PMDI CAS 9016-87-9 Polymethylene Polyphenyl Polyisocyanate
I-Shanghai Ruifu Chemical Co., Ltd. ngumenzi ohamba phambili wePolymethylene Polyphenyl Polyisocyanate (PMDI; Polymeric MID) (i-CAS: 9016-87-9) enomgangatho ophezulu.I-Ruifu Chemical inokubonelela ngenkonzo yehlabathi jikelele, ixabiso elikhuphisanayo, inkonzo egqwesileyo, encinci kunye nezixa ezininzi ezikhoyo.Thenga i-PMDI,Please contact: alvin@ruifuchem.com
Igama leMchiza | Polymethylene Polyphenyl Polyisocyanate |
Izithethantonye | PMDI;IPAPI;I-MID yePolymeric;I-MDI PM 200;I-Polymethylene Polyphenyl Isocyanate;Poly[(phenyl isocyanate)-co-formaldehyde];Coronatemr200;Cr200 |
Ubume beStokhwe | Kwisitokhwe, isikali soRhwebo |
Inombolo yeCAS | 9016-87-9 |
Ifomula yeemolekyuli | C8H7NO2 |
Ubunzima beMolekyuli | 149.14668 g/mol |
Indawo yokubilisa | 392℃/5 mm Hg |
Indawo yokuflasha | >230°F |
Ukuxinana | 1.2 g/mL ku-25℃(lit.) |
Refractive Index n20/D | 1.634 |
I-COA kunye ne-MSDS | Iyafumaneka |
Uphawu | Ruifu Chemical |
Into | Umgangatho Wokuhlola | Iziphumo | UvavanyoMindlela |
Imbonakalo | Ulwelo oluBrown | Ulwelo oluBrown | GB/T 13658-1992 |
Viscosity(25℃) (mPa.S) | 150~250 | 231 | GB/T 12009.3-2009 |
Umxholo weNCO(%Wt) | 30.20~32.00 | 30.87 | GB/T 12009.4-1989 |
Ukuxinana (25℃)/(g/cm3) | 1.220~1.250 | 1.232 | GB/T 4472-1984 |
Umxholo we-Acid(%, HCICinye) | ≤0.05 | 0.0060 | GB/T 12009.5-1992 |
I-Hydrolysable Chlorine(%) | ≤0.20 | 0.0544 | GB/T 12009.2-1989 |
Umqulu:220kg/Drum, okanye ngokwemfuno yomthengi.
Ukuhambisa ngenqanawe:Zisa kwihlabathi liphela ngomoya, ngolwandle ngeFedEx / DHL Express.Ukubonelela ngokukhawuleza nangokuthembekileyo.
Uzinzo:Izinzile.Ayihambelani ne-oxidizing agents enamandla, i-alcohols.Isenokubola emoyeni ofumileyo, okanye xa idibana namanzi.
Ekubeni i-PMDI yikhemikhali esebenzayo, ukusabela ngomswakama we-atmospheric kwenzeka ngokulula kwaye kukhokelela ekubunjweni kwe-ureas engaxutywanga kunye ne-carbon dioxide gas, enokubangela ukunyanzeliswa kwengcinezelo kwiibhotile ezivaliweyo kunye nokunyuka kwe-viscosity yemveliso.Izikhongozeli kufuneka zome ngokupheleleyo kwaye zivalwe ngononophelo emva kokuxinana ngenitrogen.Izikhongozeli ze-PMDI kufuneka zigcinwe zivaliwe ngokufanelekileyo kwaye zigcinwe ngaphakathi kwiqondo lokushisa eliphakathi (15-35 ℃) kwindawo engena umoya.Ukugcinwa kubushushu obuphantsi (ngaphantsi kwe-5℃) kunokukhokelela ekukhanyeni okuthile;le nto kufuneka, ke ngoko, ikhuselwe kwiqabaka.Ukuba icrystallization iyenzeka, imathiriyeli kufuneka ifudunyezwe ngokuqengqeleka idrum kwi-oveni yomoya oshushu kwi-70-80 ℃ ukuyinyibilikisa, kwaye emva koko kufuneka iphazamiseke ngokupheleleyo phambi kokusetyenziswa.Ukunyibilika kwindawo yokuhlambela amanzi akukhuthazwa.Ukugcinwa okwandisiweyo kumaqondo obushushu angaphezu kwe-50℃ akukhuthazwa ukuba kuthintelwe ekubunjweni kwezinto eziqinileyo ezinganyibilikiyo kunye nokwanda kwe-viscosity.
