I-TBDMSCl CAS 18162-48-6 tert-Butyldimethylsilyl Chloride Purity >99.5% (GC) Factory
I-Shanghai Ruifu Chemical Co., Ltd. ngumenzi ohamba phambili kunye nomthengisi we-tert-Butyldimethylsilyl Chloride (TBDMSCl) (i-CAS: 18162-48-6) enomgangatho ophezulu, amandla okuvelisa iitoni ze-1400 ngonyaka.I-Ruifu inokubonelela ngenkonzo yehlabathi jikelele, ixabiso elikhuphisanayo, amanani amancinci kunye nesixa esikhulu esikhoyo.Thenga iTBDMSCl, Please contact: alvin@ruifuchem.com
Igama leMchiza | tert-Butyldimethylsilyl Chloride |
Izithethantonye | I-TBDMSCl;I-TBDMS-Cl;I-TBSCl;I-TBS-Cl;i-tert-Butyldimethylchlorosilane;i-tert-Butylchlorodimethylsilane;I-Chlorodimethyl-tert-butylsilane;tert-Butyl(dimethyl)silane Chloride;I-Chloro-tert-Butyldimethyl-Silane |
Inombolo yeCAS | 18162-48-6 |
Ubume beStokhwe | Kwi-Stock, iMveliso yeMisa |
Ifomula yeemolekyuli | I-C6H15ClSi |
Ubunzima beMolekyuli | 150.72 |
Indawo yokunyibilika | 86.0~90.0℃(lit.) |
Indawo yokubilisa | 124.0 ~ 126.0℃ @ 760mmHg |
Ukuxinana | 0.87 g/mL ku-20℃(lit.) |
Refractive Index | n20/D 1.46 |
Inovakalelo | Ukungenwa kukufuma |
Ukunyibilika | Inyibilika kwiDichloromethane, iEther, iToluene, iBenzene |
Ugcino Temp. | Ipholile kwaye yomile (≤10℃) |
I-COA kunye ne-MSDS | Iyafumaneka |
Uphawu | Ruifu Chemical |
Into | Iinkcukacha |
Imbonakalo | Umgubo weCrystalline oMhlophe |
Ubunyulu / Indlela yokuHlalutya | >99.5% (GC) |
Indawo yokunyibilika | 86.0~90.0℃ |
T-Butyldimethylsilanol | <0.30% (GC) |
Proton NMR Spectrum | Iyahambelana neSakhiwo |
Ukunyibilika kwi-CHCL3 | Ayinambala, Icacile, 25mg/ml Pass |
Ingqalelo | Ukuqonda ukufuma.Khusela ekukhanyeni kwaye Gcina kwindawo epholileyo eyomileyo (≤10 ℃) |
Umgangatho woVavanyo | Umgangatho woShishino |
Umqulu:Ibhotile, ingxowa yefoyile yeAluminiyam, 25kg/Igubu lekhadibhodi, okanye ngokwemfuno yomthengi.
Imeko yoGcino:Ukuqonda ukufuma.Gcina kwizikhongozeli ezivaliweyo kwindawo yokugcina impahla epholileyo neyomileyo (≤10℃) kude nezinto ezingahambelaniyo.Khusela ukukhanya kunye nokufuma.
Ukuhambisa ngenqanawe:Zisa kwihlabathi liphela ngeFedEx / DHL Express.Ukubonelela ngokukhawuleza nangokuthembekileyo.
Iikhowudi zoMngcipheko
I-R22 - Iyingozi xa iginyiwe
I-R35 - Ibangela ukutshisa okukhulu
R40 - Ubungqina obuncinci besiphumo somhlaza
I-R34 - Ibangela ukutsha
I-R10 -Inokutsha
I-R19 - Isenokwenza iiperoxide ezidubulayo
I-R11-Inokutsha kakhulu
R67 - Umphunga unokubangela ukozela kunye nesiyezi
I-R65 - Inobungozi: Inokubangela umonakalo emiphungeni ukuba iginyiwe
I-R63 - Ingozi enokwenzeka yokwenzakala kumntwana ongekazalwa
R48/20 -
I-R20/21/22 - Iyingozi ngokuphefumla, xa udibana nolusu naxa uginyiwe.
I-R45 - Inokubangela umhlaza
I-R23/24/25 - Ityhefu ngokuphefumla, xa udibana nesikhumba kwaye xa uginyiwe.
I-R37 - Iyacaphukisa inkqubo yokuphefumla
R36/37/38 - Ukucaphukisa emehlweni, inkqubo yokuphefumla kunye nolusu.
Inkcazelo yoKhuseleko
S26 - Xa udibana namehlo, hlambulula ngokukhawuleza ngamanzi amaninzi kwaye ufune iingcebiso zonyango.
S36/37/39 - Nxiba iimpahla ezifanelekileyo zokukhusela, iiglavu kunye nokukhusela amehlo / ubuso.
S46 - Ukuba uginyiwe, funa iingcebiso zonyango ngokukhawuleza kwaye ubonise esi sikhongozeli okanye ileyibhile.
