Titanium(IV) Isopropoxide CAS 546-68-9 Ti 16.6~16.9% Factory High Quality

Short Description:

Titanium(IV) Isopropoxide

Synonyms: TTIP 

CAS: 546-68-9

Ti : 16.6~16.9%

Colorless to Light Yellow Clear Liquid

High Quality, Commercial Production

Contact: Dr. Alvin Huang

Mobile/Wechat/WhatsApp: +86-15026746401

E-Mail: alvin@ruifuchem.com


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Description:

Shanghai Ruifu Chemical Co., Ltd. is the leading manufacturer of Titanium(IV) Isopropoxide (TTIP) (CAS: 546-68-9) with high quality. Ruifu Chemical can provide worldwide delivery, competitive price, small and bulk quantities available. Purchase Titanium(IV) Isopropoxide, Please contact: alvin@ruifuchem.com

Chemical Properties:

Chemical Name Titanium(IV) Isopropoxide  
Synonyms TTIP; Tetraisopropyl Orthotitanate; Isopropyl Titanate; Tetraisopropyl Titanate; Titanium(IV) Tetraisopropoxide; TYZOR-organic titanate; Isopropyl Alcohol Titanium(4+) Salt
Stock Status In Stock, Production Capacity 50 Tons per Month
CAS Number 546-68-9
Molecular Formula C12H28O4Ti 
Molecular Weight 284.22 g/mol
Melting Point 14.0~17.0℃(lit.)  
Boiling Point 220℃(lit.)  
Flash Point 46℃(115°F)
Sensitive Moisture Sensitive  
Hydrolytic Sensitivity 7: Reacts Slowly with Moisture/Water
Solubility (Soluble in)  Alcohol, Chloroform, Ether, Benzene, Toluene 
Stability Stable, But Decomposes in the Presence of Moisture. Incompatible with Aqueous Solutions, Strong Acids, Strong Oxidizing Agents. Flammable.
Storage Temp.  Cool & Dry Place. Flammables Area
COA & MSDS Available
Brand Ruifu Chemical

Specifications:

Items Inspection Standards Results
Appearance Colorless to Light Yellow Clear Liquid (Visual Inspection) Clear Liquid 
Color at Time of mfg(APHA) ≤100 (Platinum Cobalt Colorimetric) 20
Purity  ≥99.0% >99.0%
Ti Contect   16.6~16.9% (Calcination Weighting) 16.74%
TiO2 Content 27.5~28.3% (Calcination Weighting) 28.05%
Specific Gravity (25℃) 0.950~0.965 g/ml (Hydrometer) 0.956 
Refractive Index  1.4670~1.4690 1.4673
Chloride Content (Cl) ≤50ppm (Titration) 22ppm
Isopropyl Alcohol ≤0.50% <0.50%
Infrared Spectrum Conforms to Structure Complies      
Conclusion The product has been tested & complies with the specifications

Package/Storage/Shipping:

Package: Bottle, 25kg/Drum, 190kg/Drum, or according to customer's requirement.
Storage Condition: Moisture sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong acids. It reacts with water to produce titanium dioxide. Store at Flammables Area.
Shipping: Deliver to worldwide by FedEx / DHL Express. Provide fast and reliable delivery. 

Advantages:

Sufficient Capacity: Sufficient facilities and technicians

Professional Service: One stop purchasing service

OEM Package: Custom package and label available

Fast Delivery: If within stock, three days delivery guaranteed

Stable Supply: Maintain reasonable stock    

Technical Support: Technology solution available

Custom Synthesis Service: Ranged from grams to kilos

High Quality: Established a complete quality assurance system

FAQ:

How to Purchase? Please contact Dr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com 

15 Years Experience? We have more than 15 years of experience in the manufacture and export of a wide range of high quality pharmaceutical intermediates or fine chemicals.

Main Markets? Sell to domestic market, North America, Europe, India, Korea, Japanese, Australia, etc.

Advantages? Superior quality, affordable price, professional services and technical support, fast delivery.

Quality AssuranceStrict quality control system. Professional equipment for analysis include NMR, LC-MS, GC, HPLC, ICP-MS, UV, IR, OR, K.F, ROI, LOD, MP, Clarity, Solubility, Microbial limit test, etc.

SamplesMost products provide free samples for quality evaluation, shipping cost should be paid by customers.

Factory AuditFactory audit welcome. Please make an appointment in advance.

MOQ? No MOQ. Small order is acceptable.

Delivery Time? If within stock, three days delivery guaranteed.

