4-Dimethylaminopyridine DMAP CAS 1122-58-3 daahirnimo>99.0% (HPLC) Kordhiye Waxqabad Sare
Shanghai Ruifu Chemical Co., Ltd. waa soo saaraha ugu horreeya ee 4-Dimethylaminopyridine (DMAP) (CAS: 1122-58-3) oo leh tayo sare leh.Kiimikada Ruifu waxay bixin kartaa gaarsiinta adduunka oo dhan, qiimo tartan ah, tiro yar iyo tiro badan oo la heli karo.Iibso DMAP, Please contact: alvin@ruifuchem.com
Magaca Kiimikada | 4-Dimethylaminopyridine |
La mid ah | DMAP;4- (Dimethylamino) pyridine;N- (4-Pyridyl) dimethylamine;N, N-Dimethylpyridin-4-Amine;N, N-Dimethyl-4-Pyridinamine;gamma-(Dimethylamino)pyridine |
Lambarka CAS | 1122-58-3 |
Heerka Saamiyada | Kaydka dhexdiisa, Awood Wax-soo-saar 40 Tan bishii |
Qaanuunka molecular | C7H10N2 |
Miisaanka Molecular | 122.17 |
Meesha dhalaalaysa | 110.0 ~ 114.0 ℃ |
Barta Karsan | 190 ℃/150 mmHg |
Cufnaanta | 0.906 g/ml at 25 ℃ |
Tusmada Dib-u-celinta | n20/D 1.431 |
Solubility in Methanol | Turbidity Aad u Daciif ah |
Ku milmay biyaha | Ku milmay Biyaha, 80 g/l 25 ℃ |
Solubility (Aad u milmay) | Chloroform, Benzene, Methanol, Acetone |
COA & MSDS | La heli karo |
Summada | Kiimikada Ruifu |
Shayga | Tilmaamaha |
Muuqashada | Caddaan ama Banaan-cad budada Crystalline |
Daahirnimada / Habka Falanqaynta | >99.0% (HPLC) |
Meesha dhalaalaysa | 110.0 ~ 114.0 ℃ |
Aan Biyo Ku milmin | <0.10% |
Qoyaanka (KF) | <0.30% |
Khasaaraha Qalajinta | <0.50% (Vacumn-ka hoos yimaada 3 saac ee 60ºC) |
Xumaanta Keliya | <0.50% |
Wadarta wasakhda | <1.00% |
Infrared Spectrum | Waafaqsan Qaab-dhismeedka |
1 H NMR Spectrum | Waafaqsan Qaab-dhismeedka |
Heerka Imtixaanka | Heerka Ganacsiga |
Xidhmada:Dhalo, bacda bireed ee aluminium, 25kg/Drum kartoonada, ama sida waafaqsan shuruudaha macmiilka.
Xaaladda Kaydinta:Ku kaydi weelasha xidhan meel qabow oo engegan (≤10℃) bakhaar ka fog walxaha aan ku haboonayn.Ka ilaali iftiinka iyo qoyaanka.
Rarida:Gaarsiiya adduunka oo dhan FedEx/DHL Express.Bixi keenid degdeg ah oo la isku halayn karo.
1122-58-3 - Khatarta iyo Badbaadada
Xeerarka Khatarta
R25 - Sun haddii la liqo
R34 - Sababaha gubashada
R24/25 -
R36/37/38 - Waxay ka xanaajisaa indhaha, habdhiska neefsiga iyo maqaarka.
R27 - Aad u sun ah marka la taabto maqaarka
R36 - Indhaha oo xanaaqsan
R24 - Sunta maqaarka
R20 - Waxyeelo u leh neefsashada
R61 - Waxa laga yaabaa inay waxyeelo u geysato ilmaha uurka ku jira
R40 - Caddayn xaddidan ee saamaynta kansarka
R23/24/25 - Sunta neefsashada, taabashada maqaarka iyo haddii la liqo.
R67 - Uumiga wuxuu keeni karaa lulmo iyo dawakhaad
R66 - Soo-gaadhista soo noqnoqda waxay keeni kartaa maqaarka qallayl ama dillaac
R21/22 - Waxyeelo u leh taabashada maqaarka iyo haddii la liqo.
R11 - Aad u guban kara
R36/37 - Ka xanaajiso indhaha iyo habka neefsashada.
R22 - Waxyeelo leh haddii la liqo
R19 - Waxa laga yaabaa inay sameeyaan peroxides qarxa
Sharaxaada Badbaadada
S36/37/39 - Xidho dhar ilaalin ku haboon, galoofyada iyo ilaalinta indhaha/wejiga.