Ukuthenga njani?Nceda uqhagamshelaneDr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com
Amava Eminyaka Eli-15?Sineminyaka engaphezu kwe-15 yamava ekwenziweni nasekuthumeleni kumazwe angaphandle uluhlu olubanzi oluphezulu lwamayeza aphakathi okanye amachiza alungileyo.
Iimarike eziphambili?Thengisa kwimarike yasekhaya, eMntla Melika, eYurophu, eIndiya, eKorea, eJapan, eOstreliya, njl.
Iingenelo?Umgangatho ophezulu, ixabiso elifikelelekayo, iinkonzo zengcali kunye nenkxaso yobugcisa, ukuhanjiswa ngokukhawuleza.
UmgangathoIsiqinisekiso?Inkqubo yokulawula umgangatho ongqongqo.Izixhobo zobuchwephesha zokuhlalutya ziquka i-NMR, LC-MS, GC, HPLC, ICP-MS, UV, IR, OR, KF, ROI, LOD, MP, Clarity, Solubility, Microbial limit test, njl.
Iisampulu?Uninzi lweemveliso zibonelela ngeesampulu zasimahla zokuvavanya umgangatho, iindleko zokuthumela kufuneka zihlawulwe ngabathengi.
Factory Audit?Uphicotho-zincwadi lwasefektri wamkelekile.Nceda wenze idinga kwangaphambili.
MOQ?Akukho MOQ.Umyalelo omncinci wamkelekile.
Ixesha lokuzisa? Ukuba ngaphakathi kwesitokhwe, ukuhanjiswa kweentsuku ezintathu kuqinisekisiwe.
Ezothutho?Nge-Express (FedEx, DHL), ngoMoya, ngoLwandle.
Amaxwebhu?Emva kwenkonzo yokuthengisa: I-COA, i-MOA, i-ROS, i-MSDS, njl.
Udibaniso lweSiko?Inokubonelela ngeenkonzo zesiko lokudibanisa ukuze zilungele iimfuno zakho zophando.
Immimiselo yokuhlawula?I-invoyisi yeProforma iya kuthunyelwa kuqala emva kokuqinisekiswa kwe-odolo, efakwe kwiinkcukacha zethu zebhanki.Intlawulo nge-T / T (i-Telex Transfer), i-PayPal, i-Western Union, njl.
Iikhowudi zoMngcipheko
I-R20 - Inobungozi ngokuphefumla
R36/37/38 - Ukucaphukisa emehlweni, inkqubo yokuphefumla kunye nolusu.
I-R42 - Inokubangela uvakalelo ngokuphefumla
I-R42/43 - Inokubangela uvakalelo ngokuphefumla kunye nokudibana nolusu.
I-R26 - Ityhefu kakhulu ngokuphefumla
I-R22 - Iyingozi xa iginyiwe
R39/23/24/25 -
I-R23/24/25 - Ityhefu ngokuphefumla, xa udibana nesikhumba kwaye xa uginyiwe.
I-R11-Inokutsha kakhulu
I-R20/21/22 - Iyingozi ngokuphefumla, xa udibana nolusu naxa uginyiwe.
Inkcazelo yoKhuseleko
S26 - Xa udibana namehlo, hlambulula ngokukhawuleza ngamanzi amaninzi kwaye ufune iingcebiso zonyango.
S28 - Emva kokudibana nolusu, hlamba ngoko nangoko ngeesepha ezininzi.
