(S)-(-)-TolBINAP CAS 100165-88-6 daahirnimo>98.0% (HPLC)
Shanghai Ruifu Chemical Co., Ltd. waa saaraha ugu horreeya ee (S)-(-) TolBINAP (CAS: 100165-88-6) oo leh tayo sare leh.Kiimikada Ruifu waxay bixin kartaa gaarsiinta adduunka oo dhan, qiimo tartan ah, adeeg aad u wanaagsan, tiro yar iyo tiro badan oo la heli karo.Iibka (S)-(-)-TolBINAP,Please contact: alvin@ruifuchem.com
Magaca Kiimikada | (S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl |
La mid ah | (S)-(-)-TolBINAP (S)-Tol-BINAP;(S)-T-BINAP;(S)-Tol-BINA;(-)-Tol-BINA;(-)-Tol-BINAP |
Heerka Saamiyada | Suuqa dhexdiisa, Wax-soo-saarka Ganacsiga |
Lambarka CAS | 100165-88-6 |
Qaanuunka molecular | C48H40P2 |
Miisaanka Molecular | 678.80 g/mol |
Meesha dhalaalaysa | 252.0 ~ 259.0 ℃ |
Xasaasi ah | Xasaasiyadda hawada.Ku kaydi Hoosta Gaaska Inert |
Biyuhu milmayn | Aan ku milmin Biyaha |
COA & MSDS | La heli karo |
Qaybaha Alaabta | Ligands;Chiral Ligands |
Asal ahaan | Shanghai, Shiinaha |
Summada | Kiimikada Ruifu |
Walxaha | Tilmaamaha | Natiijooyinka |
Muuqashada | Caddaan ilaa budo cad-cad | Budada Cad |
Meesha dhalaalaysa | 252.0 ~ 259.0 ℃ | 256.9 ℃ |
Daahirnimada / Habka Falanqaynta | >98.0% (HPLC) | 98.5% |
Daahirnimada / Habka Falanqaynta | 97.5 ~ 102.5% (Titration dhexdhexaadinta) | U hogaansama |
Nadiifnimada indhaha (ee) | >99.0% (HPLC) | 99.2% |
Wareeg gaar ah [a]20/D | -167.0°~-157.0° (C=1.052, Benzene) | -158.7° |
Infrared Spectrometry | Waafaqsan Qaab-dhismeedka | U hogaansama |
1H NMR Spectrum | Waafaqsan Qaab-dhismeedka | U hogaansama |
Gabagabo | Alaabtu waa la tijaabiyay oo waafaqday tilmaamihii la bixiyay |
Xidhmada:Dhalada fluorinated, bacda bireed aluminium, 25kg/Drum kartoonada, ama sida waafaqsan shuruudaha macmiilka.
Xaaladda Kaydinta:Weelka si adag u xidh oo ku kaydi bakhaar qabow, engegan oo hawo wanaagsan leh oo ka fog walxaha aan ku habboonayn.Ka ilaali iftiinka iyo qoyaanka.
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Sidee loo Iibsadaa?Fadlan la xidhiidhDr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com
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MOQ?Ma jiro MOQ.Dalabka yar waa la aqbali karaa.
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Xeerarka Khatarta
36/37/38 - Cuncun xagga indhaha, habka neefsashada iyo maqaarka.
Sharaxaada Badbaadada
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S36/37/39 - Xidho dhar ilaalin ku haboon, galoofyada iyo ilaalinta indhaha/wejiga.
WGK Germany 3
TSCA Maya
HS code 2931900090
(S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl ((S)-(-)-TolBINAP) (CAS: 100165-88-6) Falcelinta
ligand faa'iido leh ee palladium-catalyzed bond bond carbon-oxygen.
Ligand loogu talagalay palladium-catalyzed α-arylation of ketones.
Ligand ee Cu-catalyzed asymmetric conjugate yaraynta.
Ligand loogu talagalay Cu-catalyzed dienolate asymmetrical oo lagu daray aldehyde.
Enantioselective conjugate yaraynta lactones iyo lactams.
Ligand loo isticmaalo cycloaddition enantioselective cycloaddition ee allylsilane leh α-Imino esters.
Dareen-celinta Catalytic Aldol ee ketones.
Ligand leh rhodium catalyses [2+2+2] falcelinta duufaanta ee alkenes iyo alkynes.
Ligand loo isticmaalo iridium-catalyzed enantioselective CH bond activation ee 2- (alkylamino) -pyridine oo leh alkenes.
Iridium-catalyzed regio-, diastereo-, iyo enantioselective tert-(hydroxyl) -prenylation of alcohols.
Rhodium-catalyzed cross cyclotrimerization.
(S)-(-)-2,2'-Bis(di-p-Tolylphosphino)-1,1'-Binaphthyl ((S)-(-)-TolBINAP) (CAS: 100165-88-6) waa chiral ligand si weyn loogu isticmaalo isku-dhafka asymmetric.Waxa kale oo loo istcimaali jiray siyaalo aad u wanaagsan oo loogu talagalay hydrogenation-ka asymmetrical ee alkenes iyo qaar ka mid ah anhydrides meerto ah.BINAP waxaa loo isticmaalaa isku-dhafka dabiiciga ah ee isbeddellada enantioselective ee ay kataliyaan dhismaheeda ruthenium, rhodium, iyo palladium.
(S)-(-)-TolBINAP waxay la falgashaa nitrate silver si ay u samayso (S)-Tol-BINAP·AgNO3, kaas oo kicin kara falcelinta isbahaysiga isbahaysiga ee aldehyde si ay u sameeyaan alkolada sare ee enantiopure.Waxa laga yaabaa in loo isticmaalo sidii ligand chiral ee palladium catalyzed asymmetric double karbohydroamination of iodoarenes si loo sameeyo α-aminoamides.Waxa kale oo ay kicin kartaa falcelinta asymmetric N-allylation of ortho-tert-butylanilide derivatives leh dialyl carbonate si ay u sameeyaan chiral N-allyl ortho-tert-butylanilides.