1,1′-Bis(diphenylphosphino)ferrocene CAS 12150-46-8 DPPF Purity >98.0% Fe 9.7~10.4%
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Igama Lekhemikhali | 1,1'-Bis(diphenylphosphino)ferrocene |
Omqondofana | 1,1'-Ferrocenebis(diphenylphosphine);I-DPPF |
Inombolo ye-CAS | 12150-46-8 |
Inombolo yeCAT | I-RF-PI2275 |
Isimo Sesitoko | Esitokweni, Isikali Sokukhiqiza Sifinyelela Kumathani |
I-Molecular Formula | I-C34H28FeP2 |
Isisindo samangqamuzana | 554.39 |
Kuyazwela | Kuyazwela emoyeni |
Ukuncibilika Emanzini | Ayincibiliki Emanzini |
Ukuncibilika | Incibilika ku-Chloroform |
Ukuzwela kwe-Hydrolytic | 7: Isabela Kancane Ngomswakama/Amanzi |
Ibhrendi | I-Ruifu Chemical |
Into | Imininingwane |
Ukubukeka | Okuphuzi ukuya ku-Orange powder |
Ukuhlanzeka / Indlela Yokuhlaziya | >98.0% (Chelometric Titration) |
Insimbi (Fe) | 9.7~10.4% (Titration by Na2S2O3) |
Ikhabhoni ngokuhlaziywa kwe-Elemental | 71.1~76.2% |
I-Melting Point | 181.0~183.0℃ |
Amanzi nguKarl Fischer | <0.50% |
I-Solubility ku-CHCL3 | Okuphuzi ukuya kokuwolintshi, Ukudlula Okucacile(2.5%) |
I-Infrared Spectrum | Ivumelana Nesakhiwo |
Izinga Lokuhlola | I-Enterprise Standard |
Iphakheji: Ibhodlela, isikhwama se-Aluminium foil, 25kg/Cardboard Drum, noma ngokwemfuneko yekhasimende
Isimo Sesitoreji:Gcina ezitsheni ezivaliwe endaweni epholile neyomile;Vikela ekukhanyeni nakumswakama
I-1,1'-Bis(diphenylphosphino)ferrocene (CAS: 12150-46-8), Suzuki-Miyaura Cross Coupling Reaction, Ligands, Organic Metallic Catalysts.Ngokuvamile kusetshenziswa ekuphenduleni kwamakhemikhali okulandelayo okuyi-Buchwald-Hartwig Cross Coupling Reaction, Carbonylations, Ene Reaction, Heck Reaction, Negishi Coupling, Sonogashira Coupling, Stille Coupling, Suzuki-Miyaura Coupling, Tsuji-Trost Reaction.Izicelo Okuhlanganisa ukusetshenziswa okuvamise ukuhlanganisa ekuhlanganiseni, kwenza kalula izingxube ezinezinsimbi ezihlukahlukene, okungukuthi uma kusabela nge-acetonitrile noma i-benzonitrile complexes ye-PdCl2 yakha (dppf)PdCl2, okuyi-reagent edumile yokusabela kokuhlangana kwe-palladium-catalyzed.Okuphuma kokuphuma kwe-furan okunoveli okusebenzayo kwalungiswa nge-Pd-phosphine sequential CC kanye nokwakheka kwebhondi ye-CO.I-Ligand esetshenziswe ku-Pd(II)-catalyzed cross-coupling synthesis yezinhlelo zendandatho ye-oxazepine.I-1,1'-Bis(i-diphenylphosphino)i-ferrocene isebenza njenge-ligand ku-homogeneous catalysis.Isetshenziswa njenge-ligand ye-ruthenium-catalyzed greener amine synthesis evela kuma-amine nama-alcohol ngokuboleka i-hydrogen.Iphinde isetshenziswe njenge-ligand ye-Buchwald-Hartwig cross coupling.Ngaphezu kwalokho, isetshenziselwa ukuhlanganiswa kwenhlanganisela yokuhlanganisa kanye nokwakhiwa kwezakhiwo ezinezinsimbi ezihlukahlukene ezifana ne-palladium chloride.Ngaphezu kwalokhu, isebenza njenge-reagent ye-palladium-catalyzed coupling reactions futhi idlala indima ebalulekile ekuphenduleni kwe-Suzuki.