avea o se reagent mo palladium-catalyzed coupling reactions ma e iai foi sona sao taua i le tali a Suzuki.