I-4-Dimethylaminopyridine DMAP CAS 1122-58-3 Ubumsulwa >99.0% (HPLC) I-Highly Efficiency Catalyst
I-Shanghai Ruifu Chemical Co., Ltd. ingumkhiqizi ohamba phambili we-4-Dimethylaminopyridine (DMAP) (CAS: 1122-58-3) enekhwalithi ephezulu.I-Ruifu Chemical ingahlinzeka ngokulethwa komhlaba wonke, amanani ancintisanayo, amanani amancane nayinqwaba atholakalayo.Thenga i-DMAP, Please contact: alvin@ruifuchem.com
Igama Lekhemikhali | 4-Dimethylaminopyridine |
Omqondofana | I-DMAP;4-(Dimethylamino)pyridine;N-(4-Pyridyl)dimethylamine;N,N-Dimethylpyridin-4-Amine;N,N-Dimethyl-4-Pyridinamine;i-gamma-(Dimethylamino) pyridine |
Inombolo ye-CAS | 1122-58-3 |
Isimo Sesitoko | Esitokweni, Amandla Okukhiqiza Amathani angama-40 ngenyanga |
I-Molecular Formula | I-C7H10N2 |
Isisindo samangqamuzana | 122.17 |
I-Melting Point | 110.0~114.0℃ |
Iphuzu elibilayo | 190℃/150 mmHg |
Ukuminyana | 0.906 g/mL ku-25℃ |
I-Refractive Index | n20/D 1.431 |
I-Solubility ku-Methanol | I-Faint Turbidity |
Ukuncibilika Emanzini | Incibilika Emanzini, 80 g/l 25℃ |
I-Solubility (Incibilika Kakhulu ngaphakathi) | I-chloroform, i-benzene, i-methanol, i-acetone |
I-COA ne-MSDS | Iyatholakala |
Ibhrendi | I-Ruifu Chemical |
Into | Imininingwane |
Ukubukeka | I-Crystalline Powder Emhlophe noma Engamhlophe |
Ukuhlanzeka / Indlela Yokuhlaziya | >99.0% (HPLC) |
I-Melting Point | 110.0~114.0℃ |
Ayincibiliki Emanzini | <0.10% |
Umswakama (KF) | <0.30% |
Ukulahlekelwa Ekumisweni | <0.50% (Ngaphansi Kwe-Vacumn Amahora Ama-3 Ku-60ºC) |
Ukungcola Okukodwa | <0.50% |
Ukungcola Okuphelele | <1.00% |
I-Infrared Spectrum | Ihambisana Nesakhiwo |
1 H NMR Spectrum | Ihambisana Nesakhiwo |
Izinga Lokuhlola | I-Enterprise Standard |
Iphakheji:Ibhodlela, isikhwama se-Aluminium foil, 25kg/Cardboard Drum, noma ngokwezidingo zekhasimende.
Isimo Sesitoreji:Gcina ezitsheni ezivaliwe endaweni epholile neyomile (≤10℃) kude nezinto ezingahambelani.Vikela ekukhanyeni nakumswakama.
Ukuthumela:Thumela emhlabeni wonke nge-FedEx / DHL Express.Nikeza ukulethwa okusheshayo nokuthembekile.
1122-58-3 - Ubungozi Nokuphepha
Amakhodi Engozi
R25 - Kunobuthi uma ugwinywe
R34 - Ibangela ukusha
R24/25 -
R36/37/38 - Ukucasula amehlo, uhlelo lokuphefumula kanye nesikhumba.
R27 - Kunobuthi Kakhulu lapho uthintana nesikhumba
R36 - Ukucasula emehlweni
R24 - Ubuthi uma uthinta isikhumba
R20 - Kuyingozi ngokuhogela umoya
I-R61 - Ingabangela ukulimala enganeni engakazalwa
R40 - Ubufakazi obulinganiselwe bomphumela we-carcinogenic
R23/24/25 - Ubuthi ngokuhogela, ukuthintana nesikhumba futhi uma ugwinyiwe.
R67 - Izihwamuko zingadala ukozela kanye nesiyezi
R66 - Ukuchayeka kaningi kungabangela ukomisa kwesikhumba noma ukuqhekeka
R21/22 - Kuyingozi ukuthinta isikhumba futhi uma ugwinyiwe.
I-R11 - Ivutha Kakhulu
R36/37 - Ukucasula amehlo kanye nesistimu yokuphefumula.
R22 - Iyingozi uma igwinywe
I-R19 - Ingase yakhe ama-peroxides aqhumayo
Incazelo Yokuphepha
I-S36/37/39 - Gqoka izingubo zokuzivikela ezifanele, amagilavu nokuvikela iso/ubuso.
