I-S-Phos CAS 657408-07-6 Ubunyulu > 98.0% (HPLC) Umgangatho ophezulu weFactory
Ubonelelo lwabavelisi, ubunyulu obuphezulu, iMveliso yoRhwebo
Igama leMichiza: S-PhosCAS: 657408-07-6
Igama leMchiza | 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl |
Izithethantonye | S-Phos;I-Dicyclohexyl(2',6'-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine |
Inombolo yeCAS | 657408-07-6 |
Inombolo yeCAT | RF-F27 |
Ubume beStokhwe | Ikhona evenkileni |
Ifomula yeemolekyuli | I-C26H35O2P |
Ubunzima beMolekyuli | 410.54 |
Indawo yokunyibilika | 164.0 ~ 166.0℃ |
Ukunyibilika | Inyibilika kwiChloroform |
Uphawu | Ruifu Chemical |
Into | Iinkcukacha |
Imbonakalo | Umgubo oMhlophe |
Ubunyulu / Indlela yokuHlalutya | >98.0% (HPLC) |
Izinyibilikisi | <0.50% |
NMR | Iyahambelana neSakhiwo |
Umgangatho woVavanyo | Umgangatho woShishino |
Ukusetyenziswa | Buchwald Ligands & Precatalysts |
Iphakheji: Ibhotile, ingxowa yefoyile yeAluminiyam, 25kg/Igubu lekhadibhodi, okanye ngokwemfuno yomthengi.
Imeko yoGcino:Gcina kwizikhongozeli ezivaliweyo kwindawo epholileyo neyomileyo;Khusela ukukhanya kunye nokufuma.
I-S-Phos (i-CAS: i-657408-07-6) i-air-stable, i-electron-rich biaryl phosphine ligand ephuhliswe liqela le-Buchwald ukuphucula i-reactivity ye-palladium catalysis ngexesha lokuphendula ukudibanisa.I-S-Phos inokusetyenziswa njenge-ligand kwezi nkqubo zilandelayo: I-Palladium catalyzed i-Suzuki-Miyaura yokuhlangana kwe-cross-coupling reaction phakathi kwe-Boc-protected aminomethyltrifluoroborate kunye ne-aryl chlorides okanye i-hetaryl chlorides ukwenza i-aminomethylarnes ehambelanayo.I-Palladium catalyzed i-Suzuki-Miyaura-cross-coupling reaction phakathi kwe-4-methyl-substituted piperidinylzinc reagent kunye ne-aryl okanye i-heteroaryl iodides eyahlukeneyo ukwenza i-piperidines eyahlukileyo.I-Intramolecular Suzuki-Miyaura ukudibanisa ukwenza i-18-membered macrocyclic ring ngexesha le-multi-step synthesis ye-riccardin C. Isetyenziswe ngokubambisana ne-palladium ukwenza i-catalyst esebenzayo kakhulu yokwakhiwa kwebhondi ye-CN.I-Ligand/palladium catalyst ye-Suzuki-Miyaura cross-coupling reactions jikelele.I-Ligand / palladium catalyst ye-Suzuki-Miyaura yokudibanisa i-aryltrifluoroborates kunye ne-aryl chlorides.I-Ligand / palladium catalyst ye-Suzuki-Miyaura reaction of heteroaryl halides kunye ne-heteroaryl boronic acids kunye ne-esters.I-Ligand/palladium catalyst ye-Kumada-Corriu cross-coupling reaction.I-Ligand / i-palladium catalyst ye-borylation ye-aryl halides kunye ne-pinacol borane.Ukudityaniswa kweSuzuki okubandakanya ii-amino acids.I-synthesis ye-biaryl derivatives ye-4-hydroxyphenyl glycine, i-tyrosine kunye ne-tryptophan.I-synthesis ye-adamantylzinc reagents efakwe endaweni esebenzisa i-Mg-insertion phambi kwe-zinc chloride.I-catalyst esebenzayo kakhulu ye-palladium-catalyzed Suzuki-Miyura reaction of heteroaryl halides kunye ne-heteroaryl boronic acids kunye ne-esters.