PyBrOP CAS 132705-51-2 Mimo> 99.0% (HPLC) Awọn Atunṣe Isopọpọ Ile-iṣẹ
Shanghai Ruifu Kemikali Co., Ltd jẹ olupilẹṣẹ asiwaju ti Bromotripyrrolidinophosphonium Hexafluorophosphate (PyBrOP) (CAS: 132705-51-2) pẹlu didara to gaju.Kemikali Ruifu n pese lẹsẹsẹ ti awọn reagents aabo ati awọn isọdọkan.Ruifu le pese ifijiṣẹ agbaye, idiyele ifigagbaga, kekere ati awọn iwọn olopobobo ti o wa.Ra PyBrOP,Please contact: alvin@ruifuchem.com
Orukọ Kemikali | Bromotripyrrolidinophosphonium Hexafluorophosphate |
Awọn itumọ ọrọ sisọ | PyBrOP;Bromo-tris-Pyrrolidinophosphonium Hexafluorophosphate;Bromotri (1-Pyrrolidinyl) phosphonium Hexafluorophosphate |
Iṣura Ipo | Ni Iṣura, Ibi iṣelọpọ |
Nọmba CAS | 132705-51-2 |
Ilana molikula | C12H24BrF6N3P2 |
Òṣuwọn Molikula | 466,19 g / mol |
Ojuami Iyo | > 100 ℃ |
Ni imọlara | Ọrinrin Sensitive, Ooru Sensitive |
Ibi ipamọ otutu. | Itura & Ibi Gbẹ (≤-20℃) |
COA & MSDS | Wa |
Ẹka | Awọn Reagents Apapo |
Brand | Ruifu Kemikali |
Awọn nkan | Ayewo Standards | Awọn abajade |
Ifarahan | Funfun lati Pa-White Crystalline Powder | Ibamu |
Kloride (Cl) | ≤0.02% | <0.02% |
Pipadanu lori Gbigbe | <0.50% | 0.13% |
Awọn Irin Eru (Pb) | ≤20ppm | <20ppm |
Mimọ / Analysis Ọna | > 99.0% (HPLC) | 99.6% |
31P, 19F, 1H NMR julọ.Oniranran | Ni ibamu | Ni ibamu |
Itupalẹ Alakọbẹrẹ (C,H,N, P, F, Br) | Ni ibamu | Ni ibamu |
ESI | Ni ibamu | Ni ibamu |
Ipari | Ọja naa ti ni idanwo & ni ibamu pẹlu awọn pato |
Apo:Igo, apo apamọwọ Aluminiomu, 25kg / Paali Drum, tabi gẹgẹbi ibeere alabara.
Ipò Ìpamọ́:Fipamọ sinu awọn apoti edidi ni itura ati ki o gbẹ (≤-20℃) ile itaja kuro lati awọn nkan ti ko ni ibamu.Dabobo lati ina ati ọrinrin.
Gbigbe:Firanṣẹ si agbaye nipasẹ FedEx / DHL Express.Pese ifijiṣẹ yarayara ati igbẹkẹle.
Bawo ni lati Ra?Jọwọ kan siDr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com
15 Ọdun Iriri?A ni diẹ sii ju ọdun 15 ti iriri ni iṣelọpọ ati okeere ti ọpọlọpọ awọn agbedemeji elegbogi didara tabi awọn kemikali to dara.
Awọn ọja akọkọ?Ta si ọja ile, North America, Europe, India, Korea, Japanese, Australia, ati be be lo.
Awọn anfani?Didara to gaju, idiyele ifarada, awọn iṣẹ alamọdaju ati atilẹyin imọ-ẹrọ, ifijiṣẹ yarayara.
DidaraIdaniloju?Eto iṣakoso didara to muna.Awọn ohun elo ọjọgbọn fun itupalẹ pẹlu NMR, LC-MS, GC, HPLC, ICP-MS, UV, IR, OR, KF, ROI, LOD, MP, Clarity, Solubility, Microbial limit test, bbl
Awọn apẹẹrẹ?Pupọ awọn ọja pese awọn apẹẹrẹ ọfẹ fun igbelewọn didara, idiyele gbigbe yẹ ki o san nipasẹ awọn alabara.
Ayẹwo ile-iṣẹ?Ayẹwo ile-iṣẹ kaabo.Jọwọ ṣe ipinnu lati pade ni ilosiwaju.
MOQ?Ko si MOQ.Ibere kekere jẹ itẹwọgba.
Akoko Ifijiṣẹ? Ti o ba wa laarin ọja iṣura, iṣeduro ifijiṣẹ ọjọ mẹta.
Gbigbe?Nipa Express (FedEx, DHL), nipasẹ Air, nipasẹ Okun.
