Trimethylsilyl Trifluoromethanesulfonate CAS 27607-77-8 Purity >99.0% (GC)

Short Description:

Name: Trimethylsilyl Trifluoromethanesulfonate 

CAS: 27607-77-8

Purity: >99.0% (GC)  

Colorless or Light Yellow Transparent Liquid

High Quality, Commercial Production

E-Mail: alvin@ruifuchem.com


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Description:

Shanghai Ruifu Chemical Co., Ltd. is the leading manufacturer and supplier of Trimethylsilyl Trifluoromethanesulfonate (CAS: 27607-77-8) with high quality. We can provide COA, worldwide delivery, small and bulk quantities available. Please contact: alvin@ruifuchem.com

Chemical Properties:

Chemical Name Trimethylsilyl Trifluoromethanesulfonate
Synonyms TMS Triflate; TMSOTf; Trifluoromethanesulfonic Acid Trimethylsilylester; Trimethylsilyl Triflate; Trifluoromethanesulfonic Acid Trimethylsilyl Ester; TMS-OTf
CAS Number 27607-77-8
CAT Number RF-PI2096
Stock Status In Stock, Production Scale Up to Tons
Molecular Formula C4H9F3SiSO3 
Molecular Weight 222.26
Boiling Point 77℃/80mmHg
Sensitivity Moisture & Air Sensitive
Water Solubility  Reacts
Hydrolytic Sensitivity 8: Reacts Rapidly With Moisture, Water, Protic Solvents
Brand Ruifu Chemical

Specifications:

Item Specifications
Appearance Colorless or Light Yellow Transparent Liquid, Stimulating Smell
Purity / Analysis Method >99.0% (GC)
Proton NMR Spectrum Conforms to Structure
Fluorine NMR Spectrum Conforms to Structure
Density (20℃)  1.228~1.230
Refractive Index n20/D 1.359~1.361
H2O ≤0.02%
SO42- ≤50ppm
F- ≤10ppm
Cl- ≤50ppm
Test Standard Enterprise Standard

Package & Storage:

Package: Bottle, 25kg/Barrel, or according to customer's requirement

Storage Condition: Store in sealed containers at cool and dry place; Protect from light and moisture

Advantages:

1

FAQ:

Application:

Trimethylsilyl Trifluoromethanesulfonate (CAS: 27607-77-8) is a strong Lewis acid catalyst and efficient silylating agent. Usually used in a Dieckmann-like cyclization of ester-imides and diesters,and also used to prepare difluoroboron triflate etherate a powerful Lewis acid especially in acetonitrile solvent. Trimethylsilyl Trifluoromethanesulfonate is generally used following reactions:1. Silylation. TMSOTf is widely used in the conversion of carbonyl compounds to their enol ethers. The conversion is some 109 faster with TMSOTf/triethylamine than with chlorotrimethylsilane. Trimethylsilyl Trifluoromethanesulfonate is a trialkylsilyl triflate used as a catalyst in organic synthesis. It is used in combination with boron trifluoride eth yl ether to prepare a Lewis acid that is more powerful than its components and especially effective in acetonitrile solvent.

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