S-Phos CAS 657408-07-6 Mama>98.0% (HPLC) Falegaosi Mea Maualuluga

S-Phos (CAS: 657408-07-6) o se ea-stable, electron-rich biaryl phosphine ligand atiaʻe e le vaega Buchwald e faʻaleleia ai le gaioiga o le palladium catalysis i le taimi o faʻasalalauga faʻafefe.E mafai ona fa'aogaina le S-Phos e fai ma ligand i faiga nei: Palladium catalyzed Suzuki-Miyaura cross-coupling reaction between Boc-protected aminomethyltrifluoroborate ma aryl chlorides po'o hetaril chlorides e fausia ai le aminomethylarenes talafeagai.Palladium catalyzed Suzuki-Miyaura cross-coupling tali i le va 4-methyl-sui piperidinylzinc reagent ma eseese aryl po o heteroaryl iodides e fausia ai piperidines suitulaga eseese.Intramolecular Suzuki-Miyaura soʻotaga e fausia ai le mama macrocyclic 18-membered i le taimi o le faʻasologa o laʻasaga tele o riccardin C. Faʻaaogaina faʻatasi ma le palladium e fausia ai se faʻamalosi malosi mo le faʻavaeina o le CN.Ligand/palladium fa'ato'aga mo fa'aulu fa'asu'esu'ega lautele Suzuki-Miyaura.Ligand / palladium faʻamalosi mo le Suzuki-Miyaura faʻapipiʻiina o aryltrifluoroborates faʻatasi ai ma aril chlorides.Ligand / palladium catalyst mo le Suzuki-Miyaura tali o heteroaryl halides ma heteroaryl boronic acids ma esters.Ligand/palladium fa'atosina mo le tali fa'a'oso'o fa'a'au'au o Kumada-Corriu.Ligand/palladium catalyst mo le borylation o aryl halides ma pinacol borane.Suzuki sooga e aofia ai amino acids.Fa'asologa o mea e maua mai le biaryl o le 4-hydroxyphenyl glycine, tyrosine ma le tryptophan.Fa'asologa o sui sui o le adamantylzinc reagents e fa'aaoga ai le Mg-faaofiina i luma o le zinc chloride.E sili ona lelei faʻamalosi mo le palladium-catalyzed Suzuki-Miyura tali o heteroaryl halides ma heteroaryl boronic acids ma esters.