Awọn iwe aṣẹ?Lẹhin iṣẹ tita: COA, MOA, ROS, MSDS, ati bẹbẹ lọ ni a le pese.
Aṣa Synthesis?Le pese awọn iṣẹ iṣelọpọ aṣa lati baamu awọn iwulo iwadii rẹ dara julọ.
Awọn ofin sisan?Iwe risiti Proforma yoo firanṣẹ ni akọkọ lẹhin ijẹrisi aṣẹ, ti ifi alaye banki wa sinu.Isanwo nipasẹ T/T (Telex Gbigbe), PayPal, Western Union, ati bẹbẹ lọ.
Awọn koodu ewu
R36 / 37/38 - Irritating si oju, eto atẹgun ati awọ ara.
R34 - Okunfa Burns
Apejuwe Abo
S26 - Ni ọran ti olubasọrọ pẹlu awọn oju, fi omi ṣan lẹsẹkẹsẹ pẹlu ọpọlọpọ omi ki o wa imọran iṣoogun.
S36 - Wọ aṣọ aabo to dara.
S45 - Ni ọran ti ijamba tabi ti o ba ni ailara, wa imọran iṣoogun lẹsẹkẹsẹ (fi aami han nigbakugba ti o ṣee ṣe.)
S36/37/39 - Wọ aṣọ aabo to dara, awọn ibọwọ ati aabo oju / oju.
S27 - Mu gbogbo aṣọ ti o ti doti kuro lẹsẹkẹsẹ.
WGK Germany 3
FLUKA BRAND F CODES 10-21
HS koodu 2933990099
Bromotripyrrolidinophosphonium Hexafluorophosphate (PyBrOP) (CAS: 132705-51-2) jẹ reagent iduroṣinṣin fun idapọ ti N-Methylamino acids ni iṣelọpọ peptide.Ti a lo fun iṣelọpọ ti awọn depsipeptides.
PyBroP jẹ reagent idapọ peptide kan ti o ti lo ninu iṣelọpọ ti tumo rostate kan pato peptide-peptoid arabara prodrugs.Reagent idapọ peptide ifaseyin dara fun α, α-dialkyl amino acids.
Ayase fun: kolaginni ti akọkọ amides, taara dehydrative phosphonium agbelebu coupling, taara arylation, pyrrolidide formations nipasẹ phosphonium iyọ sipo reagents.
PyBroP jẹ iyọ phosphonium ti a lo ninu kemistri idapọ peptide, ti o jọra si PyCloP.PyBroP ṣe afihan ṣiṣe ti o ga julọ ni sisọpọ awọn amino acids N-methylated ati α, amino acids ti o ni idapada, pẹlu awọn eso ti o dara julọ, ko si epimerisation ati awọn oṣuwọn ifaseyin iyara.PyBroP jẹ iduro to duro ti o le ṣee lo ninu ilana-ikoko kan ati pe o jẹ tiotuka ninu awọn nkanmimu ti o wọpọ ti a lo fun kemistri asopọpọ peptide.PyBroP jẹ itọsẹ ti phosphonium coupling reagent BOP ṣugbọn o ni nkan pyrrolidine kan ni aaye dimethylamine ti BOP.Ero ti o wa lẹhin apẹrẹ ti PyBroP ni lati ṣe idiwọ iṣelọpọ ti majele pupọ ati ọja carcinogenic nipasẹ HMPA ti ipilẹṣẹ pẹlu BOP, ṣugbọn pẹlu awọn iṣe afiwera.
PyBroP le ṣee lo bi reagent idapọ: Fun Suzuki – Miyaura agbelebu-pipapọ ti phenols ati arylboronic acids lati ṣepọ biaryls ati heterobiaryls.Lati ṣiṣẹ awọn pyrimidines (ti a ṣepọ lati 3,4-dihydropyrimidin-2 (1H) -awọn (DHPMs) nipasẹ Kappe dehydrogenation) nipa lilo orisirisi awọn nucleophiles.Lati ṣepọ awọn foramidines nipa sisọpọ pẹlu orisirisi amines akọkọ ati N, N-diisopropylethylamine.O tun le ṣee lo bi ohun mimuuṣiṣẹpọ reagent: Fun imuṣiṣẹ ti mnu C-OH ni awọn heterocycles tautomerizable lati ṣe iyo phosphonium eyiti o ṣe iranlọwọ fun iṣọpọ Sonogashira ti awọn heterocycles pẹlu ọpọlọpọ awọn alkynes.Fun imuṣiṣẹ ikoko kan-ikoko ti iwe adehun CO ni phenols ati iṣesi idapọ siwaju pẹlu oxide phosphine tabi phosphite lati ṣẹda awọn iwe CP.