(Trimethylsilyl)diazomethane CAS 18107-18-1 2.0 M Solution in Hexanes
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Chemical Name | (Trimethylsilyl)diazomethane (2.0 M Solution in Hexanes) |
Synonyms | Trimethylsilyldiazomethane; TMS-Diazomethane; (Diazomethyl)trimethylsilane; (2.0 M Solution in Hexanes) |
CAS Number | 18107-18-1 |
CAT Number | RF-PI2226 |
Stock Status | In Stock, Production Scale Up to Tons |
Molecular Formula | C4H10N2Si |
Molecular Weight | 114.22 |
Boiling Point | 96℃ |
Density | 0.773 g/mL at 25℃ |
Sensitive | Light Sensitive, Moisture Sensitive, Heat Sensitive |
Solubility | Immiscible With Water. Miscible With Most Organic Solvents |
Stability | Shock Sensitive |
Brand | Ruifu Chemical |
Item | Specifications |
Appearance | Light Yellow to Yellow Clear Liquid |
Concentration | 2.0 M Solution in Hexanes |
High Boiling Impurities | To Pass Test |
Proton NMR Spectrum | Conforms to Structure |
Test Standard | Enterprise Standard |
Package: Fluorinated Bottle, 25kg/Drum, or according to customer's requirement
Storage Condition: Store in sealed containers at cool and dry place; Protect from light and moisture
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(Trimethylsilyl)diazomethane (CAS: 18107-18-1) is used as one-carbon homologation reagent; stable, safe substitute for diazomethane; participating in the synthesis reactions of insertion reactions; ketenylation reactions;preparation of homoallylic sulfides; pericyclic reactions; [C-N-N] 1,3-dipole for the preparation of azoles. (Trimethylsilyl)diazomethane is used as an analyte in the determination of some phenolic organohalogens in human serum by GC-MS. (Trimethylsilyl)diazomethane is considered as a non-explosive substitute to diazomethane for the homologation of carbonyl derivatives, mainly ketones, via reactions such as Tiffeneau-Demjanov rearrangement.
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