TBDMSCl CAS 18162-48-6 tert-Butyldimethylsilyl Chloride Purity>99.5% (GC) Ile-iṣẹ
Shanghai Ruifu Kemikali Co., Ltd jẹ olupilẹṣẹ asiwaju ati olupese ti tert-Butyldimethylsilyl Chloride (TBDMSCl) (CAS: 18162-48-6) pẹlu didara giga, agbara iṣelọpọ 1400 tons fun ọdun kan.Ruifu le pese ifijiṣẹ agbaye, idiyele ifigagbaga, kekere ati awọn iwọn olopobobo ti o wa.Ra TBDMSCl, Please contact: alvin@ruifuchem.com
Orukọ Kemikali | tert-Butyldimethylsilyl kiloraidi |
Awọn itumọ ọrọ sisọ | TBDMSCl;TBDMS-Cl;TBSCl;TBS-Cl;tert-Butyldimethylchlorosilane;tert-Butylchlorodimethylsilane;Chlorodimethyl-tert-butylsilane;tert-Butyl (dimethyl) silane kiloraidi;Chloro-tert-Butyldimethyl-Silane |
Nọmba CAS | 18162-48-6 |
Iṣura Ipo | Ni Iṣura, Ibi iṣelọpọ |
Fọọmu Molecular | C6H15ClSi |
Òṣuwọn Molikula | 150.72 |
Ojuami Iyo | 86.0 ~ 90.0 ℃ (tan.) |
Ojuami farabale | 124.0 ~ 126.0 ℃ @ 760mmHg |
iwuwo | 0.87 g/mL ni 20 ℃ (tan.) |
Atọka Refractive | n20 / D 1,46 |
Ni imọlara | Ọrinrin Sensitive |
Solubility | Soluble ni Dichloromethane, Ether, Toluene, Benzene |
Ibi ipamọ otutu. | Itura ati Gbẹ (≤10℃) |
COA & MSDS | Wa |
Brand | Ruifu Kemikali |
Nkan | Awọn pato |
Ifarahan | Funfun Crystalline Powder |
Mimọ / Analysis Ọna | > 99.5% (GC) |
Ojuami Iyo | 86.0 ~ 90.0 ℃ |
T-Butyldimethylsilanol | <0.30% (GC) |
Proton NMR julọ.Oniranran | Ni ibamu si Eto |
Solubility ni CHCL3 | Alailowaya, Ko o, 25mg/ml Pass |
Ifarabalẹ | Ifarabalẹ ọrinrin.Daabobo lati ina ati Fipamọ ni aaye gbigbẹ tutu (≤10℃) |
Igbeyewo Standard | Standard Enterprise |
Apo:Igo, apo apamọwọ Aluminiomu, 25kg / Paali Drum, tabi gẹgẹbi ibeere alabara.
Ipò Ìpamọ́:Ifarabalẹ ọrinrin.Fipamọ sinu awọn apoti edidi ni itura ati ki o gbẹ (≤10℃) ile-itaja kuro lati awọn nkan ti ko ni ibamu.Dabobo lati ina ati ọrinrin.
Gbigbe:Firanṣẹ si agbaye nipasẹ FedEx / DHL Express.Pese ifijiṣẹ yarayara ati igbẹkẹle.
Awọn koodu ewu
R22 - ipalara ti o ba gbe
R35 - O fa awọn gbigbona nla
R40 - Ẹri to lopin ti ipa carcinogenic
R34 - Okunfa Burns
R10 - flammable
R19 - Le dagba awọn ibẹjadi peroxides
R11 - Gíga flammable
R67-Vapors le fa drowsiness ati dizziness
R65 - ipalara: Le fa ibaje ẹdọfóró ti o ba gbe mì
R63 - Owun to le ewu ipalara si awọn unborn ọmọ
R48/20 -
R20/21/22 - Ipalara nipasẹ ifasimu, ni olubasọrọ pẹlu awọ ara ati ti o ba gbe.
R45 - Le fa akàn
R23/24/25 - Majele nipasẹ ifasimu, ni olubasọrọ pẹlu awọ ara ati ti o ba gbe.
R37 - Irritating si eto atẹgun
R36 / 37/38 - Irritating si oju, eto atẹgun ati awọ ara.
Apejuwe Abo
S26 - Ni ọran ti olubasọrọ pẹlu awọn oju, fi omi ṣan lẹsẹkẹsẹ pẹlu ọpọlọpọ omi ki o wa imọran iṣoogun.
S36/37/39 - Wọ aṣọ aabo to dara, awọn ibọwọ ati aabo oju / oju.
S46 - Ti o ba gbemi, wa imọran iṣoogun lẹsẹkẹsẹ ki o ṣafihan apoti yii tabi aami.
S62 - Ti o ba gbemi, ma ṣe fa eebi;wa imọran iṣoogun lẹsẹkẹsẹ ki o ṣafihan apoti yii tabi aami.
