1,1′-Bis(diphenylphosphino)ferrocene CAS 12150-46-8 DPPF Ucoceko >98.0% Fe 9.7~10.4%
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Igama leMchiza | 1,1'-Bis(diphenylphosphino)ferrocene |
Izithethantonye | 1,1'-Ferrocenebis(diphenylphosphine);DPPF |
Inombolo yeCAS | 12150-46-8 |
Inombolo yeCAT | RF-PI2275 |
Ubume beStokhwe | Kwi-Stock, iMveliso yoMveliso ukuya kwiiToni |
Ifomula yeemolekyuli | C34H28FeP2 |
Ubunzima beMolekyuli | 554.39 |
Inovakalelo | Ubuthathaka bomoya |
Ukunyibilika emanzini | Ayinyibilikiyo emanzini |
Ukunyibilika | Inyibilika kwiChloroform |
Uvakalelo lweHydrolytic | 7: Iphendula ngokucothayo Ngobumanzi/Amanzi |
Uphawu | Ruifu Chemical |
Into | Iinkcukacha |
Imbonakalo | Yellow ukuya kwiOrenji Powder |
Ubunyulu / Indlela yokuHlalutya | >98.0% (Chelometric Titration) |
Intsimbi (Fe) | 9.7 ~ 10.4% (Titration ngu-Na2S2O3) |
Ikhabhoni ngohlalutyo lwe-Elemental | 71.1~76.2% |
Indawo yokunyibilika | 181.0 ~ 183.0℃ |
Amanzi nguKarl Fischer | <0.50% |
Ukunyibilika kwi-CHCL3 | Umthubi ukuya kwiOrenji, Ukudlula okucacileyo(2.5%) |
I-Infrared Spectrum | Iyahambelana neSakhiwo |
Umgangatho woVavanyo | Umgangatho woShishino |
Iphakheji: Ibhotile, ingxowa yefoyile yeAluminiyam, 25kg/Igubu lekhadibhodi, okanye ngokwemfuno yomthengi
Imeko yoGcino:Gcina kwizikhongozeli ezivaliweyo kwindawo epholileyo neyomileyo;Khusela ukukhanya kunye nokufuma
I-1,1'-Bis(diphenylphosphino)ferrocene (CAS: 12150-46-8), i-Suzuki-Miyaura Cross Coupling Reaction, i-Ligands, i-Organic Metallic Catalysts.Ngokuqhelekileyo isetyenziswe kwiimpendulo zemichiza ezilandelayo ezizezi Buchwald-Hartwig Cross Coupling Reaction, Carbonylations, Ene Reaction, Heck Reaction, Negishi Coupling, Sonogashira Coupling, Stille Coupling, Suzuki-Miyaura Coupling, Tsuji-Trost Reaction.Izicelo Ezisetyenziswa ngokuqhelekileyo ikhompawundi yolungelelwaniso kwi-synthesis, yenza ngokulula iikhompleksi ezineentsimbi ezahlukeneyo, okt xa usabela nge-acetonitrile okanye i-benzonitrile complexes ye-PdCl2 yenza (dppf) PdCl2, eyi-reagent ethandwayo ye-palladium-catalyzed coupling reactions.Inoveli ephuma kwifuran esebenzayo yalungiswa ngePd-phosphine elandelelanayo yeCC kunye nokwakhiwa kwebhondi yeCO.I-Ligand isetyenziswe kwi-Pd (II) -i-catalyzed cross-coupling synthesis ye-oxazepine ring systems.I-1,1'-Bis(diphenylphosphino) i-ferrocene isebenza njenge-ligand kwi-homogeneous catalysis.Isetyenziswa njenge-ligand ye-ruthenium-catalyzed greener amine synthesis esuka kwi-amines kunye ne-alcohol ngokuboleka kwe-hydrogen.Ikwasetyenziswa njenge-ligand ye-Buchwald-Hartwig cross coupling.Ngaphaya koko, isetyenziswa ekudibaneni kolungelelwaniso lwekhompawundi kunye nokwakheka kweekhompleksi ezineentsimbi ezahlukeneyo ezifana ne-palladium chloride.Ukongeza koku, isebenza njenge-reagent ye-palladium-catalyzed coupling reactions kwaye idlala indima ebalulekileyo kwi-Suzuki reaction.