1,1′-Bis (diphenylphosphino) Ferrocene CAS 12150-46-8 DPPF Mimọ> 98.0% Fe 9.7 ~ 10.4%
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Orukọ Kemikali | 1,1'-Bis (diphenylphosphino) ferrocene |
Awọn itumọ ọrọ sisọ | 1,1'-Ferrocenebis (diphenylphosphine);DPPF |
Nọmba CAS | 12150-46-8 |
NỌMBA CAT | RF-PI2275 |
Iṣura Ipo | Ninu Iṣura, Iwọn iṣelọpọ Ti o to Awọn Toonu |
Fọọmu Molecular | C34H28FeP2 |
Òṣuwọn Molikula | 554.39 |
Ni imọlara | Afẹfẹ Ifamọ |
Solubility ninu Omi | Ailopin ninu Omi |
Solubility | Soluble ni Chloroform |
Hydrolytic ifamọ | 7: Fesi Laiyara Pẹlu Ọrinrin/Omi |
Brand | Ruifu Kemikali |
Nkan | Awọn pato |
Ifarahan | Yellow to Orange Powder |
Mimọ / Analysis Ọna | > 98.0% (Titration Chelometric) |
Irin (Fe) | 9.7 ~ 10.4% (Titration nipasẹ Na2S2O3) |
Erogba nipa Elemental Analysis | 71.1 ~ 76.2% |
Ojuami Iyo | 181.0 ~ 183.0 ℃ |
Omi nipa Karl Fischer | <0.50% |
Solubility ni CHCL3 | Yellow to Orange, Clear(2.5%) Pass |
Infurarẹẹdi julọ.Oniranran | Ni ibamu si Eto |
Igbeyewo Standard | Standard Enterprise |
Package: Igo, apo bankanje aluminiomu, 25kg / Paali ilu, tabi gẹgẹ bi ibeere alabara
Ipò Ìpamọ́:Fipamọ sinu awọn apoti ti a fi edidi ni itura ati ibi gbigbẹ;Dabobo lati ina ati ọrinrin
1,1'-Bis (diphenylphosphino) ferrocene (CAS: 12150-46-8), Suzuki-Miyaura Cross Coupling Reaction, Ligands, Organic Metallic catalysts.Ni gbogbogbo ti a lo ninu awọn aati kemikali atẹle eyun Buchwald-Hartwig Cross Coupling Reaction, Carbonylations, Ene Reaction, Heck Reaction, Negishi Coupling, Sonogashira Coupling, Stille Coupling, Suzuki-Miyaura Coupling, Tsuji-Trost Reaction.Awọn ohun elo idapọmọra iṣakojọpọ ti o wọpọ ti a lo ninu iṣelọpọ, ni imurasilẹ ṣe awọn eka pẹlu awọn irin oriṣiriṣi, ie nigbati o ba n ṣe pẹlu acetonitrile tabi awọn eka benzonitrile ti PdCl2 o jẹ fọọmu (dppf) PdCl2, eyiti o jẹ reagent olokiki fun awọn aati idapọpọ palladium-catalyzed.Awọn itọsẹ furan ti a ṣe iṣẹ-ara aramada ni a pese sile nipasẹ ọna kika Pd-phosphine CC ati dida CO mnu.Ligand lo ninu a Pd (II) -catalyzed agbelebu-pipapọ kolaginni ti oxazepine oruka awọn ọna šiše.1,1'-Bis (diphenylphosphino) ferrocene n ṣiṣẹ bi ligand ni catalysis isokan.O ti wa ni lo bi awọn kan ligand fun ruthenium-catalyzed greener amine kolaginni lati amines ati alcohols nipa hydrogen-yiya.O tun wa ni iṣẹ bi ligand fun Buchwald-Hartwig agbelebu.Siwaju sii, o ti wa ni lilo ninu awọn kolaginni ti ipoidojuko yellow bi daradara bi awọn Ibiyi ti awọn eka pẹlu orisirisi awọn irin bi palladium kiloraidi.Ni afikun si eyi, o ṣe iranṣẹ bi reagent fun awọn aati idapọmọra palladium-catalyzed ati tun ṣe ipa pataki ninu iṣesi Suzuki.