4-Dimethylaminopyridine DMAP CAS 1122-58-3 Kuchena> 99.0% (HPLC) Yakanyanya Kushanda Catalyst
Shanghai Ruifu Chemical Co., Ltd. ndiyo inotungamira kugadzira 4-Dimethylaminopyridine (DMAP) (CAS: 1122-58-3) nemhando yepamusoro.Ruifu Chemical inogona kupa kutumirwa kwepasirese, mutengo wemakwikwi, madiki uye akawanda akawanda aripo.Tenga DMAP, Please contact: alvin@ruifuchem.com
Chemical Name | 4-Dimethylaminopyridine |
Mashoko anoreva zvakafanana | DMAP;4-(Dimethylamino)pyridine;N-(4-Pyridyl) dimethylamine;N,N-Dimethylpyridin-4-Amine;N,N-Dimethyl-4-Pyridinamine;gamma-(Dimethylamino)pyridine |
Nhamba yeCAS | 1122-58-3 |
Stock Status | MuStock, Kukwanisa Kugadzira Matani makumi mana pamwedzi |
Molecular Formula | C7H10N2 |
Molecular Weight | 122.17 |
Melting Point | 110.0~114.0℃ |
Boiling Point | 190 ℃/150 mmHg |
Density | 0.906 g/mL pa25℃ |
Refractive Index | n20/D 1.431 |
Solubility muMethanol | Very Faint Turbidity |
Solubility mumvura | Soluble muMvura, 80 g/l 25℃ |
Solubility (Yakanyanya Soluble mukati) | Chloroform, benzene, methanol, acetone |
COA & MSDS | Available |
Brand | Ruifu Chemical |
Item | Zvinotsanangurwa |
Chitarisiko | Ichena kana Isina-White Crystalline Powder |
Kuchena / Analysis Method | >99.0% (HPLC) |
Melting Point | 110.0~114.0℃ |
Insoluble Mumvura | <0.10% |
Kunyorova (KF) | <0.30% |
Kurasikirwa Pakuomesa | <0.50% (Under Vacumn Kwemaawa matatu Pa60ºC) |
Kusachena Kumwechete | <0.50% |
Zvose Zvisina Kuchena | <1.00% |
Infrared Spectrum | Zvinoenderana NeChimiro |
1 H NMR Spectrum | Zvinoenderana NeChimiro |
Test Standard | Enterprise Standard |
Package:Bhodhoro, Aluminium foil bag, 25kg/Cardboard Drum, kana zvinoenderana nezvinodiwa nemutengi.
Storage Condition:Chengetedza mumidziyo yakavharwa panzvimbo inotonhorera uye yakaoma (≤10 ℃) yekuchengetera kure nezvinhu zvisingaenderane.Dzivirira kubva kuchiedza uye unyoro.
KutumiraKuendesa kupasirese neFedEx / DHL Express.Ipa kutumirwa nekukurumidza uye kwakavimbika.
1122-58-3 - Njodzi uye Kuchengeteka
Risk Codes
R25 - Muchetura kana ukamedzwa
R34 - Zvinokonzera kupisa
R24/25 -
R36/37/38 - Kushungurudza maziso, kufema system uye ganda.
R27 - Yakanyanya Toxic pakubata neganda
R36 - Kushungurudza maziso
R24 - Muchetura pakubata neganda
R20 - Inokuvadza nekufema
R61 - Inogona kukonzera kukuvadza kumwana asati aberekwa
R40 - Uchapupu hushoma hwekuita carcinogenic
R23/24/25 - Muchetura nekufema, kubata neganda uye kana kumedzwa.
R67 - Mhepo inogona kukonzera hope uye dzungu
R66 - Kudzokororwa kuratidzwa kunogona kukonzera kuoma kweganda kana kuputika
R21/22 - Inokuvadza kubata neganda uye kana ikamedzwa.
R11 - Yakanyanya Kupisa
R36/37 - Inogumbura maziso uye kufema system.