S45 - Uma kwenzeka ingozi noma uzizwa ungaphilile, funa iseluleko sezokwelapha ngokushesha (bonisa ilebula noma nini lapho kunokwenzeka.)
I-S28A -
S26 - Uma uthintana namehlo, geza ngokushesha ngamanzi amaningi futhi ufune iseluleko sezokwelapha.
I-S28 - Ngemva kokuthinta isikhumba, geza ngokushesha ngensipho eningi.
I-S36/37 - Gqoka izingubo zokuzivikela ezifanele namagilavu.
I-S53 - Gwema ukuchayeka - thola imiyalelo ekhethekile ngaphambi kokusetshenziswa.
S27 - Khumula ngokushesha zonke izingubo ezingcolile.
S22 - Ungaphefumuli uthuli.
S16 - Gcina kude nemithombo yokuthungela.
Omazisi be-UN UN 2811 6.1/PG 2
I-WGK Germany 3
I-RTECS US8400000
I-TSCA T
I-HS Code 2942000000
Inothi Le-Hazard Inobuthi/Iyagqwala
I-Hazard Class 8
Ukupakisha Iqembu II
Ubuthi LD50 ngomlomo kuNogwaja: 140 mg/kg LD50 dermal Rabbit 90 mg/kg
I-4-Dimethylaminopyridine (DMAP) (i-CAS: i-1122-58-3) i-catalyst entsha esebenza kahle kakhulu esetshenziswa kabanzi ekuhlanganiseni kwamakhemikhali.Inamandla amakhulu e-catalytic ku-organic synthesis, synthesis yezidakamizwa, isibulala-zinambuzane, udayi, iphunga elimnandi le-acylation, i-alkylation, i-etherification nezinye izinhlobo zokusabela, futhi inomphumela osobala kakhulu ekuthuthukiseni isivuno.I-acylation yotshwala;i-acylation ye-phenols;I-acylation yama-amine;i-acylation ye-enolates;Ukusabela kwe-isocyanates;Izinhlobonhlobo Zokusebenza;Ukudluliselwa Kwamaqembu Asebenzayo.
I-DMAP, i-super nucleophilic acylation catalyst.I-resonance yeqembu le-electron-donating dimethylamino esakhiweni salo kanye nendandatho engumzali (indandatho ye-pyridine) ingenza kusebenze i-athomu ye-nitrogen eringini ukuze ingene esikhundleni se-nucleophilic, evuselela kakhulu ukumelana notshwala obuphansi kanye nama-amine/ama-acids Umsebenzi. ukusabela kwe-acylation/esterification cishe izikhathi eziyi-104 ~ 106 kune-pyridine.Ukudluliswa kwe-Acyl kuwuguquko oluvamile emvelweni kanye nokuhlanganiswa kwezinto eziphilayo, lapho i-chiral DMAP iyisisusa esivamile sokudlulisa i-acyl.Kusukela ngo-1996, i-Vedejs nethimba le-Fu babike ukuthi ama-catalyst e-DMAP e-chiral aphakathi nendawo kanye ne-planar chiral ngokulandelana, ama-chiral DMAP catalysts athuthukiswe kakhulu.Izinhlobonhlobo ze-central chiral, i-planar chiral, i-spiro chiral kanye ne-central chiral DMAP kuye kwabikwa ngokulandelana, futhi kusetshenziswe kahle ekuphenduleni okuningi kokudluliswa kwe-asymmetric acyl.
I-DMAP iyi-nucleophilic catalyst eguquguquka kakhulu yokusabela kwe-acylation kanye ne-esterifications.Iphinde isetshenziswe ekuguquleni okuhlukahlukene kwezinto eziphilayo njenge-Baylis-Hillman reaction, ukusabela kwe-Dakin-West, ukuvikelwa kwama-amines, ama-C-acylations, ama-silylations, ukusetshenziswa kumakhemikhali wemikhiqizo yemvelo, nokunye okuningi.
I-DMAP ingasetshenziswa njenge-catalyst: Ukuze kuhlanganiswe ama-alcohol ane-acid anhydrides ngaphansi kwezimo ezisizayo nezingenayo i-solvent ukuze kuhlanganiswe ama-ester ahambisanayo.Ekuphenduleni kwe-Baylis-Hillman ukwakha ibhondi ye-carbon-carbon ngokuhlangana kwe-alkene ecushiwe ne-aldehyde noma i-ketone.
I-catalyst esebenza kahle kakhulu yokusabela kwe-acylation.