S38 - Kwimeko yokungonelanga komoya, nxiba izixhobo ezifanelekileyo zokuphefumula.
S45 - Kwimeko yengozi okanye ukuba uziva ungaphilanga, funa ingcebiso kagqirha ngokukhawuleza (bonisa ileyibhile nanini na kunokwenzeka.)
S36/37 -Nxiba iimpahla ezifanelekileyo zokukhusela kunye neeglavu.
S23 - Musa ukuphefumla umphunga.
S16 - Gcina kude kwimithombo yomlilo.
S7 - Gcina isikhongozeli sivalwe ngokuqinileyo.
S36 - Nxiba iimpahla ezifanelekileyo zokukhusela.
WGK eJamani 3
RTECS TR0350000
I-Polymethylene Polyphenyl Polyisocyanate (PMDI; i-Polymeric MID) (i-CAS: 9016-87-9)
I-PMDI yi-disocyanate-diphenylmethane(MDI)-based composition equlethe ezinye ze-isocyanates eziphezulu zokusebenza.Ukusebenza malunga ne-2.6-2.7.Ilulwelo oluntsundu kumaqondo obushushu akwindawo engqongileyo.
I-PMDI ingasetyenziswa ngokubanzi kwimveliso ye-PU eqinile ye-foam ye-heat-insulating materials;iphinda isetyenziswe kwi-foam ye-isocyanurate, iipeyinti, i-adhesives, i-foam yesakhiwo, i-cellular integral foam yesikhumba, i-automotive bumper kunye neendawo zangaphakathi, i-foam ephezulu kunye ne-synthetic wood, njl.Ngoko ke, ifanelekile ngokukodwa kwimveliso efuna ukuhamba okungqongqo kweenkqubo.
I-PMDI yipolymer yobunjineli esetyenziselwa ukuhlanganiswa kwe-polyurethane foams eyomelela kakhulu kunye ne-flame retardancy.I-toxin ye-Environmental kuluhlu lwe-US EPA Toxic Release Inventory (TRI).
Isetyenziselwa ukwenza i-elastomer ye-microporous polyurethane elastomer esebenza kakhulu, i-coating kunye ne-polyurethane ethambileyo yokuzicoca ugwebu, kuquka i-soles, amatayara aqinileyo angundoqo, ii-fenders zemoto, i-absorbers, iipleyiti zokuminxa, ivili lokuqhuba, imiqamelo yesihlalo, iindawo zokuhlala, izixhobo zangaphakathi, njl. Ikwasetyenziswa ngokubanzi ekwenzeni i-adhesives, i-coatings, i-prepolymers kunye ne-semi-prepolymers.
Isetyenziselwa ukwenza iiplastiki zogwebu, izinto zokuncamathelisa, njl.njl ezisetyenziswa ekwenzeni izinto zepolyurethane, ezisetyenziswa kakhulu kushishino lokwakha, ishishini leemoto, ishishini lombane, njengezinto zokugquma i-thermal okanye zokulala.
