(S)-(-)-TolBINAP CAS 100165-88-6 Mama >98.0% (HPLC)
Shanghai Ruifu Chemical Co., Ltd. o le taʻutaʻua taʻutaʻua o (S)-(-)-TolBINAP (CAS: 100165-88-6) faʻatasi ai ma tulaga maualuga.Ruifu Chemical e mafai ona tuʻuina atu i le lalolagi atoa, tau faʻatauvaʻa, auaunaga sili ona lelei, laʻititi ma tele tele o loʻo avanoa.Fa'atau (S)-(-)-TolBINAP,Please contact: alvin@ruifuchem.com
| Igoa Vailaau | (S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl |
| Synonyms | (S)-(-)-TolBINAP (S)-Tol-BINAP;(S)-T-BINAP;(S)-Tol-BINA;(-)-Tol-BINA;(-)-Tol-BINAP |
| Tulaga Fa'asoa | I Fa'atauga, Gaosiga Fa'apisinisi |
| Numera CAS | 100165-88-6 |
| Fuafua mole | C48H40P2 |
| Molecular Weight | 678.80 g/mol |
| Lisi Lisi | 252.0~259.0 ℃ |
| Ma'ale'ale | Ea maaleale.Teu I lalo o Kesi Inert |
| Suavai Solubility | E le mafai ona solu i le Vai |
| COA & MSDS | Avanoa |
| Vaega o oloa | Ligands;Kiral Ligands |
| Amataga | Shanghai, Saina |
| Fa'ailoga | Ruifu Chemical |
| Aitema | Fa'amatalaga | I'uga |
| Fa'aaliga | Pa'epa'e i le Pa'epa'e Pa'epa'e | Pa'u Pa'epa'e |
| Lisi Lisi | 252.0~259.0 ℃ | 256.9℃ |
| Mama / Suʻesuʻega Metotia | >98.0% (HPLC) | 98.5% |
| Mama / Suʻesuʻega Metotia | 97.5~102.5% (Fa'asa'o Fa'a'esea) | E usitaia |
| Mama o mata (ee) | >99.0% (HPLC) | 99.2% |
| Ta'amilosaga Fa'apitoa [a]20/D | -167.0°~-157.0° (C=1.052, Benzene) | -158.7° |
| Infrared Spectrometry | O gatasi ma le Fauga | E usitaia |
| 1H NMR Alaleo | O gatasi ma le Fauga | E usitaia |
| Fa'ai'uga | Ua uma ona fa'ata'ita'iina le oloa ma fa'amalieina fa'atonuga | |
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Tulaga lamatia
36/37/38 - Fa'aitaita'i i mata, faiga fa'alenava ma le pa'u.
Fa'amatalaga Saogalemu
S26 - Pe a pa'i i mata, fufulu vave i le tele o vai ma saili fautuaga faafoma'i.
S36/37/39 - Fai ofu puipui talafeagai, totigilima ma mata/mata.
WGK Siamani 3
TSCA Nu
HS Code 2931900090
(S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl ((S)-(-)-TolBINAP) (CAS: 100165-88-6) Tali
Liga aoga mo le palladium-catalyzed carbon-oxygen bond formation.
Ligand mo palladium-catalyzed α-arylation o ketones.
Ligand mo Cu-catalyzed asymmetric conjugate faaitiitia.
Ligand mo Cu-catalyzed asymmetric dienolate faaopoopo i aldehydes.
Enantioselective conjugate faʻaitiitia o lactones ma lactams.
Ligand faʻaaogaina i le enantioselective cycloaddition o allenylsilanes ma α-Imino esters.
Catalytic Aldol tali atu i ketones.
Ligani fa'atasi ai ma le rhodium fa'ata'ita'i [2+2+2] fa'aoso fa'aopoopo o alkenes ma alkynes.
Ligand faʻaaogaina i le iridium-catalyzed enantioselective CH bond activation o le 2-(alkylamino) -pyridine ma alkenes.
Iridium-catalyzed regio-, diastereo-, ma enantioselective tert-(hydroxyl)-prenylation o ava malosi.
Rhodium-catalyzed cross cyclotrimerization.
(S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl ((S)-(-)-TolBINAP) (CAS: 100165-88-6) o le chiral ligan fa'aaoga lautele i le fa'aa'e tutusa.Na fa'aogaina fo'i e fai ma fa'agāluega e sili ona lelei mo le fa'a-asymmetric hydrogenation o alkenes ma nisi cyclic anhydride.O loʻo faʻaaogaina le BINAP i le faʻaogaina o meaola mo suiga enantioselective e faʻamalosia e ona lavelave o ruthenium, rhodium, ma palladium.
(S)-(-)-TolBINAP tali atu i le nitrate siliva e fai (S)-Tol-BINAP·AgNO3, lea e mafai ona catalyze le enantioselective allylation tali o aldehydes e fausia enantiopure ava malosi lona lua.E mafai ona faʻaaogaina e avea o se ligand chiral i le palladium catalyzed asymmetric double carbohydroamination o iodoarenes e fausia ai α-aminoamides.E mafai fo'i ona fa'atupuina le fa'aogaina o le N-allylation asymmetric ole ortho-tert-butylanilide derivatives ma le diallyl carbonate e fausia ai chiral N-allyl ortho-tert-butylanilides.