S45 - Haddii ay dhacdo shil ama haddii aad dareento xanuun, raadso talo caafimaad isla markiiba (tus calaamadda mar kasta oo ay suurtagal tahay.)
S28A -
S26 - Haddii ay dhacdo in indhaha la taabto, isla markiiba ku raaci biyo badan oo raadso talo caafimaad.
S28 - Kadib taabashada maqaarka, isla markiiba ku dhaq saabuun-suds badan.
S36/37 - Xidho dhar difaac ku haboon iyo galoofyada.
S53 - Iska ilaali soo-gaadhista - hel tilmaamo gaar ah kahor isticmaalka.
S27 - Isla markiiba iska siib dhammaan dharka wasakhaysan.
S22 - Ha neefsan boorka.
S16 - Ka fogow ilaha dabka.
Aqoonsiga UN UN 2811 6.1/PG 2
WGK Germany 3
RTECS US8400000
TSCA T
HS code 294200000
Xusuus-qorka Khatarta ah Sun/Dabakh
Khatarta Fasalka 8
Kooxda Baakadaha II
Sunta LD50 ee afka ah ee Bakaylaha: 140 mg/kg LD50 dermal Bakayle 90 mg/kg
4-Dimethylaminopyridine (DMAP) (CAS: 1122-58-3) waa kicin wax ku ool ah oo cusub oo si weyn loogu isticmaalo isku dhafka kiimikada.Waxay leedahay awoodda kicinta sare ee isku-dhafka organic, isku-darka daroogada, sunta cayayaanka, dheeha, udgoonka udgoonka ee acylation, alkylation, etherification iyo noocyada kale ee falcelinta, waxayna leedahay saameyn aad u muuqata oo ku saabsan hagaajinta dhalidda.Acylation ee khamriga;Acylation of phenols;Acylation ee amines;Dhaqdhaqaaqa enolate;Falcelinta isocyanates;Codsiyada kala duwan;Wareejinta Kooxaha Waxqabadka
DMAP, waa kicinta acylation nucleophilic super.Dhawaaqa kooxda dimethylamino-ku-deeqaha elektaroonigga ah ee qaab-dhismeedkeeda iyo giraanta waalidka (giraanta pyridine) waxay si xoog leh u kicin kartaa atamka nitrogen ee giraanta si uu u maro beddelka nucleophilic, taas oo si weyn u kicinaysa iska caabbinta sare, alkolada falcelis yar iyo amines / acids Dhaqdhaqaaqa falcelinta acylation/esterification waxay ku saabsan tahay 104 ~ 106 jeer marka loo eego pyridine.Wareejinta Acyl waa isbeddel caadi ah oo ku yimaada dabeecadda iyo isku-dhafka noolaha, kaas oo chiral DMAP uu yahay kicinta wareejinta acyl-ka caadiga ah.Laga soo bilaabo 1996, kooxda Vedejs iyo Fu waxay ka warbixiyeen kicinta dhexe ee chiral iyo planar chiral DMAP siday u kala horreeyaan, kiciyaasha chiral DMAP ayaa si weyn loo horumariyay.Chiral dhexe oo kala duwan, planar chiral, spiro chiral iyo chiral dhexe DMAP ayaa la soo sheegay midba midka kale, waxaana si wanaagsan loo dabaqay falcelino badan oo kala wareejinta asymmetric acyl.
DMAP waa kicinta nucleophilic oo aad isku dhafan oo loogu talagalay falcelinta acylation-ka iyo caddaymaha.Waxa kale oo lagu shaqaaleysiiyay isbeddello dabiici ah oo kala duwan sida falcelinta Baylis-Hillman, falcelinta Dakin-West, ilaalinta amines, C-acylations, silylations, codsiyada kiimikooyinka dabiiciga ah, iyo kuwo kale oo badan.
DMAP waxa loo isticmaali karaa kiciyayaal ahaan: Soo kicinta alkolada leh anhydrides aashitada oo hoos timaada saldhig caawimo- iyo xaalado aan dareere lahayn si loo soo saaro esters u dhigma.Gudaha Baylis-Hillman falcelinta si loo sameeyo curaarta kaarboon-carbon iyadoo la isku xirayo alkene firfircoon iyo aldehyde ama ketone.
Dajiye wax ku ool ah oo heer sare ah oo kicinaya falcelinta acylation.