TransportationBy Express (FedEx, DHL), by Air, by Sea.

Documents? After sales service: COA, MOA, ROS, MSDS, etc. can be provided.

Custom SynthesisCan provide custom synthesis services to best fit your research needs.

Payment TermsProforma invoice will be sent first after confirmation of order, enclosed our bank information. Payment by T/T (Telex Transfer), PayPal, Western Union, etc. 

546-68-9 - Risk and Safety:

Risk Codes
R10 - Flammable
R36 - Irritating to the eyes
R36/37/38 - Irritating to eyes, respiratory system and skin.
R11 - Highly Flammable
R67 - Vapors may cause drowsiness and dizziness
Safety Description
S16 - Keep away from sources of ignition.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S7/9 -
UN IDs UN 2413 3/PG 3
WGK Germany 2
RTECS NT8060000
FLUKA BRAND F CODES 21
TSCA Yes
HS Code 2905199090
Hazard Class 3
Packing Group III

Application:

Titanium(IV) Isopropoxide (TTIP) (CAS: 546-68-9) is colorless to light yellow clear liquid. TTIP is a titanium-based coordination compound. Smoke in moist air. Water rapid hydrolysis, soluble in alcohol, ether, ketone, benzene and other organic solvents. In case of high heat, open flame or contact with oxidant, there is a risk of combustion. The reaction with water or water vapor gives off a toxic or flammable gas. In case of high fever, the internal pressure of the container increases, and there is a risk of cracking and explosion.
The catalyst for the esterification reaction is used for the transesterification reaction of esters such as acrylic acid and the polymerization of epoxy resin, phenolic plastic, silicone resin, polybutadiene, PP and PE. Can also be used as raw materials for the pharmaceutical industry and the preparation of metal and rubber, metal and plastic adhesives. It can also be used as surface modifier, adhesion promoter and paraffin and oil additives.
A precursor for the preparation of Titania. Commonly used as a precursor for the preparation of Titania (TiO2). Novel metal oxide/phosphonate hybrids were formed from titanium(IV) isopropoxide in a two-step sol-gel process. Starting material for barium-strontium-titanate thin films. Used to make porous titanosilicates, potential ion-exchange materials for cleanup of radioactive wastes. Applied in the formation of a heterosupermolecule consisting of a TiO2 nanocrystallite-viologen electron acceptor complexwhose light-induced electron transfer has been demonstrated.
TIPT is a type of very lively primary alcohol titanium oxide; it hydrolyzes when contacted with moisture in air. TIPT is mainly used as catalyst in esterification reaction or transesterification,also being used as catalyst of polyolefin. It can be used to improve the adherence and crosslinking of resin having alcohol group or carboxyl group, used in heat resistant and corrosion resistant coating. It also can be used in the manufacture of glass and glass fiber. TIPT can only be used in oil system.
Applications:
Coating: Glass, metals, fillers and pigments can be treated with TIPT to give increased surface hardness; adhesion promotion; heat, chemical and scratch resistance; coloring effects; light reflection; iridescence; and corrosion resistance.
Paint additive: TIPT can be used as an additive in paints to cross-link -OH functional polymers or binders; to promote adhesion; or to act as a binder itself.
TiO2 pigments and films: Micro- or nano-scale TiO2 pigments can be formed from TIPT. It can also be used to create a polymeric TiO2 film on surfaces via pyrolytic or hydrolytic processes.

546-68-9 - Safety:

Rat oral LD50: 7460mg/kg. May cause irritation to eyes, skin, inhalation, ingestion or percutaneous absorption may be harmful to the body. This substance is harmful to the environment, and special attention should be paid to the pollution of water bodies. Stored in a high-dryness clean warehouse. Keep away from fire and heat source. The bin temperature should not exceed 30℃. Protection from direct sunlight. The packaging must be sealed and free from moisture. Should be stored separately from the oxidant.  

Production Method:

Titanium Tetrachloride, Isopropyl Alcohol, and liquid Ammonia were heated and dissolved in toluene as a solvent to undergo an esterification reaction. The reaction product was filtered off by-product ammonium chloride by suction, and the product was obtained by distillation.

Air & Water Reactions:

Highly flammable. Fumes in air. Soluble in water. Decomposes rapidly in water to form flammable isopropyl alcohol. 

Reactivity Profile:

Metal alkyls, such as TETRAISOPROPYL TITANATE, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols.

Health Hazard:

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Flammability and Explosibility:

Flammable.

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