S62 - Ukuba uginyiwe, musa ukugabha;funa iingcebiso zonyango ngokukhawuleza kwaye ubonise esi sikhongozeli okanye ileyibhile.
S45 - Kwimeko yengozi okanye ukuba uziva ungaphilanga, funa ingcebiso kagqirha ngokukhawuleza (bonisa ileyibhile nanini na kunokwenzeka.)
S25 - Kuphephe ukudibana namehlo.
S16 - Gcina kude kwimithombo yomlilo.
S28 - Emva kokudibana nolusu, hlamba ngoko nangoko ngeesepha ezininzi.
S27 - Khulula ngoko nangoko zonke iimpahla ezingcolisekileyo.
I-S33 -Thatha amanyathelo okhuseleko ngokuchasene nokukhutshwa okumileyo.
S29 - Musa ukuthulula kwimisele.
S53-Kuphephe ukuvezwa-fumana imiyalelo ekhethekileyo phambi kokusetyenziswa.
S36/37 -Nxiba iimpahla ezifanelekileyo zokukhusela kunye neeglavu.
Ii-ID ze-UN UN 2925 4.1/PG 2
WGK eJamani 2
RTECS VV2000000
FLUKA BRAND F IIKHOWUDI 10-21
TSCA Ewe
Ikhowudi yeHS 2931900090
Inqaku Lengozi Linokutsha/I-Corrosion/Inobuzaza bokufuma
Udidi lweengozi 4.1
Ukupakisha Iqela III
I-tert-Butyldimethylsilyl Chloride (TBDMSCl) (i-CAS: i-18162-48-6) i-organosilicon i-compound enokuthi isetyenziswe njenge-reagent ekhuselekileyo yokukhusela i-alcohol, i-amines, i-amides, kunye ne-carboxylic acids eyahlukeneyo.I-tert-Butyldimethylsilyl Chloride yikhemikhali esetyenziselwa ukukhusela i-alcohols ngexesha le-organic synthesis.Isebenza njengesixhobo esikhuselayo esikhuselayo se-amines, i-amide kunye ne-alcohol.
I-TBDMSCl yi-agent ekhuselayo ye-organosilicon ethintelweyo, esetyenziswa kakhulu ekudityanisweni kwamachiza okuqala.Isetyenziswe njengeqela elikhuselayo le-hydroxyl kwi-synthesis ye-ribonucleosides, kwaye i-oxidant kunye ne-decyanide.
Izixhobo ezincedisayo zokwenziwa kwe-prostaglandin, ii-antibiotics, iziyobisi ze-hypolipidemic, i-lovastatin kunye ne-simvastatin esetyenziswa njenge-pharmaceutical intermediates kwaye isetyenziswa kwi-organic synthesis, njenge-agent ekhuselayo ye-hydroxyl kwi-organic synthesis esetyenziswa kwi-intermediates kunye ne-organic synthesis, yi-agent ekhuselayo ye-silicone. , esetyenziswa ngokubanzi ekudityanisweni kwamachiza okuqala.Isetyenziswe njengeqela elikhuselayo kwiqela le-hydroxyl kwi-synthesis ye-ribonucleosides, kunye ne-oxidant kunye ne-decyanating agent.isilanizer.Njenge-agent ekhuselayo ye-hydroxyl kwi-organic synthesis, i-reagents derivatization isetyenziselwa ukuhlalutya kunye nokulungiselela.Khusela utywala obuphezulu.Iphendula kunye neealkoholi ukwenza i-silicone ether.Ukumiselwa kokuhambelana kwe-cholesterol derivatives.
Inkcazo ye-ChEBI: I-Tert-butyldimethylsilyl chloride yi-silyl chloride equka i-athomu yesilicon ephakathi ebotshelelwe ngokudibeneyo kwikloro enye, i-tert-butyl kunye namaqela amabini e-methyl.I-tert-Butyldimethylsilyl chloride yi-agent ephumayo esetyenziswa kwi-gas chromatography/mass spectrometry izicelo.Inendima njenge-reagent yechromatographic.
I-tert-Butyldimethylsilyl Chloride (TBDMSCl) (i-CAS: i-18162-48-6) yenziwe ngokuphendula kwe-tert-butyllithium kunye ne-dichlorodimethylsilane.
Isisombululo sepentane se-dichlorodimethylsilane sapholiswa ukuya ku-0℃, kwaye isisombululo sepentane se-tert-butyllithium songezwa ngokuxutywa ngokuxutywa phantsi kwenitrogen.Ubushushu bugcinwe kwi-0 ℃, buxutywe kwi-1.5 h kwaye emva koko bufudunyezwe kwi-25 ℃, kwaye ukusabela kwaqhubeka kwi-48 h.I-Distillation, qokelela i-125℃ (97.5kPa) amaqhezu, yima ukuqinisa, kwaye ufumane i-tert-butyldimethylsilyl chloride.Isivuno sama-70%.