TBDMS Triflate CAS 69739-34-0 Purity >98.0% (Neutralization Titration)

Short Description:

tert-Butyldimethylsilyl Trifluoromethanesulfonate

Syn.: tert-Butyldimethylsilyl Triflate; TBDMS Triflate

CAS: 69739-34-0

Purity: >98.0% (Neutralization Titration) 

Appearance: Colorless to Light Yellow Fuming Liquid

Contact: Dr. Alvin Huang

Mobile/Wechat/WhatsApp: +86-15026746401

E-Mail: alvin@ruifuchem.com


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Description:

Shanghai Ruifu Chemical Co., Ltd. is the leading manufacturer and supplier of tert-Butyldimethylsilyl Trifluoromethanesulfonate (CAS: 69739-34-0) with high quality. We can provide COA, worldwide delivery, small and bulk quantities available. Please contact: alvin@ruifuchem.com

Chemical Properties:

Chemical Name tert-Butyldimethylsilyl Trifluoromethanesulfonate
Synonyms Trifluoromethanesulfonic Acid tert-Butyldimethylsilylester; tert-Butyldimethylsilyl Triflate; TBDMS Triflate; TBS Triflate
CAS Number 69739-34-0
CAT Number RF-PI2112
Stock Status In Stock, Production Scale Up to Tons
Molecular Formula C7H15F3O3SSi
Molecular Weight 264.34
Boiling Point  65.0~67.0℃/12 mm Hg(lit.)
Water Solubility  Decomposes
Sensitivity Moisture Sensitive
Hydrolytic Sensitivity 8: Reacts Rapidly With Moisture, Water, Protic Solvents
Hazard Note  Flammable / Corrosive
Hazard Class  3
Packing Group  III
HS Code  29310095
Shelf Life 60 Months
Articles / Brochures  Silicon Compounds
Brand Ruifu Chemical

Specifications:

Item Specifications
Appearance Colorless to Light Yellow Fuming Liquid  
Purity / Analysis Method >98.0% (Neutralization Titration)
Refractive Index n20/D  1.384~1.388
Density (20℃)  1.148~1.156
Water (K.F) <0.10%
Infrared Spectrum Conforms to Structure
Proton NMR Spectrum Conforms to Structure
Test Standard Enterprise Standard

Package & Storage:

Package: Fluorinated Bottle, 25kg/Barrel, or according to customer's requirement

Storage Condition: Store in sealed containers at cool and dry place; Protect from light and moisture

Advantages:

1

FAQ:

Application:

tert-Butyldimethylsilyl Trifluoromethanesulfonate (CAS: 69739-34-0) is a highly reactive silylating agent and lewis acid capable of converting primary, secondary and tertiary alcohols to their respectctive TBDMS. TrifluoroMethanesulfonic acid tert-butyldiMethylsilyl ester is also used to covert ketones and lactones into their enol silyl ethers. TBDMS Triflate is used as a highly reactive silylating agent and Lewis acid capable of converting primary, secondary, and tertiary alcohols1b to the corresponding TBDMS ethers, and converting ketones and lactones, into their enol silyl ethers; promoting conjugate addition of alkynylzinc compounds and triphenylphosphine5 to α,β-enones; activation of chromones in [4 + 2] cycloaddition reactions;rearrangement of allylic tributylstannyl silyl ethers; activation of pyridine rings toward Grignard reagents and transalkylation of tertiary amine N-oxides;and transformation of N-t-butoxycarbonyl groups into N-alkoxycarbonyl groups.

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