(Trimethylsilyl)diazomethane CAS 18107-18-1 2.0 M Solution in Hexanes

Short Description:

Chemical Name: (Trimethylsilyl)diazomethane

Synonyms: TMS-Diazomethane 

CAS: 18107-18-1

Concentration: 2.0 M Solution in Hexanes  

Appearance: Light Yellow to Yellow Clear Liquid

E-Mail: alvin@ruifuchem.com


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Description:

Shanghai Ruifu Chemical Co., Ltd. is the leading manufacturer and supplier of (Trimethylsilyl)diazomethane, 2.0 M Solution in Hexanes (CAS: 18107-18-1) with high quality. We can provide COA, worldwide delivery, small and bulk quantities available. If you are interested in this product, please send detailed information includes CAS number, product name, quantity to us. Please contact: alvin@ruifuchem.com

Chemical Properties:

Chemical Name (Trimethylsilyl)diazomethane (2.0 M Solution in Hexanes)
Synonyms Trimethylsilyldiazomethane; TMS-Diazomethane; (Diazomethyl)trimethylsilane; (2.0 M Solution in Hexanes)
CAS Number 18107-18-1
CAT Number RF-PI2226
Stock Status In Stock, Production Scale Up to Tons
Molecular Formula C4H10N2Si 
Molecular Weight 114.22  
Boiling Point 96℃
Density   0.773 g/mL at 25℃
Sensitive Light Sensitive, Moisture Sensitive, Heat Sensitive
Solubility  Immiscible With Water. Miscible With Most Organic Solvents
Stability Shock Sensitive
Brand Ruifu Chemical

Specifications:

Item Specifications
Appearance Light Yellow to Yellow Clear Liquid
Concentration 2.0 M Solution in Hexanes  
High Boiling Impurities To Pass Test
Proton NMR Spectrum  Conforms to Structure
Test Standard Enterprise Standard

Package & Storage:

Package: Fluorinated Bottle, 25kg/Drum, or according to customer's requirement

Storage Condition: Store in sealed containers at cool and dry place; Protect from light and moisture

Advantages:

1

FAQ:

Application:

(Trimethylsilyl)diazomethane (CAS: 18107-18-1) is used as one-carbon homologation reagent; stable, safe substitute for diazomethane; participating in the synthesis reactions of insertion reactions; ketenylation reactions;preparation of homoallylic sulfides; pericyclic reactions; [C-N-N] 1,3-dipole for the preparation of azoles. (Trimethylsilyl)diazomethane is used as an analyte in the determination of some phenolic organohalogens in human serum by GC-MS. (Trimethylsilyl)diazomethane is considered as a non-explosive substitute to diazomethane for the homologation of carbonyl derivatives, mainly ketones, via reactions such as Tiffeneau-Demjanov rearrangement.

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