Iodotrimethylsilane CAS 16029-98-4 daahirnimo>99.0% (Argentmetric Titration) Warshada

Iodotrimethylsilane (CAS: 16029-98-4) kaas oo leh aashito adag (Me3Si) -saldhig jilicsan (I) bond ayaa soo bandhigaysa oksijiin xooggan oo ku wajahan ethers, esters, lactones, acetals, iyo molecules kale oo ku lug leh atom oxygen sida koox shaqeynaya.Isticmaalka iodotrimethylsilane sida wakiilku wuxuu keenay kala-bax fudud oo ah ester-ka tert-butyl, taasoo siinaya asiidhka karboxilic ee u dhigma wax soo saar aad u fiican.Iodotrimethylsilane waxaa loo isticmaalaa soo bandhigida kooxda trimethylsilyl ee isku-dhafka organic.Waxa kale oo ay faa'iido u leedahay falanqaynta chromatography gaaska iyada oo u beddeleysa khamriga silyl ether derivative, taas oo ka dhigaysa mid aad u kacsan marka loo eego molecule asalka ah.Iodotrimethylsilane waa reagent wax ku ool u ah ether, ester, carbamate, ketal, iyo jeexjeexa lactone.Soo bandhigida kooxda TMS, tusaale ahaan, TMS enol ethers.Dareemayaasha furaha u ah ilaalinta xulashada ee kooxda N-Cbz iyadoo ay joogaan unug trimethyltin ah.Reagent ayaa dhawaan la sheegay inuu u beddelay allyl- iyo benzylphosphosphosphosphotriesters-ka iodide u dhigma.Iodotrimethylsilane waa wakiilka xannibaadda caadiga ah ee soo saarista dawooyinka, oo si weyn loogu isticmaalo isku-darka daawooyinka.Waxay difaaci kartaa ama difaaci kartaa kooxaha shaqeeya iyagoo dooranaya, waxay u dhaqmi kartaa sidii wakiilka xannibaadda silane.Iodotrimethylsilane waa reagent ujeedo badan oo loo isticmaalo falcelino dabiici ah oo kala duwan.Waxaa loo isticmaalaa dealkylation ee xeryahooda yar sida lactones, ethers, acetals, iyo carbamates iyo wakiilka trimethylsilylating ee synthesis ee silyl imino esters, alkyl iyo silanes alkenyl, iwm Waxa kale oo u dhaqmo sida kicinta a Lewis acid iyo sida wakiilka yaraynta in falcelin dabiici ah oo badan.Iodotrimethylsilane waxaa loo isticmaali karaa sida reagent isku dhafan oo loogu talagalay dealkylation khafiif ah ethers, karboksylic esters, lactones, carbamate, acetals, fosfonate iyo fosfat esters;jeexjeexyada epoxides, ketones cyclopropyl;Beddelka fosfooraska vinyl ilaa vinyl iodide;reagent nucleophilic dhexdhexaad ah oo loogu talagalay falcelinta is-dhaafsiga halogen, kaarboonyl iyo falcelinta isku-darka isku-darka;u isticmaal sida wakiilka trimethylsilylating ee samaynta enol ethers, silyl imino esters, iyo N-silylenamines, alkyl, alkenyl iyo alkynyl silanes;Lewis acid kicinta samaynta acetal, α- alkoxymethylation of ketones, falcelinta acetals leh ethers silyl enol iyo allylsilanes;yaraynta wakiilka epoxides, ediones, α-ketols, sulfoxides, iyo halides sulfonyl;wakiilka fuuq-baxa ee oximes.