Iodotrimethylsilane CAS 16029-98-4 Ukuhlanzeka >99.0% (Argentmetric Titration) Factory

Iodotrimethylsilane (CAS: 16029-98-4) ene-asidi eqinile (Me3Si) -soft base (I) ibhondi ibonisa i-oxygenophilicity eqinile kuma-ethers, esters, lactones, acetals, namanye ama-molecule ahlanganisa i-athomu ye-oksijini njengeqembu elisebenzayo.Ukusetshenziswa kwe-iodotrimethylsilane njenge-ejenti kulethe ukuqhekeka okulula kwe-tert-butyl ester, okunikeza i-carboxylic acid ehambisanayo ngesivuno esihle kakhulu.Iodotrimethylsilane isetshenziselwa ukwethulwa kweqembu le-trimethylsilyl ku-organic synthesis.Kuwusizo futhi ekuhlaziyweni kwe-chromatography yegesi ngokuguqula utshwala bubenze i-silyl ether derivative, ngaleyo ndlela buyenze buguquke kakhulu kune-molecule yokuqala.I-Iodotrimethylsilane iyi-reagent esebenzayo ye-ether, i-ester, i-carbamate, i-ketal, ne-lactone cleavage.Ngokwethulwa kweqembu le-TMS, isb, ama-TMS enol ethers.I-reagent eyinhloko yokuvinjelwa okukhethiwe kweqembu le-N-Cbz phambi kwe-trimethyltin moiety.I-Reagent isanda kubikwa ukuthi iguqule i-alyl- ne-benzylphosphotriesters kuma-iodide ahambisanayo.I-Iodotrimethylsilane iyi-ejenti evimbelayo evamile ekukhiqizeni imithi, esetshenziswa kakhulu ekuhlanganiseni kwezidakamizwa.Ingavikela noma ivikele amaqembu asebenzayo ngokukhetha, isebenze njenge-ejenti yokuvimbela i-silane.I-Iodotrimethylsilane iyi-reagent enemisebenzi eminingi esetshenziswa ekuphenduleni okuhlukahlukene kwe-organic.Isetshenziselwa ukuhlanganiswa kwezinhlanganisela ezimbalwa ezifana ne-lactones, ethers, acetals, ne-carbamates kanye ne-trimethylsilylating agent ukuze kuhlanganiswe i-silyl imino esters, i-alkyl kanye ne-alkenyl silanes, njll. Iphinde isebenze njenge-catalyst ye-Lewis acid futhi njenge-ejenti yokunciphisa ukusabela okuningi kwe-organic.Iodotrimethylsilane ingasetshenziswa njenge-reagent eguquguqukayo ekuhlanganiseni okuncane kwe-ethers, i-carboxylic esters, i-lactones, i-carbamates, i-acetals, i-phosphonate ne-phosphate esters;ukuhlukaniswa kwama-epoxides, i-cyclopropyl ketones;ukuguqulwa kwe-vinyl phosphates ku-vinyl iodide;i-neutral nucleophilic reagent yokusabela kokushintshaniswa kwe-halogen, ukusabela kwe-carbonyl kanye ne-conjugate add;sebenzisa njenge-ejenti ye-trimethylsilylating ekwakheni i-enol ethers, i-silyl imino esters, ne-N-silylenamines, i-alkyl, i-alkenyl ne-alkynyl silanes;I-Lewis acid catalyst yokwakheka kwe-acetal, i-α- alkoxymethylation yama-ketones, yokusabela kwama-acetals ane-silyl enol ethers nama- allylsilanes;i-ejenti yokunciphisa i-epoxides, i-enediones, i-α-ketols, i-sulfoxides, ne-sulfonyl halides;i-dehydrating ejenti yama-oximes.