S45 - Ni ọran ti ijamba tabi ti o ba ni ailara, wa imọran iṣoogun lẹsẹkẹsẹ (fi aami han nigbakugba ti o ṣee ṣe.)
S25 - Yago fun olubasọrọ pẹlu awọn oju.
S16 - Jeki kuro lati awọn orisun ti iginisonu.
S28 - Lẹhin olubasọrọ pẹlu awọ ara, wẹ lẹsẹkẹsẹ pẹlu ọpọlọpọ ọṣẹ-suds.
S27 - Mu gbogbo aṣọ ti o ti doti kuro lẹsẹkẹsẹ.
S33 - Ṣe awọn ọna iṣọra lodi si awọn idasilẹ aimi.
S29 - Ma ṣe ofo sinu ṣiṣan.
S53 - Yago fun ifihan - gba awọn ilana pataki ṣaaju lilo.
S36/37 - Wọ aṣọ aabo ati awọn ibọwọ to dara.
UN ID UN 2925 4.1/PG 2
WGK Germany 2
RTECS VV2000000
FLUKA BRAND F CODES 10-21
TSCA Bẹẹni
HS koodu 2931900090
Akọsilẹ ewu Flammable/Ibajẹ/Ọrinrin Sensitive
Ewu Kilasi 4.1
Iṣakojọpọ Ẹgbẹ III
tert-Butyldimethylsilyl Chloride (TBDMSCl) (CAS: 18162-48-6) jẹ agbo organosilicon kan ti o le ṣee lo bi idabobo to wapọ fun awọn ọti, amines, amides, ati awọn acids carboxylic orisirisi.tert-Butyldimethylsilyl Chloride jẹ kemikali ti a lo lati daabobo awọn ọti lakoko iṣelọpọ Organic.O ṣe bi reagent aabo to wapọ fun amines, amides ati awọn oti.
TBDMSCl jẹ oluranlowo aabo organosilicon sterically, eyiti o jẹ lilo pupọ ni iṣelọpọ ti awọn oogun atilẹba.O ti wa ni lo bi awọn kan aabo ẹgbẹ fun hydroxyl ni kolaginni ti ribonucleosides, ati ki o jẹ tun ẹya oxidant ati decyanide.
Awọn ohun elo aise oluranlọwọ fun iṣelọpọ ti prostaglandins, awọn oogun apakokoro kan, awọn oogun hypolipidemic lovastatin ati simvastatin ti a lo bi awọn agbedemeji elegbogi ati ti a lo ninu iṣelọpọ Organic, bi oluranlowo aabo hydroxyl ni iṣelọpọ Organic ti a lo ninu awọn agbedemeji oogun ati iṣelọpọ Organic, jẹ aṣoju aabo silikoni ti o ni idiwọ sterile. , o gbajumo ni lilo ninu awọn kolaginni ti atilẹba oloro.O ti wa ni lo bi awọn kan aabo ẹgbẹ fun awọn hydroxyl ẹgbẹ ninu awọn kolaginni ti ribonucleosides, ati ki o jẹ tun ẹya oxidant ati decyanating oluranlowo.silanizer.Gẹgẹbi oluranlowo aabo hydroxyl ni iṣelọpọ Organic, awọn reagents itọsẹ ni a lo fun itupalẹ ati igbaradi.Dabobo awọn ọti-lile giga.Reacts pẹlu alcohols lati dagba silikoni ether.Ipinnu ti conformation ti idaabobo awọ awọn itọsẹ.
ChEBI Itumọ: Tert-butyldimethylsilyl kiloraidi jẹ kiloraidi silyl ti o ni atomu silikoni aarin kan ti a so pọ mọ chloro kan, tert-butyl kan ati awọn ẹgbẹ methyl meji.tert-Butyldimethylsilyl kiloraidi jẹ aṣoju itọsẹ ti a lo ninu awọn ohun elo kiromatofi gaasi/mass spectrometry.O ni ipa kan bi reagent chromatographic.
tert-Butyldimethylsilyl Chloride (TBDMSCl) (CAS: 18162-48-6) jẹ iṣelọpọ nipasẹ iṣesi ti tert-butyllithium pẹlu dichlorodimethylsilane.
Ojutu pentane ti dichlorodimethylsilane ti tutu si 0℃, ati ojutu pentane ti tert-butyllithium ni a ṣafikun ni sisọ silẹ pẹlu gbigbọn labẹ nitrogen.A tọju iwọn otutu ni 0 ℃, aruwo fun awọn wakati 1.5 ati lẹhinna kikan si 25 ℃, ati pe iṣesi naa tẹsiwaju fun awọn wakati 48.Distillation, gba awọn ida 125 ℃ (97.5kPa), duro lati fi idi mulẹ, ati gba kiloraidi tert-butyldimethylsilyl.Imujade 70%.