R22 - Zvinokuvadza kana ikamedzwa
R19 - Inogona kugadzira peroxides inoputika
Tsanangudzo Yekuchengetedza
S36/37/39 - Pfeka zvipfeko zvekudzivirira zvakakodzera, magurovhosi uye kudzivirira maziso/chiso.
S45 - Kana pakaitika tsaona kana ukanzwa usinganzwe zvakanaka, tsvaga zano rekurapa nekukasira (ratidza chinyorwa pese pazvinogoneka.)
S28A -
S26 - Kana wasangana nemaziso, simbura nekukasira nemvura yakawanda uye tsvaga mazano ekurapwa.
S28 - Mushure mekusangana neganda, geza nekukasira nesipo yakawanda.
S36/37 - Pfeka zvipfeko zvekudzivirira zvakakodzera uye magurovhosi.
S53 - Dzivisa kuratidzwa - wana mirairo yakakosha usati washandisa.
S27 - Bvisa pakarepo zvipfeko zvese zvakasvibiswa.
S22 - Usafeme guruva.
S16 - Chengetedza kure nenzvimbo dzekudzima.
UN IDs UN 2811 6.1/PG 2
WGK Germany 3
RTECS US8400000
TSCA T
HS Code 2942000000
Hazard Note Inotyisa/Inoparadza
Hazard Kirasi 8
Packing Group II
Toxicity LD50 nemuromo muTsuro: 140 mg/kg LD50 dermal Rabbit 90 mg/kg
4-Dimethylaminopyridine (DMAP) (CAS: 1122-58-3) chinhu chitsva chekugadzirisa zvakanyanya chinoshandiswa zvakanyanya mumakemikari synthesis.Iyo ine yakakwira catalytic kugona mune organic synthesis, dhizaini synthesis, mushonga wezvipembenene, dhayi, inonhuhwirira synthesis yeacylation, alkylation, etherification uye mamwe marudzi ekuita, uye ine mhedzisiro iri pachena pakuvandudza goho.Acylation yedoro;acylation ye phenols;Acylation yemamines;Acylation yeanolates;Maitiro e isocyanates;Miscellaneous Applications;Kutamiswa kweMapoka Anoshanda.
DMAP, ndeye super nucleophilic acylation catalyst.Iyo resonance ye electron-donating dimethylamino boka muchimiro chayo uye mhete yemubereki (pyridine ring) inogona kumisa zvakasimba atomu yenitrogen paringi kuti ipinde nucleophilic substitution, iyo inonyanya kukonzeresa kupikisa kwakanyanya, kuderera-reactive alcohols uye amines / acids Chiitiko. yeacylation/esterification reaction inenge 104 ~ 106 nguva yepyridine.Acyl kufambisa ishanduko yakajairika mumasikirwo uye organic synthesis, umo chiral DMAP yakajairika asymmetric acyl kutamisa catalyst.Kubva 1996, Vedejs nechikwata cheFu vakashuma chepakati chiral uye planar chiral DMAP catalysts zvichiteerana, chiral DMAP catalysts dzakagadzirwa zvakanyanya.Yakasiyana-siyana yepakati chiral, planar chiral, spiro chiral uye yepakati chiral DMAP yakashumwa imwe mushure meimwe, uye yakashandiswa zvakanaka mune akawanda asymmetric acyl kutamisa maitiro.
DMAP inogoneka kwazvo nucleophilic catalyst yeacylation reactions uye esterifications.Inoshandiswawo mukuchinja kwakasiyana-siyana kwehupenyu seBaylis-Hillman reaction, Dakin-West reaction, kuchengetedza maamines, C-acylations, silylations, kushandiswa mune zvakasikwa zvigadzirwa chemistry, uye zvimwe zvakawanda.
DMAP inogona kushandiswa sechinhu chinokonzeresa: Kune acylation yezvinwiwa zvine acid anhydrides pasi peyairesi base- uye solvent-isina mamiriro ekugadzira anoenderana esters.MuBaylis-Hillman maitiro ekugadzira kabhoni-kabhoni bond nekubatanidza alkene yakagadziriswa ine aldehyde kana ketone.
Iyo inoshanda zvakanyanya inokonzeresa yeacylation reactions.