Fmoc-Asp(OtBu)-OH CAS 71989-14-5 Mama >99.0% (HPLC) Falegaosimea
Shanghai Ruifu Chemical Co., Ltd. o le taʻutaʻua taʻutaʻua o le Fmoc-L-Aspartic Acid β-tert-Butyl Ester (Fmoc-Asp(OtBu)-OH) (CAS: 71989-14-5) ma le maualuga.O le Ruifu Chemical e maua mai ai se faasologa o amino acids.E mafai ona matou tuʻuina atu i le lalolagi atoa le tuʻuina atu, tau faʻatauvaʻa, laʻititi ma tele aofaʻi avanoa.Fa'atau Fmoc-Asp(OtBu)-OH,Please contact: alvin@ruifuchem.com
Igoa Vailaau | Fmoc-L-Aspartic Acid β-tert-Butyl Ester |
Synonyms | Fmoc-Asp(OtBu)-OH;Fmoc-L-Asp(OtBu)-OH;N-Fmoc-L-Aspartic Acid 4-tert-Butyl Ester;Fmoc-L-Aspartic Acid beta-tert-Butyl Ester;N-α-Fmoc-L-Aspartic Acid β-tert Butyl Ester;4-tert-Butyl N-Fmoc-L-Aspartate;4-tert-Butyl N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-L-Aspartate;N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-L-Aspartic Acid 4-tert-Butyl Ester;N-(9-Fluorenylmethoxycarbonyl)-L-Aspartic Acid β-tert-Butyl Ester;N-(9-Fluorenylmethoxycarbonyl)Aspartic Acid 4-tert-Butyl Ester |
Tulaga Fa'asoa | E tele |
Numera CAS | 71989-14-5 |
Fuafua mole | C23H25NO6 |
Molecular Weight | 411.45 g/mol |
Lisi Lisi | 145.0~160.0 ℃ |
Malosi | 1.251 |
Suavai Solubility | Laititi Solu i le Vai |
Temp. | Nofoaga malulu ma mago (2~8℃) |
COA & MSDS | Avanoa |
Vaega | Fmoc-Amino Acids |
Fa'ailoga | Ruifu Chemical |
Aitema | Tulaga Fa'atonu | I'uga |
Fa'aaliga | Pa'u Pa'epa'e | Pa'u Pa'epa'e |
Ta'amilosaga Fa'apitoa [α]20/D | -24.0°±2.5° (C=1 ile DMF) | -25.10° |
Lisi Lisi | 145.0~160.0 ℃ | 146.8~147.5 ℃ |
Mama o mata | <0.20% D-Enantiomer | 0.0271% |
Malamalama ole Fofo | 0.3 kalama ile 2ml DMF Clear Solution | E usitaia |
Su'ega Kaiser | <0.05% | <0.05% |
Vai saunia e Karl Fischer | <0.50% | 0.37% |
Ma'imau ile Fa'amago | <0.50% (70℃, 2h) | 0.23% |
Fmoc-β-Ala-OH | <0.10% (HPLC) | E usitaia |
Fmoc-β-Ala-Asp (OtBu)-OH | <0.10% (HPLC) | E usitaia |
Fmoc-Asp(OtBu)-Asp(OtBu)-OH | <0.10% (HPLC) | E usitaia |
Fmoc-Asp-OH | <0.10% (HPLC) | E usitaia |
Su'ega ole Amino Acid | <0.20% (GC) | E usitaia |
Ethyl Acetate | <0.50% (GC) | E usitaia |
Mama / Suʻesuʻega Metotia | >99.0% (HPLC) | 99.84% |
Alaleo Mass | E tusa ai ma le Tulaga | E usitaia |
NMR Alaleo | E tusa ai ma le Tulaga | E usitaia |
Fa'ai'uga | Ua uma ona fa'ata'ita'iina le oloa ma fa'amalieina fa'atonuga |
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Fa'afefea ona Fa'atau?Fa'amolemole fa'afeso'ota'iDr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com
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WGK Siamani 3
HS Code 2922491990
Vasega o Tulaga Lamatia
Fmoc-L-Aspartic Acid β-tert-Butyl Ester (Fmoc-Asp(OtBu)-OH) (CAS: 71989-14-5) o se vailaʻau vavalo, e masani ona faʻaaogaina i le polypeptide synthesis process, mo le puipuiga o le amino acid.Fmoc-amino acids, faʻaaogaina i le peptide synthesis, faʻaaogaina e avea o se mea faʻapipiʻi faʻale-aganuʻu, vailaʻau vailaʻau, vailaʻau faʻasolosolo poʻo vailaʻau faʻamaʻi.
Sauniuniga: Faʻaopoopo le 581g o le tert-Butyl Acetate ma le 133g o le Aspartic Acid i se fagu tolu-gutu ML, faʻafefe, ma faʻaopopo le perchloric acid dropwise, tali i le 10 ℃ mo le 48 itula, faʻamafanafana i le 0 ℃, ona faʻaopopoina lea o le 700ml vai, ave'esea (o le tert-Butyl Acetate totoe e pei o le solvent extraction), fa'amuta i le Na2CO3 i le pH = 7, vavaeeseina o le vai, o le tert-Butyl Acetate layer na fa'atumauina i lalo o le fa'aitiitia o le mamafa e maua ai se fa'afefiloi o Asp(OtBu)2, Asp(OtBu) ma le suauu Asp-OtBu, lea na tuʻufaʻatasia ma le aqueous layer e faʻaaogaina.O le faʻafefiloi na maua na tuʻuina atu i le 125 ml tolu fagu, G cuso4 · 5H2O faʻaopoopoina, ma faʻafetaui le pH i le 3 faʻatasi ai ma le faʻaogaina o le hydrochloric acid.O le paluga na faʻafefe ma faʻamafanafana i le 50 ℃.Mo le 12 itula e saunia ai Cu[Asp(OtBu)]x.(x = 1~2);Ona lalo ifo lea i le vevela o le potu, faaopoopo le 116.2G tetramethylethylenediamine ma le 300ml dioxane, ona fetuunai lea o le pH i le 8 ~ 9 ma le triethylamine e saunia ai Asp(OtBu);Ona faaopoopo lea o le 82gFmoc-OSu i totonu o le Asp(OtBu), tausia le pH 8 ~ 9, tali mo le 8 itula, ona aveese mai lea ma le ethyl acetate, acidify, fufuluina i le vai, faʻamama faʻamama, tioata, faʻamago, 85g o Fmoc-L-aspartic acid beta. -tert-butyl ester na maua i se fua o le 20.7%.E ala ile HPLC su'esu'ega ole Fmoc-L-Aspartic Acid β-tert-Butyl Ester.