Iodotrimethylsilane CAS 16029-98-4 Mimọ> 99.0% (Titration Argentmetric) Ile-iṣẹ

Iodotrimethylsilane (CAS: 16029-98-4) eyiti o ni acid lile (Me3Si) -ipilẹ asọ (I) mnu ṣe afihan oxygenophilicity ti o lagbara si awọn ethers, esters, lactones, acetals, ati awọn ohun elo miiran ti o kan atomu atẹgun bi ẹgbẹ iṣẹ kan.Lilo iodotrimethylsilane gẹgẹbi oluranlowo mu ifasilẹ irọrun ti ester tert-butyl, fifun acid carboxylic ti o baamu ni ikore to dara julọ.A lo Iodotrimethylsilane fun ifihan ti ẹgbẹ trimethylsilyl ni iṣelọpọ Organic.O tun wulo fun itupalẹ chromatography gaasi nipa yiyipada oti sinu itọsẹ silyl ether, nitorinaa jẹ ki o ni iyipada diẹ sii ju moleku atilẹba lọ.Iodotrimethylsilane jẹ reagent to munadoko fun ether, ester, carbamate, ketal, ati lactone cleavage.Fun iṣafihan ẹgbẹ TMS, fun apẹẹrẹ, TMS enol ethers.Aṣoju bọtini fun idabobo yiyan ti ẹgbẹ N-Cbz kan ni iwaju ohun elo trimethyltin kan.Laipẹ ni ijabọ Reagent lati ṣe iyipada allyl- ati benzylphosphosphotriesters si awọn iodides ti o baamu.Iodotrimethylsilane jẹ aṣoju ìdènà aṣoju ni iṣelọpọ elegbogi, ti a lo ni lilo pupọ ni awọn iṣelọpọ ti awọn oogun.O le ṣe aabo tabi daabobo awọn ẹgbẹ iṣẹ ni yiyan, ṣiṣẹ bi aṣoju dina silane.Iodotrimethylsilane jẹ reagent multipurpose ti a lo ni ọpọlọpọ awọn aati Organic.O ti wa ni lilo fun awọn dealkylation ti diẹ agbo bi lactones, ethers, acetals, ati carbamates ati trimethylsilylating oluranlowo fun awọn kolaginni ti silyl imino esters, alkyl ati alkenyl silanes, bbl O tun ìgbésẹ bi a Lewis acid ayase ati bi a atehinwa oluranlowo ni ọpọlọpọ awọn aati Organic.Iodotrimethylsilane le ṣee lo bi awọn kan wapọ reagent fun awọn ìwọnba dealkylation ti ethers, carboxylic esters, lactones, carbamates, acetals, phosphonate ati fosifeti esters;cleavage ti epoxides, cyclopropyl ketones;iyipada ti fainali phosphates si fainali iodides;Reagent nucleophilic didoju fun awọn aati paṣipaarọ halogen, carbonyl ati awọn aati afikun conjugate;lo bi a trimethylsilylating oluranlowo fun Ibiyi ti enol ethers, silyl imino esters, ati N-silylenamines, alkyl, alkenyl ati alkynyl silanes;Lewis acid ayase fun dida acetal, α- alkoxymethylation ti awọn ketones, fun awọn aati ti acetals pẹlu silyl enol ethers ati allylsilanes;idinku aṣoju fun epoxides, ediones, α-ketols, sulfoxides, ati sulfonyl halides;Dehydrating oluranlowo fun oximes.