Iodotrimethylsilane CAS 16029-98-4 Ubunyulu > 99.0% (Argentmetric Titration) Factory

Iodotrimethylsilane (i-CAS: i-16029-98-4) ene-asidi enzima (Me3Si) -isiseko esithambileyo (I) ibhondi ibonisa i-oksijeni eqinile kwi-ethers, i-esters, i-lactones, i-acetals, kunye nezinye iiathomu ezibandakanya i-athomu ye-oxygen njengeqela elisebenzayo.Ukusetyenziswa kwe-iodotrimethylsilane njenge-arhente yazisa i-facile cleavage ye-tert-butyl ester, inika i-carboxylic acid ehambelanayo kwisivuno esihle kakhulu.Iodotrimethylsilane isetyenziselwa ukuqaliswa kweqela le-trimethylsilyl kwi-organic synthesis.Ikwaluncedo kuhlalutyo lwe-chromatography yerhasi ngokuguqula utywala bube yi-silyl ether derivative, ngaloo ndlela bube buguquguquka ngakumbi kune-molecule yokuqala.Iodotrimethylsilane yireagent esebenzayo ye-ether, ester, carbamate, ketal, kunye nelactone cleavage.Ukwazisa iqela le-TMS, umz., i-TMS enol ethers.I-reagent ephambili yokukhusela okukhethiweyo kweqela le-N-Cbz phambi kwe-trimethyltin moiety.I-Reagent isanda kubikwa ukuba iguqule i-alyl- kunye ne-benzylphosphotriesters kwi-iodides ehambelanayo.Iodotrimethylsilane sisithintelo esiqhelekileyo kwimveliso yamayeza, esetyenziswa kakhulu ekudibaneni kwamachiza.Inokukhusela okanye ikhusele amaqela asebenzayo ngokukhethayo, isebenze njenge-arhente yokuthintela i-silane.Iodotrimethylsilane yi-reagent yemisebenzi emininzi esetyenziswa kwiindlela ezahlukeneyo zendalo.Isetyenziselwa ukuthengiswa kweekhompawundi ezimbalwa ezifana ne-lactones, i-ethers, i-acetals, kunye ne-carbamates kunye ne-trimethylsilylating agent ukwenzela ukuhlanganiswa kwe-silyl imino esters, i-alkyl kunye ne-alkenyl silanes, njl. iimpendulo ezininzi eziphilayo.Iodotrimethylsilane ingasetyenziselwa njenge-reagent eguquguqukayo kwi-dealkylation epholileyo ye-ethers, i-carboxylic esters, i-lactones, i-carbamates, i-acetals, i-phosphonate kunye ne-phosphate esters;ukuqhekeka kweepoxides, i-cyclopropyl ketones;ukuguqulwa kwe-vinyl phosphates kwi-vinyl iodides;Ukungathathi hlangothi kwe-nucleophilic reagent ye-halogen reaction reactions, i-carbonyl kunye ne-conjugate yokudibanisa ukuphendula;sebenzisa njenge-agent ye-trimethylsilylating yokwenziwa kwe-enol ethers, i-silyl imino esters, kunye ne-N-silylenamines, i-alkyl, i-alkenyl kunye ne-alkynyl silanes;I-Lewis acid catalyst yokwenza i-acetal formation, i-alkoxymethylation yee-ketones, ukusabela kwe-acetals kunye ne-silyl enol ethers kunye ne-alylsilanes;i-agent yokunciphisa i-epoxides, i-enediones, i-α-ketols, i-sulfoxides, kunye ne-sulfonyl halides;i-agent ekhupha amanzi kwi-oximes.