I-PMDI iguquguquka kakhulu kwaye inetyhefu encinci ekuphefumleleni ukuphefumla kunye nokufunxa kwesikhumba, kodwa iqulethe amaqela e-isocyanate (NCO) asabela ngokulula ngokufuma, xa ubushushu bezinto eziphathekayo bufudunyezwa ngaphezu kwe-40 ℃ (njengokunyibilika) okanye ukusebenza. okusingqongileyo akuphuhli komoya kakuhle, kuya kwandisa ubutyhefu bomphunga, ukongeza ekusebenziseni inkqubo yokutshiza indawo yokwakhiwa komsebenzi, kunokukhokelela ekwandeni koxinzelelo lwamasuntswana amisiweyo emoyeni kwaye kubangele ubuthi.Umsebenzi kwindawo efanayo kufuneka unxibe imaski yegesi kunye nesixhobo sokuphefumla, ngaphandle koko, ukuphefumla okuphindaphindiweyo koxinzelelo olugqithisileyo lomphunga kuya kubangela ukwaliwa nokuphefumla.Ngokukhawuleza xa uyifumana esikhumbeni okanye ngaphakathi kweso, hlambulula ngamanzi kwaye uhlambe ulusu ngesepha namanzi.Ukupakishwa kwedrum yentsimbi, imveliso ayinakuguquguquka, inokuthuthwa ngokuhambelana nemimiselo echaphazelekayo yeekhemikhali eziqhelekileyo.Ngenxa yobume bemichiza esebenzayo ye-PMDI, kulula ukusabela ngamanzi ukuvelisa i-urea engabonakaliyo kunye nokukhulula i-carbon dioxide, ebangela i-drum barrel kunye nokwandisa i-viscosity.Ngoko ke, ngexesha lenkqubo yokugcina, isitya kufuneka sivalwe ngokungqongqo kwaye sizaliswe ngokukhuselwa kwe-nitrogen eyomileyo.I-PMDI kufuneka ibe kwindawo yokushisa (20 ~ 25 deg C) kwigumbi elinomoya opholileyo ogcinwe ngokungqongqo;Ukuba ukushisa kokugcina kuphantsi kakhulu (ngaphantsi kwe-5 deg C) kunokukhokelela ekubunjweni kwe-crystallization phenomenon, ngoko kufuneka ubeke ingqalelo kwi-antifreeze.Nje ukuba icrystallization yenzekile, kufuneka itshiswe kwaye inyibilikiswe kwi-70-80 ℃ ngaphambi kokusetyenziswa, kwaye ishukunyiswe kakuhle.Kufuneka ugweme ukugcinwa kwexesha elide ngaphezu kwe-50 ℃, Ukuze ugweme ukubunjwa kwezinto eziqinileyo ezinganyibilikiyo kunye nokwandisa i-viscosity.Ubomi beshelufu ye-PMDI ngunyaka we-1 phantsi kweemeko ezifanelekileyo zokugcina.
IiPropati zoMzi kunye nezeMichiza:Ulwelo olumdaka olubalayo olunevumba elinukayo.
Iintshukumo zoMoya naManzi:Iphendula ngamanzi ngokucothayo yenze i-scum enzima kwaye ikhulule igesi yecarbon dioxide.Uxinzelelo oluyingozi lunokwakheka ukuba isikhongozeli sivalekile.
Iprofayile yeReactivity:I-Polymethylene polyphenyl polyisocyanate idibana namanzi ngokucothayo yenze i-scum enzima kwaye ikhulule igesi yecarbon dioxide.Uxinzelelo oluyingozi lunokwakheka ukuba isikhongozeli sivalekile.I-base-catalysed reactions ye-isocyanates ene-alcohols kufuneka iqhutywe kwii-solvents ezingenayo.Ukusabela okunjalo ngokungabikho kwezinyibilikisi kaninzi kwenzeka ngobundlobongela obuqhushumbayo [Wischmeyer 1969].
Ingozi ethandabuzekayo carcinogen.
Ingozi yezempilo:Ukuphefumla kubangela ukuphefumla, ukungakhululeki kwesifuba, kunye nokunciphisa ukusebenza kwemiphunga;ukuphefumla, ukukhohlela, kunye nesikhohlela nazo zinokwenzeka.Ukudibana nolwelo kucaphukisa amehlo kunye nolusu.Ukusela kubangela ukucaphuka komlomo kunye nesisu.
Ingozi yoMlilo:Ukuziphatha eMlilweni: Izikhongozeli zinokugqabhuka.
Iprofayile yoKhuseleko:Ityhefu ephakathi ngokuyiginya.Yityhefu encinci ngokuphefumla.I-carcinogen ethandabuzekayo kunye nedatha yovavanyo ye-neoplastigenic ngendlela yokufakelwa.Xa ishushu ukuze ibole ikhupha imisi eyityhefu yeNOx.